摘要:
The present invention provides a production method of a hydroxyl-containing polymer including: protecting a hydroxyl group of a hydroxyl-containing monomer with a protecting group to make the monomer a protected monomer with decreased hydrophilicity; adding the protected monomer alone or together with a hydrophobic monomer to a water-based medium containing a salt and a dispersion stabilizer; adding a polymerization initiator to the mixture to carry out suspension polymerization; and de-protecting the obtained polymer having the protecting group to recover the hydroxyl group.
摘要:
The invention provides a maleimidyl-containing material having a substituent group defined by the following structural formula (1) containing a maleimidyl group (maleimido group): wherein A denotes a spacer containing an amino acid or a peptide spacer P. Also, the invention provides a production method of the above-mentioned maleimidyl-containing material involving a step of reacting a material containing an amino acid or a peptide chain with a compound containing a maleimido group.
摘要:
The present invention relates to a maleimide group-containing polymer particle containing a crosslinked polymer particle containing a group represented by the following formula (1) and to a method of producing the maleimide group-containing crosslinked polymer particle by reacting hydroxymethylmaleimide with a hydroxyl group-containing polymer particle obtained by introducing a polyethylene glycol into a crosslinked polymer particle: wherein n denotes an integer of 1 or more.
摘要:
A method for quantitatively determining the amount of maleimidyl groups on a polymer fine particle containing at least maleimidyl groups, by allowing a fluorescent material having an SH group to react with the maleimidyl groups and determining the amount of maleimidyl groups by means of measuring the fluorescence of the fluorescent material.
摘要:
A crosslinked polymer particle can be obtained by carrying out a crosslinking reaction between a non-crosslinked polymer particle containing a succinimidoxycarbonyl group and a compound having two or more amino groups.
摘要:
The present invention provides a method for producing hydroxyl group-containing polymer particles including causing cross-linked polymer particles containing a (meth)acrylate polymer to react in the presence of a metal-containing ester-exchange reaction catalyst with at least one compound selected from the group consisting of a compound including at least two hydroxyl groups and a compound including at least one primary amino group and at least one hydroxyl group, the cross-linked polymer particles comprising the (meth)acrylate polymer represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group; R2 to R4 may be the same or different from each other, and each independently represents a substituted or non-substituted alkyl group or a substituted or non-substituted aryl group, any one of which has 1 to 12 carbon atoms; and n represents an integer of 1 or more.
摘要翻译:本发明提供一种含羟基聚合物颗粒的制造方法,其包括使含有(甲基)丙烯酸酯聚合物的交联聚合物颗粒在含金属的酯交换反应催化剂存在下与至少一种选自 由包含至少两个羟基的化合物和包含至少一个伯氨基和至少一个羟基的化合物组成的组,所述交联聚合物颗粒包含由下式(I)表示的(甲基)丙烯酸酯聚合物, 其中R 1表示氢原子或甲基; R 2至R 4可以彼此相同或不同,并且各自独立地表示取代或未取代的烷基或取代或未取代的芳基,其中任何一个具有1至12个碳 原子 n表示1以上的整数。
摘要:
According to an aspect of the invention, there is provided a hydroxyl group-containing magnetic polymer which is a particulate hydroxyl group-containing magnetic polymer including a magnetic powder and a polymer of ethylenically unsaturated monomers, the content of the magnetic powder being within the range of from 5 to 90% by mass, the ethylenically unsaturated monomers comprising a hydrophilic monomer having a hydroxyl group and a hydrophobic monomer, and the amount of hydroxyl groups in the portion of the hydroxyl group-containing polymer being within the range of from 0.3 to 5.0 mmol/g.
摘要:
The present invention relates to a maleimide group-containing polymer particle containing a crosslinked polymer particle containing a group represented by the following formula (1) and to a method of producing the maleimide group-containing crosslinked polymer particle by reacting hydroxymethylmaleimide with a hydroxyl group-containing polymer particle obtained by introducing a polyethylene glycol into a crosslinked polymer particle: wherein n denotes an integer of 1 or more.
摘要:
The present invention relates to a method of producing a functional polymer particle having at least one kind of functional group selected from the following structure group (A), which comprises the step of reacting a non-crosslinked polymer particle having a succinimidoxycarbonyl group with a compound having at least one kind of functional group selected from the following structure group (A) and at least one functional group selected from the group consisting of a primary amino group and a secondary amino group:
摘要:
A polymer comprising a styrene-based monomer and t-butyl methacrylate, wherein a proportion of the styrene-based monomer in the polymer is 30% by mol to 90% by mol and the polymer has a functional group represented by the following formula (1) which includes a maleimidyl group: wherein in the formula (1), X represents —O— or —NH— and Q represents a spacer group. A ligand immobilization support comprising the polymer.