TRANSPARENT CONDUCTIVE FILM AND METHOD FOR PRODUCTION THEREOF
    8.
    发明申请
    TRANSPARENT CONDUCTIVE FILM AND METHOD FOR PRODUCTION THEREOF 审中-公开
    透明导电薄膜及其生产方法

    公开(公告)号:US20090286071A1

    公开(公告)日:2009-11-19

    申请号:US12414098

    申请日:2009-03-30

    申请人: Kazuaki SASA

    发明人: Kazuaki SASA

    IPC分类号: B32B9/04 C23C14/35

    摘要: the transparent conductive film of the present invention is a transparent conductive film, comprising: an organic polymer film substrate; a first oxide thin film with a high visible-light transmittance formed on the organic polymer film substrate; and a ZnO-based transparent conductive thin film formed on the first oxide thin film, wherein the first oxide thin film has an oxygen content corresponding to 60 to 90% of the stoichiometric value before the ZnO-based transparent conductive thin film is formed. The transparent conductive film exhibits low resistance even when the ZnO-based transparent conductive thin film is relatively thin (particularly 100 nm or less in thickness), and has a low rate of change in resistance value even under a humidification and heating environment.

    摘要翻译: 本发明的透明导电膜是透明导电膜,包括:有机聚合物膜基材; 在有机聚合物膜基材上形成具有高可见光透射率的第一氧化物薄膜; 以及在所述第一氧化物薄膜上形成的ZnO系透明导电薄膜,其中,所述第一氧化物薄膜的氧含量相当于形成所述ZnO系透明导电薄膜前的化学计量值的60〜90%。 即使在ZnO系透明导电性薄膜相对较薄(特别是厚度在100nm以下)的情况下,透明导电膜也具有低电阻,即使在加湿环境下也具有低电阻变化率。

    Process of producing sulfonic group-containing substituted polyacetylene membrane, membrane obtained thereby and application thereof
    9.
    发明申请
    Process of producing sulfonic group-containing substituted polyacetylene membrane, membrane obtained thereby and application thereof 审中-公开
    制备含磺基取代的聚乙炔膜的方法,由此获得的膜及其应用

    公开(公告)号:US20070231654A1

    公开(公告)日:2007-10-04

    申请号:US11730008

    申请日:2007-03-29

    IPC分类号: H01M8/10 C08J5/22

    摘要: A process of producing a substituted polyacetylene electrolyte membrane which is a solid electrolyte membrane having a sulfonic group uniformly introduced thereinto, with its electrode assembly being useful as an electrochemical device or a fuel cell and an electrolyte membrane using the same are provided. A process of producing a sulfonic group-containing substituted polyacetylene membrane, which includes molding a substituted polyacetylene containing a repeating unit represented by the following formula (1) into a membrane state and bringing the molding into contact with a sulfonating agent to achieve sulfonation and a substituted polyacetylene membrane which is produced by the subject production process and in which the sulfonic group is uniformly distributed in a membrane thickness direction. In the formula (1), either one or all of R1 and R2 represent a silyl group represented by the following formula (2); and the remainder represents hydrogen, a hydroxyl group, an alkyl group or an alkoxy group each having from 1 to 8 carbon atoms, a t-butyldimethylsilyloxy group, an acetyloxy group, or a group represented by the following formula (3). In the formula (2), X1, X2 and X3 each independently represents a linear or branched alkyl group having from 1 to 6 carbon atoms. In the formula (3), R3 represents hydrogen, a hydroxyl group, an alkyl group or an alkoxy group each having from 1 to 8 carbon atoms, a trimethylsilyl group, a t-butyldimethylsilyloxy group, an acetyloxy group, or a group represented by the formula (2).

    摘要翻译: 提供了一种具有均匀引入磺酸基的固体电解质膜的取代聚乙炔电解质膜的制造方法,其电极组件可用作电化学装置或燃料电池以及使用该电解质膜的电解质膜。 含有磺酸基的取代的聚乙炔膜的制造方法,其包括将含有下述式(1)表示的重复单元的取代聚乙炔成型为膜状,使模制物与磺化剂接触以实现磺化和 取代聚乙炔膜,其通过本制造方法制造,其中磺酸基在膜厚度方向上均匀分布。 在式(1)中,R 1和R 2中的一个或全部表示由下式(2)表示的甲硅烷基。 其余为氢,羟基,烷基或碳原子数1〜8的烷氧基,叔丁基二甲基甲硅烷氧基,乙酰氧基或下述式(3)所示的基团。 在式(2)中,X 1,X 2和X 3各自独立地表示具有1至6个碳原子的直链或支链烷基 碳原子。 在式(3)中,R 3表示氢,羟基,烷基或具有1至8个碳原子的烷氧基,三甲基甲硅烷基,叔丁基二甲基甲硅烷氧基, 乙酰氧基或由式(2)表示的基团。

    Method for producing (meth) acrylic acid ester polymer
    10.
    发明申请
    Method for producing (meth) acrylic acid ester polymer 审中-公开
    (甲基)丙烯酸酯聚合物的制备方法

    公开(公告)号:US20050038218A1

    公开(公告)日:2005-02-17

    申请号:US10945903

    申请日:2004-09-22

    摘要: There is provided a (meth) acrylic ester polymer having A silicon-containing functions group capable of crosslinking Through formation of a siloxane bond, or a composition comprising the polymer, which does not contain any environment-hostile aromatic compound derived from a solvent, and of which TVOC (total volatile organic compound) emission is less than 1,500·g/m3. There is further provided a method for producing a polymer comprising a (meth) acrylic ester monomer unit as a molecular chain and having a silicon-containing functional group capable of crosslinking through formation of a siloxane bond, which comprises polymerizing a (meth)acrylic ester monomer using a solvent not containing any aromatic solvents as a polymerization solvent.

    摘要翻译: 提供具有能够交联的含硅官能团的(甲基)丙烯酸酯聚合物通过形成硅氧烷键,或者包含不含有衍生自溶剂的任何环境恶化芳族化合物的聚合物的组合物,以及 其中TVOC(总挥发性有机化合物)排放量小于1,500.g / m 3。 还提供了一种制备聚合物的方法,所述聚合物包含(甲基)丙烯酸酯单体单元作为分子链,并且具有能够通过形成硅氧烷键而交联的含硅官能团,其包括聚合(甲基)丙烯酸酯 使用不含任何芳族溶剂的溶剂作为聚合溶剂的单体。