Cooling And Pelletizing Process For Semi-Crystalline Polymers
    1.
    发明申请
    Cooling And Pelletizing Process For Semi-Crystalline Polymers 有权
    半结晶聚合物的冷却和造粒工艺

    公开(公告)号:US20120319318A1

    公开(公告)日:2012-12-20

    申请号:US13466182

    申请日:2012-05-08

    IPC分类号: B29C47/76

    摘要: Methods and systems for pelletizing low molecular weight semi-crystalline polymers are provided herein. Polymer compositions comprising the semi-crystalline polymer and a solvent are provided to a devolatilizing device, where the solvent is at least partially evaporated under vacuum conditions, resulting in removal of heat from the polymer by evaporative cooling and crystallization of the polymer. Once the polymer has reached the desired temperature, the polymer exits the devolatilizer and is pelletized. Semi-crystalline polymers that may be used in the present invention include propylene-based copolymers, such as propylene-ethylene and propylene-hexene copolymers having a heat of fusion, Hf, from about 5 to about 75 J/g and a weight average molecular weight, Mw, from about 10,000 to about 200,000 g/mol.

    摘要翻译: 本文提供了用于造粒低分子量半结晶聚合物的方法和系统。 将包含半结晶聚合物和溶剂的聚合物组合物提供给脱挥发分装置,其中溶剂在真空条件下至少部分蒸发,导致通过蒸发冷却和聚合物结晶从聚合物中除去热量。 一旦聚合物达到所需温度,聚合物就离开脱挥发物并造粒。 可用于本发明的半结晶聚合物包括基于丙烯的共聚物,例如丙烯 - 乙烯和丙烯 - 己烯共聚物,其熔融热,Hf为约5至约75J / g,重均分子量 重量,Mw,约10,000至约200,000g / mol。

    Cooling and pelletizing process for semi-crystalline polymers
    2.
    发明授权
    Cooling and pelletizing process for semi-crystalline polymers 有权
    半结晶聚合物的冷却和造粒工艺

    公开(公告)号:US09296837B2

    公开(公告)日:2016-03-29

    申请号:US13466182

    申请日:2012-05-08

    摘要: Methods and systems for pelletizing low molecular weight semi-crystalline polymers are provided herein. Polymer compositions comprising the semi-crystalline polymer and a solvent are provided to a devolatilizing device, where the solvent is at least partially evaporated under vacuum conditions, resulting in removal of heat from the polymer by evaporative cooling and crystallization of the polymer. Once the polymer has reached the desired temperature, the polymer exits the devolatilizer and is pelletized. Semi-crystalline polymers that may be used in the present invention include propylene-based copolymers, such as propylene-ethylene and propylene-hexene copolymers having a heat of fusion, Hf, from about 5 to about 75 J/g and a weight average molecular weight, Mw, from about 10,000 to about 200,000 g/mol.

    摘要翻译: 本文提供了用于造粒低分子量半结晶聚合物的方法和系统。 将包含半结晶聚合物和溶剂的聚合物组合物提供给脱挥发分装置,其中溶剂在真空条件下至少部分蒸发,导致通过蒸发冷却和聚合物结晶从聚合物中除去热量。 一旦聚合物达到所需温度,聚合物就离开脱挥发物并造粒。 可用于本发明的半结晶聚合物包括基于丙烯的共聚物,例如丙烯 - 乙烯和丙烯 - 己烯共聚物,其熔融热,Hf为约5至约75J / g,重均分子量 重量,Mw,约10,000至约200,000g / mol。

    Methods for monitoring reactor passivation for gas phase polymerization
    5.
    发明授权
    Methods for monitoring reactor passivation for gas phase polymerization 失效
    监测气相聚合反应器钝化的方法

    公开(公告)号:US07718743B2

    公开(公告)日:2010-05-18

    申请号:US12184681

    申请日:2008-08-01

    IPC分类号: C08F2/00 C08F2/34 B01J19/24

    摘要: Methods and system for in-situ measurement of polymer growth within an olefin polymerization reactor are provided. The method includes polymerizing one or more olefins within a reactor at a first temperature sufficient to deposit a polymer coating therein. A second temperature is created within the reactor, and a rate of temperature change is measured from the first temperature to the second temperature. The rate of temperature change is correlated to a thickness of the polymer coating deposited within the reactor.

    摘要翻译: 提供了在烯烃聚合反应器内原位测量聚合物生长的方法和系统。 该方法包括在足以在其中沉积聚合物涂层的第一温度下在反应器内聚合一种或多种烯烃。 在反应器内产生第二温度,并且从第一温度到第二温度测量温度变化率。 温度变化的速率与沉积在反应器内的聚合物涂层的厚度相关。

    Polymer compositions exhibiting enhanced flow-induced crystallization
    6.
    发明申请
    Polymer compositions exhibiting enhanced flow-induced crystallization 审中-公开
    表现出增强的流动诱导结晶的聚合物组合物

    公开(公告)号:US20090163666A1

    公开(公告)日:2009-06-25

    申请号:US12316760

    申请日:2008-12-16

    IPC分类号: C08L9/00 C08L23/06 B29C47/00

    摘要: Provided is a polymer composition having a linear, semi-crystalline thermoplastic matrix polymer and a second thermoplastic polymer. The second polymer is a substantially saturated hydrocarbon polymer including (i) a backbone chain and (ii) one or more substantially hydrocarbon sidechains connected to the backbone chain. The sidechains each have a number-average molecular weight of from 2,500 g/mol to 125,000 g/mol and an MWD by SEC of 1.0 to 3.5. The mass ratio of sidechain molecular mass to backbone molecular mass is from 0.01:1 to 100:1. The matrix polymer is present at 95 wt % or more based on the weight of the composition. The second polymer is present at 0.2 to 5.0 wt % or more based on the weight of the composition. Provided is also a method for enhancing flow-induced crystallization in a linear, semi-crystalline thermoplastic matrix polymer. Provided is also a method for processing a polymer composition.

    摘要翻译: 提供了具有线性,半结晶热塑性基质聚合物和第二热塑性聚合物的聚合物组合物。 第二聚合物是基本上饱和的烃聚合物,包括(i)主链和(ii)连接到主链上的一个或多个基本上是烃的侧链。 侧链各自的数均分子量为2500g / mol至125,000g / mol,SEC的MWD为1.0至3.5。 侧链分子量与骨架分子量的质量比为0.01:1〜100:1。 基于组合物的重量,基质聚合物的存在量为95重量%以上。 基于组合物的重量,第二聚合物的含量为0.2〜5.0重量%以上。 提供了一种用于在线性半结晶热塑性基质聚合物中增强流动诱导结晶的方法。 还提供了一种加工聚合物组合物的方法。

    Methods For Monitoring Reactor Passivation For Gas Phase Polymerization
    7.
    发明申请
    Methods For Monitoring Reactor Passivation For Gas Phase Polymerization 失效
    气相聚合反应器钝化监测方法

    公开(公告)号:US20100029865A1

    公开(公告)日:2010-02-04

    申请号:US12184681

    申请日:2008-08-01

    IPC分类号: C08F2/01 B01J19/24

    摘要: Methods and system for in-situ measurement of polymer growth within an olefin polymerization reactor are provided. The method includes polymerizing one or more olefins within a reactor at a first temperature sufficient to deposit a polymer coating therein. A second temperature is created within the reactor, and a rate of temperature change is measured from the first temperature to the second temperature. The rate of temperature change is correlated to a thickness of the polymer coating deposited within the reactor.

    摘要翻译: 提供了在烯烃聚合反应器内原位测量聚合物生长的方法和系统。 该方法包括在足以在其中沉积聚合物涂层的第一温度下在反应器内聚合一种或多种烯烃。 在反应器内产生第二温度,并且从第一温度到第二温度测量温度变化率。 温度变化的速率与沉积在反应器内的聚合物涂层的厚度相关。

    Polymerization initated at sidewalls of carbon nanotubes
    9.
    发明授权
    Polymerization initated at sidewalls of carbon nanotubes 有权
    在碳纳米管的侧壁处开始聚合

    公开(公告)号:US07879940B2

    公开(公告)日:2011-02-01

    申请号:US10561253

    申请日:2004-06-21

    IPC分类号: B60C1/00 C08F4/46

    摘要: The present invention is directed to aryl halide (such as aryl bromide) functionalized carbon nanotubes that can be utilized in anionic polymerization processes to form polymer-carbon nanotube materials with improved dispersion ability in polymer matrices. In this process the aryl halide is reacted with an alkyllithium species or is reacted with a metal to replace the aryl-bromine bond with an aryl-lithium or aryl-metal bond, respectively. It has further been discovered that other functionalized carbon nanotubes, after deprotonation with a deprotonation agent, can similarly be utilized in anionic polymerization processes to form polymer-carbon nanotube materials. Additionally or alternatively, a ring opening polymerization process can be performed. The resultant materials can be used by themselves due to their enhanced strength and reinforcement ability when compared to their unbound polymer analogs. Additionally, these materials can also be blended with pre-formed polymers to establish compatibility and enhanced dispersion of nanotubes in otherwise hard to disperse matrices resulting in significantly improved material properties. The resultant polymer-carbon nanotube materials can also be used in drug delivery processes due to their improved dispersion ability and biodegradability, and can also be used for scaffolding to promote cellular growth of tissue.

    摘要翻译: 本发明涉及可用于阴离子聚合方法形成聚合物 - 碳纳米管材料的芳族卤化物(例如芳基溴)官能化碳纳米管,其具有改进的聚合物基质中的分散能力。 在该方法中,芳基卤化物与烷基锂物质反应,或与金属反应,分别用芳基 - 锂或芳基 - 金属键代替芳基 - 溴键。 还已经发现,其它官能化碳纳米管在去质子化脱质子化之后,可以类似地用于阴离子聚合方法中以形成聚合物 - 碳纳米管材料。 另外地或替代地,可以进行开环聚合过程。 所得材料由于与未结合的聚合物类似物相比具有增强的强度和增强能力,可以自己使用。 另外,这些材料也可以与预先形成的聚合物混合以建立纳米管在其它难分散的基质中的相容性和增强的分散,导致显着改善的材料性质。 所得到的聚合物 - 碳纳米管材料由于其改进的分散能力和生物降解性也可用于药物递送过程中,并且也可用于支架以促进组织的细胞生长。

    Carbon nanotube reinforced polymer nanocomposites
    10.
    发明申请
    Carbon nanotube reinforced polymer nanocomposites 有权
    碳纳米管增强聚合物纳米复合材料

    公开(公告)号:US20090030090A1

    公开(公告)日:2009-01-29

    申请号:US11659407

    申请日:2005-08-02

    摘要: The present invention is directed to carbon nanotube (CNT)/polymer composites, i.e., nanocomposites, wherein the CNTs in such nanocomposites are highly dispersed in a polymer matrix, and wherein the nanocomposites comprise a compatibilizing surfactant that interacts with both the CNTs and the polymer matrix. The present invention is also directed to methods of making these nanocomposites. In some such methods, the compatibilizing surfactant provides initial CNT dispersion and subsequent mixing with a polymer. The present invention is also directed to methods of using these nanocomposites in a variety of applications.

    摘要翻译: 本发明涉及碳纳米管(CNT)/聚合物复合材料,即纳米复合材料,其中这种纳米复合材料中的CNT被高度分散在聚合物基体中,并且其中纳米复合材料包含与CNT和聚合物相互作用的相容性表面活性剂 矩阵。 本发明还涉及制备这些纳米复合材料的方法。 在一些这样的方法中,相容性表面活性剂提供初始的CNT分散并随后与聚合物混合。 本发明还涉及在各种应用中使用这些纳米复合材料的方法。