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1.发明授权
公开(公告)号：US4131594A
公开(公告)日：1978-12-26
申请号：US579064
申请日：1975-05-20
CPC分类号： C08L67/02
摘要： A fire-resistant thermoplastic polyester resin composition having excellent anti-dripping properties which comprises(A) an aromatic polyester resin,(B) a graft copolymer of a butadiene polymer-vinyl monomer in an amount of at least 0.5 parts by weight but less than 25 parts by weight per 100 parts by weight of said polyester resin (A),(c) a fire retardant in an amount of from 0.5 to 35 parts by weight per 100 parts by weight of said polyester resin (A).
摘要翻译： 一种具有优异的抗滴落性能的耐火热塑性聚酯树脂组合物，其包含（A）芳族聚酯树脂，（B）丁二烯聚合物 - 乙烯基单体的接枝共聚物，其量为至少0.5重量份但小于 所述聚酯树脂（A）每100重量份为25重量份，（C）相对于所述聚酯树脂（A）100重量份为0.5〜35重量份的阻燃剂。
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2.发明授权
公开(公告)号：US4102853A
公开(公告)日：1978-07-25
申请号：US622498
申请日：1975-10-15
摘要： A fire-retardant thermoplastic polyester resin composition free from "dripping" comprising(A) 100 parts by weight of an aromatic polyester resin,(B) from 0.5 to 100 parts by weight of an alkaline earth metal carbonate, and(C) from 0.5 to 50 parts by weight of a fire retardant.
摘要翻译： 不含“滴”的阻燃热塑性聚酯树脂组合物，其包含（A）100重量份的芳族聚酯树脂，（B）0.5至100重量份的碱土金属碳酸盐和（C）0.5 至50重量份的阻燃剂。
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公开(公告)号：US4031165A
公开(公告)日：1977-06-21
申请号：US617844
申请日：1975-09-29
摘要： In a process for preparing a block copolyester elastomer having a softening point of at least 120.degree. C. by reacting an aromatic polyester (I) having a reduced viscosity of at least 0.4 and derived from an aromatic dicarboxylic acid or its ester-forming derivative as a main acid component with an aliphatic polyester (II) having a reduced viscosity of at least 0.4 and derived from an aliphatic dicarboxylic acid or an aliphatic hydroxycarboxylic acid or an ester-forming derivative of each of these acids in the molten state; the improvement whereinA. the aromatic polyester (I) is derived from a dicarboxylic acid component more than 70 mole % of which consists of terephthalic acid and diol component more than 70 mole % of which consists of tetramethylene glycol or trimethylene glycol,B. the weight ratio of the aromatic polyester (I) to the aliphatic polyester (II) is 0.25 to 9, andC. the reaction between the polyester (I) and the polyester (II) is carried out until a polymer is obtained which has an elasticity recovery of at least 50% after it is stretched 20% and then relaxed for 5 minutes.
摘要翻译： 在制备软化点为至少120℃的嵌段共聚酯弹性体的方法中，通过使具有至少0.4的比浓的粘度的芳族聚酯（I）与来自芳族二羧酸或其成酯衍生物的芳族聚酯 一种主要的酸成分，其中具有至少0.4的比浓粘度的脂肪族聚酯（II）衍生自熔融状态的这些酸的脂肪族二羧酸或脂族羟基羧酸或成酯衍生物; 其中A.芳香族聚酯（I）衍生自多于70摩尔％的二羧酸成分，其中多于70摩尔％的对苯二甲酸和二醇组分由四亚甲基二醇或三亚甲基二醇组成。B. 芳香族聚酯（I）与脂肪族聚酯（II）的重量比为0.25〜9，C进行聚酯（I）与聚酯（II）的反应，直到得到具有弹性的聚合物 在拉伸20％后再恢复至少50％，然后松弛5分钟。
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公开(公告)号：US4242398A
公开(公告)日：1980-12-30
申请号：US51742
申请日：1979-06-25
申请人： Yasuhiko Segawa , Noritsugu Saiki
发明人： Yasuhiko Segawa , Noritsugu Saiki
CPC分类号： B29C51/145 , B29C70/00 , B32B5/26 , B29C51/082 , B29K2309/08 , B29K2995/0007 , Y10S428/921 , Y10T428/24612 , Y10T428/24967 , Y10T428/24992 , Y10T428/26 , Y10T428/266 , Y10T428/27 , Y10T442/674
摘要： A fibrous shaped article having a surface with raised and depressed portions, said fibrous article consisting of a unitary laminated structure resulting from the compression molding under heat of (A) a heat compression-moldable nonwoven fibrous web and (B) a nonwoven fibrous sheet, said fibrous sheet (B) being laminated to at least one surface of said fibrous web (A); said fibrous web (A) having a compression stress, at 10% compression at the temperature of said compression molding, of at least 0.5 g/cm.sup.2 ; said nonwoven fibrous sheet (B) consisting of a continuous unitary reticulated sheet structure of an assembly of many fibers of a thermoplastic polymer, said constituent fibers having an initial modulus of not more than 5 g/denier and an elongation of at least 20% both at the temperature of said compression molding and being interconnected in a spaced-apart relationship, and said nonwoven fibrous sheet (B) having a plastic deformation ratio, at 30% elongation at the temperature of said compression molding, of at least 50% and an elongation stress, at 30% elongation at the temperature of said compression molding, of not more than 0.15 kg/cm; and said web (A) and said sheet (B) satisfying the following relation:S.ltoreq.0.03 Tin which T is the compression stress (g/cm.sup.2) of said web (A) at 10% compression at the temperature of said compression molding, and S is the elongation stress (kg/cm) of said sheet (B) at 30% elongation at the temperature of said compression molding. This article is useful as soundproofing materials, heat insulating materials, cushioning materials, etc.
摘要翻译： 一种具有凸起和凹陷部分的表面的纤维状制品，所述纤维制品由（A）热压缩成型非织造纤维幅材和（B）非织造纤维片材在加热下由压塑而成的单一叠层结构体组成， 所述纤维片材（B）被层压到所述纤维网（A）的至少一个表面上; 所述纤维网（A）具有至少0.5g / cm 2的压缩应力，在所述压缩模塑的温度下10％压缩; 所述非织造纤维片（B）由热塑性聚合物的许多纤维的组合的连续的单一网状片状结构组成，所述构成纤维的初始模量不超过5g /旦尼尔，伸长率为至少20％ 在所述压缩模塑的温度下并以间隔的关系相互连接，并且所述非织造纤维片材（B）具有塑性变形率，在所述压缩模塑的温度下在30％伸长率下为至少50％，并且 在所述压缩模塑的温度下在30％伸长率下的伸长应力不大于0.15kg / cm; 和所述片材（A）和所述片材（B）满足以下关系：S
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公开(公告)号：US5814696A
公开(公告)日：1998-09-29
申请号：US701550
申请日：1996-08-22
CPC分类号： H01H50/305 , C08L67/02 , C08L67/025 , H01H9/02
摘要： A polyester resin composition comprising (A) an aromatic polyester resin and (B) a polyester block copolymer resin which consists essentially of (a) a polyester soft block comprising an aromatic dicarboxylic acid component and a glycol component having 5 or more carbon atoms as main constituents and having a melting point of about 100.degree. C. or less or being amorphous and (b) a polyester hard block having a melting point of about 150.degree. C. or more. A relay component formed of the above polyester resin composition has excellent vibration-damping and noise suppression properties.
摘要翻译： 一种聚酯树脂组合物，其包含（A）芳族聚酯树脂和（B）聚酯嵌段共聚物树脂，其基本上由（a）包含芳族二羧酸组分和具有5个或更多个碳原子的二醇组分的聚酯软嵌段 成分，熔点约为100℃以下，或为无定形，（b）熔点为150℃以上的聚酯硬质块。 由上述聚酯树脂组合物形成的中继部件具有优异的减震和噪声抑制特性。
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公开(公告)号：US5384184A
公开(公告)日：1995-01-24
申请号：US128314
申请日：1993-09-28
IPC分类号： C08G63/181 , C08G63/688 , C08G63/692 , D03D15/08 , D03D15/12
CPC分类号： D03D15/08 , C08G63/181 , C08G63/6886 , C08G63/6926 , D03D15/12 , Y10T442/413
摘要： A polyester block copolymer having an inherent viscosity of at least 0.6, which comprises (A) 30 to 90% by weight of polyester segments comprising a benzenedicarboxylic acid as the main acid component and a diol having 5 to 12 carbon atoms between the hydroxyl groups as the main glycol component and (B) 70 to 10% by weight of polyester segments comprising an aromatic dicarboxylic acid as the main acid component and ethylene glycol, trimethylene glycol, tetramethylene glycol or 1,4-cyclohexane dimethanol as the main glycol component, wherein (i) when a polyester having an inherent viscosity of at least 0.6 is formed by polycondensation of the components constituting the polyester segments (A), the melting point of the obtained polyester is lower than 50.degree. C. or the obtained polyester is amorphous, and (ii) when a polyester having an inherent viscosity of at least 0.6 is formed by polycondensation of the components constituting the polyester segments (B), the melting point of the polyester is higher than 180.degree. C. This polyester block copolymer provides an elastic yarn having a high elastic recovery and a high heat resistance.
摘要翻译： 具有至少0.6的特性粘度的聚酯嵌段共聚物，其包含（A）30至90重量％的包含苯二甲酸作为主要酸组分的聚酯链段和羟基之间具有5至12个碳原子的二醇作为 主要二元醇组分和（B）70至10重量％的包含芳族二羧酸作为主要酸组分的聚酯链段和乙二醇，三亚甲基二醇，1,4-丁二醇或1,4-环己烷二甲醇作为主要二醇组分，其中 （i）当通过构成聚酯链段（A）的组分的缩聚形成具有至少0.6的特性粘度的聚酯时，所得聚酯的熔点低于50℃，或所得聚酯是无定形的， 和（ii）当通过构成聚酯链段（B）的组分的缩聚形成特性粘度至少为0.6的聚酯时，聚合物的熔点 ster高于180℃。该聚酯嵌段共聚物提供了具有高弹性回复性和高耐热性的弹性纱线。
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公开(公告)号：US4619987A
公开(公告)日：1986-10-28
申请号：US785478
申请日：1985-10-08
申请人： Noritsugu Saiki , Tadashi Konishi
发明人： Noritsugu Saiki , Tadashi Konishi
摘要： A process for preparing a high-molecular weight polyester comprising additionally polymerizing a polyester obtained from a dicarboxylic acid component composed mainly of an aromatic dicarboxylic acid and/or an ester-forming derivative thereof and a glycol component composed mainly of ethylene glycol and/or an ester-forming derivative thereof and having an intrinsic viscosity of at least 0.8, at a temperature above the melting point of the polyester and under a reduced pressure, in the presence of a compound (A) successively generating a substance which is gaseous under the polymerization conditions and does not substantially reduce the molecular weight of the polyester, to form a polyester having an intrinsic viscosity of at least 1.0.
摘要翻译： 一种制备高分子量聚酯的方法，其包括另外聚合由主要由芳族二羧酸和/或其成酯衍生物组成的二羧酸组分得到的聚酯和主要由乙二醇和/或 酯形成衍生物，其特性粘度至少为0.8，在高于聚酯熔点的温度下，在减压下，在连续产生在聚合物下为气态的物质的化合物（A）的存在下， 条件并且基本上不降低聚酯的分子量，形成特性粘度至少为1.0的聚酯。
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公开(公告)号：US6133358A
公开(公告)日：2000-10-17
申请号：US142638
申请日：1998-09-10
申请人： Mioko Suzuki , Noritsugu Saiki
发明人： Mioko Suzuki , Noritsugu Saiki
CPC分类号： C08L67/02
摘要： A non-halogen flame retardant polyester resin composition shows high flame retardancy with a small amount of a flame retardant, provides a molded product not causing dripping at the time of combustion, is excellent in mechanical strength and resin knead-processability, and is free from bleed-out by annealing, wherein the resin composition comprises 100 parts by weight of a polyester such as polytetramethylene terephthalate, 1 to 15 parts by weight of coated red phosphorus powder and 3 to 70 parts by weight of a novolak phenol resin.
摘要翻译： PCT No.PCT / JP98 / 00013 Sec。 371日期：1998年9月10日 102（e）1998年9月10日PCT PCT。1998年1月6日PCT公布。 公开号WO98 / 30632 日期1998年7月16日非卤素阻燃聚酯树脂组合物用少量阻燃剂显示出高阻燃性，提供在燃烧时不引起滴落的成型体，机械强度和树脂捏合加工性优异 并且通过退火没有渗出，其中树脂组合物包含100重量份的聚酯，例如聚对苯二甲酸丁二醇酯，1至15重量份的涂覆的红磷粉末和3至70重量份的酚醛清漆酚 树脂。
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公开(公告)号：US5631060A
公开(公告)日：1997-05-20
申请号：US597933
申请日：1996-02-07
IPC分类号： C08J5/00 , B29C45/00 , C08K5/09 , C08L67/00 , C08L67/02 , G06F3/02 , H01H13/14 , H01H13/70 , G06C7/02
CPC分类号： H01H13/70 , B29C45/0001 , B29C45/0081 , B29L2031/466 , H01H2209/002 , H01H2229/044 , Y10T428/24025 , Y10T428/24479
摘要： A resin molded article having a moveable projecting portion suitable for use in forming a keyboard or keyboard switch and which is substantially free from flex fatigue. At least the moveable projecting portion of the molded article is formed from a resin composition containing a polyether ester block copolymer and a small amount of an alkali metal salt of an aliphatic carboxylic acid having 10 to 36 carbon atoms. The polyether ester block copolymer contains units from terephthalic acid, tetramethylene glycol and polyoxytetramethylene glycol. The resin molded article includes a thick projecting (moveable) portion, a base portion and a flexible thin side portion connecting the thick projecting portion to the base portion. The side portion has a thickness of 0.05 to 0.5 mm and a flexibility retention of at least 85%.
摘要翻译： 一种具有适于用于形成键盘或键盘开关并且基本上没有挠曲疲劳的可移动突出部分的树脂模制品。 至少模塑制品的可移动突出部分由含有聚醚酯嵌段共聚物和少量具有10至36个碳原子的脂族羧酸的碱金属盐的树脂组合物形成。 聚醚酯嵌段共聚物含有来自对苯二甲酸，四亚甲基二醇和聚氧四亚甲基二醇的单元。 树脂成形品具有厚的突起（可移动）部分，基部和将厚的突出部分连接到基部的柔性薄侧部分。 侧部的厚度为0.05〜0.5mm，弹性保持率为85％以上。
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公开(公告)号：US4959442A
公开(公告)日：1990-09-25
申请号：US421305
申请日：1989-10-12
CPC分类号： C08J7/12 , C08G79/025 , C08J2385/02
摘要： A shaped polyphosphazene article having a modified surface portion thereof and exhibiting a desired property and/or performance comprises a polyphosphazene polymer having at least 50 molar % or more of repeating units of the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 in the first and second side chains --OR.sup.1 and --OR.sup.2 respectively represent, independently from each other, an aliphatic, cycloaliphatic or aromatic radical, and having at least a portion of a surface portion thereof in which at least 5 molar % of the first and second side chains are converted to one or more types of third side chains --OR.sup.3 wherein R.sup.3 represents an aliphatic, cycloaliphatic or aromatic radical and which are different from --OR.sup.1 and --OR.sup.2.
摘要翻译： 具有改性表面部分并具有所需性能和/或性能的成型聚磷腈制品包括具有至少50摩尔％或更多的式（I）的重复单元的聚磷腈聚合物：其中R1和 第一和第二侧链-OR1和-OR2中的R2分别独立地表示脂肪族，脂环族或芳族基团，并且具有其表面部分的至少一部分，其中至少5摩尔％的第一 并且第二侧链转化成一种或多种类型的第三侧链-OR 3，其中R 3表示脂族，脂环族或芳族基团，并且不同于-OR 1和-OR 2。
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