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公开(公告)号：US20120142885A1
公开(公告)日：2012-06-07
申请号：US13305361
申请日：2011-11-28
CPC分类号： C09J175/06 , C08G18/10 , C08G18/12 , C08G18/4018 , C08G18/4202 , C08G18/4238 , C08G18/4833 , C08G2170/20 , C09J175/04 , C08G18/307
摘要： Provided is a moisture-curing hot melt adhesive, which has superior overall performance, including heat resistance, adhesiveness, and solidification performance, and with which there is no reduction in the resulting IC card quality or productivity. Also provided is an IC card obtained by applying such a moisture-curing hot melt adhesive. The moisture-curing hot melt adhesive for an IC card comprises a urethane prepolymer (A) having a chemical structure (A1) derived from a polyester polyol (a1) that has isocyanate groups at the terminals and that is obtained by reacting of a diol and a dicarboxylic acid having 10 carbons or fewer. The moisture-curing hot melt adhesive has a shear modulus with non-moisture curing that is between (1×104) and (1×108) Pa at 40° C. and between (1×100) and (1×104) at 80° C. An IC card can be ideally produced by bonding a decorative material and a substrate using the moisture-curing hot melt adhesive.
摘要翻译： 提供了具有优异的整体性能，包括耐热性，粘合性和凝固性能的湿固化热熔粘合剂，并且不会导致所得IC卡质量或生产率的降低。 还提供了通过应用这种湿固化热熔粘合剂获得的IC卡。 用于IC卡的湿固化热熔粘合剂包括具有衍生自末端具有异氰酸酯基的聚酯多元醇（a1）的化学结构（A1）的氨基甲酸酯预聚物（A），其通过二醇和 具有10个或更少碳原子的二羧酸。 湿润固化热熔粘合剂具有非湿度固化的剪切模量，在40℃和（1×100）和（1×104）之间在（1×10 4）和（1×10 8）Pa之间 80℃。通过使用湿固化热熔粘合剂将装饰材料和基材接合，可以理想地制造IC卡。
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公开(公告)号：US07176250B2
公开(公告)日：2007-02-13
申请号：US10799734
申请日：2004-03-15
申请人： Akihiko Asakawa , Masaru Yamauchi
发明人： Akihiko Asakawa , Masaru Yamauchi
IPC分类号： C08J3/12
CPC分类号： C09D127/12 , C08L27/12 , C08L27/16 , C08L29/10 , C08L33/08 , C08L33/12 , C08L2205/02 , C09D129/10 , C08L2666/04
摘要： A non-vinylidene fluororesin powder coating material having blocking resistance and high impact resistance, is provided. A fluororesin powder coating composition comprising a non-vinylidene fluororesin having a Tg higher than 40° C. and a resin having a Tg of from 0 to 40° C.
摘要翻译： 提供了具有抗粘连性和高耐冲击性的非亚乙烯基氟树脂粉末涂料。 一种氟树脂粉末涂料组合物，其包含Tg高于40℃的Tg的Tg为0〜40℃的非亚乙烯基氟树脂。
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公开(公告)号：US07153907B2
公开(公告)日：2006-12-26
申请号：US10806103
申请日：2004-03-23
申请人： Akihiko Asakawa , Masaru Yamauchi , Sho Masuda , Masao Unoki
发明人： Akihiko Asakawa , Masaru Yamauchi , Sho Masuda , Masao Unoki
IPC分类号： C08F8/30
CPC分类号： C09D127/12 , C08L27/12 , C08L2205/02 , C08L2666/04
摘要： A composition for fluororesin powder coating material, with which a coating film having an excellent matte effect is obtainable without impairing features of fluororesins including excellent weather resistance, and a process for its production, are presented. The composition for fluororesin powder coating material comprises at least two curing systems each comprising a fluororesin having crosslinkable sites and a curing agent reactive to the crosslinkable sites, wherein the respective curing systems substantially independently react and crosslink, and the crosslinking reaction time of one curing system is different by at least 20 seconds from the crosslinking reaction time of other curing system(s).
摘要翻译： 提供了一种用于氟树脂粉末涂料的组合物，其具有优异的无光泽效果的涂膜，而不损害包括耐候性优异的氟树脂的特征及其制备方法。 用于氟树脂粉末涂料的组合物包含至少两种固化体系，每种固化体系包含具有可交联部位的氟树脂和与可交联部位反应的固化剂，其中相应的固化体系基本上独立地反应和交联，并且一种固化体系的交联反应时间 与其它固化体系的交联反应时间不同至少20秒。
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4.发明申请RELEASE FILM, RELEASABLE CUSHION MATERIAL AND PROCESS FOR PRODUCING PRINTED BOARD 失效释放膜，可释放的垫片材料和生产印刷板的工艺公开(公告)号：US20090042038A1
公开(公告)日：2009-02-12
申请号：US12245139
申请日：2008-10-03
申请人： Tamao Okuya , Hiroshi Aruga , Masaru Yamauchi
发明人： Tamao Okuya , Hiroshi Aruga , Masaru Yamauchi
CPC分类号： H05K3/281 , B30B15/061 , Y10T156/10 , Y10T428/265 , Y10T428/3154 , Y10T428/31663
摘要： To provide a release film which does not need to be changed often for hot press and is easy to be changed; a releasable cushion material which can reduce the frequency of changing a cushion material main body; and a process for producing a printed board with good productivity and low cost.A release film 10 which is to be provided on a surface of a cushion material made of silicone rubber, and which has a layer 14 containing Si on one side of a substrate 12 made of a fluororesin; a releasable cushion material wherein the release film is provided on a surface of the cushion material made of silicone rubber so that the layer containing Si is located on the cushion material side; and a process for producing a printed board wherein, when a laminate of a printed board main body and coverlay films is subjected to hot press as sandwiched between press boards, the release film is disposed on a surface of the cushion material of the coverlay film side so that the layer containing Si is located on the cushion material side.
摘要翻译： 为了提供热压机不需要经常更换并易于更换的脱模膜; 可释放的缓冲材料，其可以降低改变衬垫材料主体的频率; 以及生产率高，成本低的印刷电路板的制造方法。 一种剥离膜10，其设置在由硅橡胶制成的衬垫材料的表面上，并且在由氟树脂制成的衬底12的一侧上具有含有Si的层14; 一种可释放的衬垫材料，其中所述脱模膜设置在由硅橡胶制成的衬垫材料的表面上，使得含有Si的层位于所述衬垫材料侧上; 以及印刷电路板的制造方法，其中，当将印刷电路板主体和覆盖膜的叠层体夹在压板之间进行热压时，将剥离膜设置在覆盖膜侧的缓冲材料的表面上 使得含有Si的层位于缓冲材料侧。
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公开(公告)号：US20070243373A1
公开(公告)日：2007-10-18
申请号：US11697864
申请日：2007-04-09
申请人： Takuya Nakao , Masaru Yamauchi , Tutomu Fusyuku
发明人： Takuya Nakao , Masaru Yamauchi , Tutomu Fusyuku
CPC分类号： C08J7/045 , C08J5/22 , C08J2327/12 , Y10T428/269 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： A film for a membrane structure, which comprises a film substrate containing a fluororesin, a photocatalyst layer and an interlayer interposed between the film substrate and the photocatalyst layer, wherein the fluororesin is at least one member selected from the group consisting of an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/hexafluoropropylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, a polyvinyl fluoride and a polyvinylidene fluoride; the interlayer contains an organic-inorganic hybrid polymer obtained by hydrolyzing/co-condensing at least one member selected from the group consisting of an organosilane, a hydrolysate of an organosilane and a condensate of an organosilane, and a silyl group-containing organic polymer; and the mass remaining ratio of the organic-inorganic hybrid polymer is from 50 to 80% at 500° C. measured by thermogravimetric analysis.
摘要翻译： 一种用于膜结构的膜，其包含含有氟树脂的薄膜基材，光催化剂层和插入在所述薄膜基材和所述光催化剂层之间的夹层，其中所述氟树脂是选自乙烯/四氟乙烯 共聚物，四氟乙烯/六氟丙烯共聚物，四氟乙烯/全氟（烷基乙烯基醚）共聚物，聚氟乙烯和聚偏二氟乙烯; 中间层包含通过水解/共缩合从有机硅烷，有机硅烷的水解产物和有机硅烷的缩合物和含甲硅烷基的有机聚合物中选择的至少一种而获得的有机 - 无机杂化聚合物; 有机无机杂化聚合物的质量剩余率在500℃下为50〜80％，通过热重分析法测定。
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6.发明授权Processes for producing a fluororesin powder having curable functional groups and its coating composition 有权制备具有可固化官能团的氟树脂粉末及其涂料组合物的方法公开(公告)号：US07144948B2
公开(公告)日：2006-12-05
申请号：US10863506
申请日：2004-06-09
申请人： Masaru Yamauchi , Toru Ishida
发明人： Masaru Yamauchi , Toru Ishida
IPC分类号： C08L23/18
CPC分类号： C09D175/04 , C08F6/10 , C08G18/0895 , C08G18/6279 , C08G18/8074 , C08G2150/20 , C08K5/0008 , C08K5/13 , C08K5/1515 , C08K5/3435 , C08K5/524 , C09D127/12 , C08L27/12
摘要： It is to provide a production process by which gelation can be prevented, in a case where a solvent is removed from a curable fluororesin to obtain a chief material resin, and then coating additives such as a curing agent are mixed to produce a powder coating composition, or in a case where a curable fluororesin, a curing agent and various additives are dissolved or dispersed in a solvent to prepare a raw material solution, and the solvent is removed from the raw material solution to directly produce a powder coating material.To a solution or dispersion of a curable fluorinated copolymer (A), a gelation inhibitor (B) is added, followed by mixing, or a gelation inhibitor (B), a curing agent (C) and as the case requires, various additives (D) are added, followed by mixing, and the solution or dispersion is supplied to a thin-film vacuum evaporator to remove the solvent.
摘要翻译： 在提供可固化氟树脂去除溶剂以获得主要材料树脂的情况下，提供可以防止凝胶化的生产方法，然后混合诸如固化剂的涂料添加剂以制备粉末涂料组合物 或者在可固化的氟树脂，固化剂和各种添加剂溶解或分散在溶剂中以制备原料溶液的情况下，并且从原料溶液中除去溶剂以直接生产粉末涂料。 向可固化的含氟共聚物（A）的溶液或分散体中加入凝胶抑制剂（B），然后混合，或凝胶抑制剂（B），固化剂（C）和根据需要的各种添加剂 D），然后混合，将溶液或分散体供给到薄膜真空蒸发器中以除去溶剂。
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公开(公告)号：US07732045B2
公开(公告)日：2010-06-08
申请号：US11697864
申请日：2007-04-09
申请人： Takuya Nakao , Masaru Yamauchi , Tutomu Fusyuku
发明人： Takuya Nakao , Masaru Yamauchi , Tutomu Fusyuku
CPC分类号： C08J7/045 , C08J5/22 , C08J2327/12 , Y10T428/269 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： A film for a membrane structure, which comprises a film substrate containing a fluororesin, a photocatalyst layer and an interlayer interposed between the film substrate and the photocatalyst layer, wherein the fluororesin is at least one member selected from the group consisting of an ethylene/tetrafluoroethylene copolymer, a tetrafluoroethylene/hexafluoropropylene copolymer, a tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, a polyvinyl fluoride and a polyvinylidene fluoride; the interlayer contains an organic-inorganic hybrid polymer obtained by hydrolyzing/co-condensing at least one member selected from the group consisting of an organosilane, a hydrolysate of an organosilane and a condensate of an organosilane, and a silyl group-containing organic polymer; and the mass remaining ratio of the organic-inorganic hybrid polymer is from 50 to 80% at 500° C. measured by thermogravimetric analysis.
摘要翻译： 一种用于膜结构的膜，其包含含有氟树脂的薄膜基材，光催化剂层和插入在所述薄膜基材和所述光催化剂层之间的夹层，其中所述氟树脂是选自乙烯/四氟乙烯 共聚物，四氟乙烯/六氟丙烯共聚物，四氟乙烯/全氟（烷基乙烯基醚）共聚物，聚氟乙烯和聚偏二氟乙烯; 中间层包含通过水解/共缩合从有机硅烷，有机硅烷的水解产物和有机硅烷的缩合物和含甲硅烷基的有机聚合物中选择的至少一种而获得的有机 - 无机杂化聚合物; 有机无机杂化聚合物的质量剩余率在500℃下为50〜80％，通过热重分析法测定。
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公开(公告)号：US07361717B2
公开(公告)日：2008-04-22
申请号：US11167304
申请日：2005-06-28
申请人： Shigeru Aida , Masaru Yamauchi , Hiroshi Aruga
发明人： Shigeru Aida , Masaru Yamauchi , Hiroshi Aruga
IPC分类号： C08F16/24
CPC分类号： C08F214/265 , C08F214/26 , C08J5/00 , C08J2327/12
摘要： A fluorocopolymer film formed by molding at a molding temperature of at most 320° C. a fluorocopolymer comprising repeating units based on ethylene, repeating units based on tetrafluoroethylene, repeating units based on hexafluoropropylene and repeating units based on a fluoroalkyl vinyl ether represented by CF2═CFORf (wherein Rf represents a C1-10 fluoroalkyl group), having a molar ratio of the repeating units based on ethylene/the repeating units based on tetrafluoroethylene of from 10/90 to 60/40, a content of the repeating units based on hexafluoropropylene to the total repeating units of from 0.1 to 20 mol % and a content of the fluoroalkyl vinyl ether to the total repeating units of from 0.1 to 10 mol %, and having a volumetric flow rate of from 0.1 to 30 mm3/sec at 297° C.
摘要翻译： 一种含氟共聚物膜，其通过在至多320℃的成型温度下模塑而成，包含基于乙烯的重复单元，基于四氟乙烯的重复单元，基于六氟丙烯的重复单元和基于CF 3表示的氟烷基乙烯基醚的重复单元的含氟共聚物， （其中R f表示C 1-10烷基），其摩尔比为 基于乙烯的重复单元/基于四氟乙烯的重复单元为10/90至60/40，基于六氟丙烯的重复单元与总重复单元的含量为0.1至20摩尔％，氟代烷基的含量 乙烯基醚至总重复单元为0.1至10摩尔％，并且在297℃下的体积流速为0.1至30毫米3 /秒。
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9.发明授权
公开(公告)号：US5510406A
公开(公告)日：1996-04-23
申请号：US240504
申请日：1994-05-09
IPC分类号： C09D137/00 , C09D145/00 , C09D147/00 , C08K5/17
CPC分类号： C09D147/00 , C09D137/00 , C09D145/00
摘要： A fluoropolymer composition for coating, which comprises a polymer having a fluorine-containing cycloaliphatic structure and at least one coupling group in its molecule and a solvent for dissolving said polymer.
摘要翻译： 一种用于涂层的含氟聚合物组合物，其包含在其分子中具有含氟脂环族结构和至少一个偶联基团的聚合物和用于溶解所述聚合物的溶剂。
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10.发明授权Release film, releasable cushion material and process for producing printed board 失效剥离膜，可释放缓冲材料和印刷板生产工艺公开(公告)号：US07754326B2
公开(公告)日：2010-07-13
申请号：US12245139
申请日：2008-10-03
申请人： Tamao Okuya , Hiroshi Aruga , Masaru Yamauchi
发明人： Tamao Okuya , Hiroshi Aruga , Masaru Yamauchi
CPC分类号： H05K3/281 , B30B15/061 , Y10T156/10 , Y10T428/265 , Y10T428/3154 , Y10T428/31663
摘要： To provide a release film which does not need to be changed often for hot press and is easy to be changed; a releasable cushion material which can reduce the frequency of changing a cushion material main body; and a process for producing a printed board with good productivity and low cost.A release film 10 which is to be provided on a surface of a cushion material made of silicone rubber, and which has a layer 14 containing Si on one side of a substrate 12 made of a fluororesin; a releasable cushion material wherein the release film is provided on a surface of the cushion material made of silicone rubber so that the layer containing Si is located on the cushion material side; and a process for producing a printed board wherein, when a laminate of a printed board main body and coverlay films is subjected to hot press as sandwiched between press boards, the release film is disposed on a surface of the cushion material of the coverlay film side so that the layer containing Si is located on the cushion material side.
摘要翻译： 为了提供热压机不需要经常更换并易于更换的脱模膜; 可释放的缓冲材料，其可以降低改变衬垫材料主体的频率; 以及生产率高，成本低的印刷电路板的制造方法。 一种剥离膜10，其设置在由硅橡胶制成的衬垫材料的表面上，并且在由氟树脂制成的衬底12的一侧上具有含有Si的层14; 一种可释放的衬垫材料，其中所述脱模膜设置在由硅橡胶制成的衬垫材料的表面上，使得含有Si的层位于所述衬垫材料侧上; 以及印刷电路板的制造方法，其中，当将印刷电路板主体和覆盖膜的叠层体夹在压板之间进行热压时，将剥离膜设置在覆盖膜侧的缓冲材料的表面上 使得含有Si的层位于缓冲材料侧。
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