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公开(公告)号:US09567413B2
公开(公告)日:2017-02-14
申请号:US13876986
申请日:2011-09-30
申请人: Yuji Imahori , Mayumi Iida , Katsuhiko Imoto
发明人: Yuji Imahori , Mayumi Iida , Katsuhiko Imoto
IPC分类号: C08F14/26 , C08F214/26 , C08F214/18 , C08F2/26
CPC分类号: C08F14/26 , C08F2/26 , C08F214/18 , C08F214/186 , C08F214/188 , C08F214/26 , C08F214/267 , C08F14/18 , C08F2/16 , C08F216/165 , C08F220/04 , C08F218/08 , C08F216/1416
摘要: Provided is a method for producing a fluoropolymer in the presence of a specific non-fluorinated compound having surface activity. The method shows a high polymerization rate, and suppresses formation of sticking polymerization materials after production of a polymer product. The method includes aqueous dispersion polymerization of a fluoroolefin in the presence of a compound (1) represented by formula (1): wherein R1 and R2 are the same as or different from each other, and each represent a C4 to C12 non-fluorinated saturated hydrocarbon group; and M is an alkali metal, an ammonium salt, or an amine salt.
摘要翻译: 其中R1和R2彼此相同或不同,并且各自表示C4-C12非氟化饱和烃基; M是碱金属,铵盐或胺盐。
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公开(公告)号:US20140018492A1
公开(公告)日:2014-01-16
申请号:US14008259
申请日:2012-03-30
申请人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
发明人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
IPC分类号: C09D127/18 , C08F218/08 , C08F214/26 , C09D131/04
CPC分类号: C09D127/18 , C08F214/18 , C08F214/186 , C08F214/267 , C08F216/1416 , C08F218/08 , C08F220/64 , C09D127/12 , C09D131/04
摘要: Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2═CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C═CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.
摘要翻译: 提供一种涂料组合物,其能够赋予具有优异的拉伸性并且还具有优异的耐污染性的涂层。 溶剂型涂料组合物包含含氟共聚物(I)和有机溶剂(II),含氟共聚物(I)包括:含有两个碳原子的全卤代烯烃结构单元(a),乙酸乙烯酯结构单元(b), 由下式(1)表示的含羟基的乙烯基单体结构单元(c):CH2 = CH-O-(CH2)n-OH其中n为2以上的整数,含羧基的单体 由下式(2)表示的结构单元(d):R1R2C = CR3-(CH2)m-COOH其中R1,R2和R3彼此相同或不同,并且各自为氢原子或C1- C10直链或支链烷基; m为2以上的整数。
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公开(公告)号:US09187589B2
公开(公告)日:2015-11-17
申请号:US13638495
申请日:2011-03-30
申请人: Yuji Imahori , Katsuhiko Imoto
发明人: Yuji Imahori , Katsuhiko Imoto
IPC分类号: C08F214/18 , C08F214/26
CPC分类号: C08F214/265 , C08F214/18 , C08F214/182 , C08F214/184 , C08F214/186 , C08F214/188
摘要: The present invention provides a novel copolymer of 2,3,3,3-tetrafluoropropene and a non-fluorinated ethylenic hydrocarbon monomer. The copolymer contains (A) a 2,3,3,3-tetrafluoropropene unit and (B) a non-fluorinated ethylenic hydrocarbon monomer unit. The copolymerization ratio (mol % ratio) of (A) and (B) is 99.9:0.1 to 0.1:99.9 and the number average molecular weight of the copolymer is 1000 to 1000000.
摘要翻译: 本发明提供2,3,3,3-四氟丙烯与非氟化烯烃单体的新型共聚物。 共聚物含有(A)2,3,3,3-四氟丙烯单元和(B)非氟化烯烃单体单元。 (A)和(B)的共聚比(摩尔%比)为99.9:0.1〜0.1:99.9,共聚物的数均分子量为1000〜1000000。
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公开(公告)号:US20130203950A1
公开(公告)日:2013-08-08
申请号:US13876986
申请日:2011-09-30
申请人: Yuji Imahori , Mayumi Iida , Katsuhiko Imoto
发明人: Yuji Imahori , Mayumi Iida , Katsuhiko Imoto
IPC分类号: C08F14/26
CPC分类号: C08F14/26 , C08F2/26 , C08F214/18 , C08F214/186 , C08F214/188 , C08F214/26 , C08F214/267 , C08F14/18 , C08F2/16 , C08F216/165 , C08F220/04 , C08F218/08 , C08F216/1416
摘要: Provided is a method for producing a fluoropolymer in the presence of a specific non-fluorinated compound having surface activity. The method shows a high polymerization rate, and suppresses formation of sticking polymerization materials after production of a polymer product. The method includes aqueous dispersion polymerization of a fluoroolefin in the presence of a compound (1) represented by formula (1): wherein R1 and R2 are the same as or different from each other, and each represent a C4 to C12 non-fluorinated saturated hydrocarbon group; and M is an alkali metal, an ammonium salt, or an amine salt.
摘要翻译: 提供了在具有表面活性的特定非氟化物的存在下制造含氟聚合物的方法。 该方法显示出高聚合速率,并且抑制聚合物产物生成后的粘着聚合材料的形成。 该方法包括在由式(1)表示的化合物(1)存在下氟代烯烃的水分散聚合:其中R1和R2彼此相同或不同,并且各自表示C4至C12非氟化饱和 烃基; M是碱金属,铵盐或胺盐。
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公开(公告)号:US20130023636A1
公开(公告)日:2013-01-24
申请号:US13638495
申请日:2011-03-30
申请人: Yuji Imahori , Katsuhiko Imoto
发明人: Yuji Imahori , Katsuhiko Imoto
IPC分类号: C08F216/20 , C08F214/18 , C08F220/10
CPC分类号: C08F214/265 , C08F214/18 , C08F214/182 , C08F214/184 , C08F214/186 , C08F214/188
摘要: The present invention provides a novel copolymer of 2,3,3,3-tetrafluoropropene and a non-fluorinated ethylenic hydrocarbon monomer. The copolymer contains (A) a 2,3,3,3-tetrafluoropropene unit and (B) a non-fluorinated ethylenic hydrocarbon monomer unit. The copolymerization ratio (mol % ratio) of (A) and (B) is 99.9:0.1 to 0.1:99.9 and the number average molecular weight of the copolymer is 1000 to 1000000.
摘要翻译: 本发明提供2,3,3,3-四氟丙烯与非氟化烯烃单体的新型共聚物。 共聚物含有(A)2,3,3,3-四氟丙烯单元和(B)非氟化烯烃单体单元。 (A)和(B)的共聚比(摩尔%比)为99.9:0.1〜0.1:99.9,共聚物的数均分子量为1000〜1000000。
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公开(公告)号:US09920214B2
公开(公告)日:2018-03-20
申请号:US14008259
申请日:2012-03-30
申请人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
发明人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe , Akiko Ohya
IPC分类号: C09D127/18 , C09D127/12 , C08F214/18 , C09D131/04 , C08F214/26 , C08F218/08 , C08F220/64 , C08F216/14
CPC分类号: C09D127/18 , C08F214/18 , C08F214/186 , C08F214/267 , C08F216/1416 , C08F218/08 , C08F220/64 , C09D127/12 , C09D131/04
摘要: Provided is a paint composition which can give a coating having excellent stretchability and further having excellent contamination resistance. A solvent-based paint composition comprises a fluorocopolymer (I), and an organic solvent (II), the fluorocopolymer (I) including: a perhaloolefin structural unit (a) that contains two carbon atoms, a vinyl acetate structural unit (b), a hydroxyl group-containing vinyl monomer structural unit (c) represented by the following formula (1): CH2═CH—O—(CH2)n—OH wherein n is an integer of 2 or more, and a carboxyl group-containing monomer structural unit (d) represented by the following formula (2): R1R2C═CR3—(CH2)m—COOH wherein R1, R2, and R3 are the same as or different from one another, and each a hydrogen atom or a C1-C10 linear or branched alkyl group; and m is an integer of 2 or more.
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公开(公告)号:US20150240012A1
公开(公告)日:2015-08-27
申请号:US14008617
申请日:2012-03-28
申请人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
发明人: Yuji Imahori , Hirotoshi Yoshida , Mayumi Iida , Kengo Ito , Yoshito Tanaka , Katsuhiko Imoto , Takuma Kawabe
IPC分类号: C08F218/08
CPC分类号: C08F218/08 , C08F2/26 , C08F14/18 , C08F214/00 , C08F214/182 , C08F214/186 , C08F214/188 , C08F214/24 , C08F214/245 , C08F214/26 , C08F214/265 , C08F14/26
摘要: The present invention provides a method for producing a copolymer containing a perhaloolefin and vinyl acetate by a novel emulsion polymerization method. The present invention relates to a method for producing a perhaloolefin-vinyl acetate copolymer by emulsion polymerization of at least a perhaloolefin having two carbon atoms and vinyl acetate in the presence of a hydrocarbon emulsifier or in the absence of an emulsifier, provided that the hydrocarbon emulsifier excludes a compound (1) represented by the formula (1): wherein R1 and R2 are the same as or different from each other and each represent a C4 to 12 unfluorinated saturated hydrocarbon group; M represents an alkali metal, an ammonium salt, or an amine salt.
摘要翻译: 本发明提供一种通过新的乳液聚合法制备含有全卤代烯烃和乙酸乙烯酯的共聚物的方法。 本发明涉及一种通过在烃类乳化剂的存在下或不存在乳化剂的情况下通过至少具有两个碳原子的全卤代烯烃和乙酸乙烯酯的乳液聚合制备全卤代烯烃 - 乙酸乙烯酯共聚物的方法,条件是烃类乳化剂 不包括由式(1)表示的化合物(1):其中R1和R2彼此相同或不同,并且各自表示C4至12个未氟饱和烃基; M表示碱金属,铵盐或胺盐。
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公开(公告)号:US20140221556A1
公开(公告)日:2014-08-07
申请号:US14347516
申请日:2012-09-14
申请人: Shumi Yoshida , Katsuhiko Imoto
发明人: Shumi Yoshida , Katsuhiko Imoto
IPC分类号: C09D127/16 , C08L27/16
CPC分类号: C09D127/16 , C08F2/22 , C08F14/22 , C08F214/222 , C08F220/06 , C08F220/18 , C08F259/08 , C08L27/16 , C09D133/02 , C09D133/16 , C08L33/12 , C08F220/02
摘要: The present invention aims to provide an aqueous dispersion capable of forming a coating film that has excellent adhesion to a substrate and excellent water resistance. The aqueous dispersion of the present invention includes fluorine-containing composite polymer particles of a polymer (A) with a repeating unit of vinylidene fluoride and a polymer (B) with a repeating unit of at least one acrylic monomer selected from the group consisting of acrylic acid, acrylic acid esters, methacrylic acid, and methacrylic acid esters, the dispersion having an acid value of at least 3 mgKOH/g.
摘要翻译: 本发明旨在提供一种能够形成对基材具有优异粘合性和优异的耐水性的涂膜的水性分散体。 本发明的水性分散体包括具有偏二氟乙烯重复单元的聚合物(A)和聚合物(B)的含氟复合聚合物颗粒,所述聚合物(B)具有选自丙烯酸类的至少一种丙烯酸类单体的重复单元 酸,丙烯酸酯,甲基丙烯酸和甲基丙烯酸酯,该分散体的酸值至少为3mgKOH / g。
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公开(公告)号:US08026313B2
公开(公告)日:2011-09-27
申请号:US12514935
申请日:2007-12-06
申请人: Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
发明人: Katsuhiko Imoto , Tetsuo Shimizu , Masayuki Hayashi , Tomohiro Iimura , Eiji Kitaura , Peter Cheshire Hupfield
IPC分类号: C08L9/00 , C08L27/12 , C08L29/00 , C08L31/00 , C08L33/02 , C08L33/04 , C08L35/02 , C08L45/00
CPC分类号: C08L27/16 , C08L27/14 , C08L33/04 , C08L2666/04
摘要: A curable polymer composition that is quickly curable to form a cured article having excellent adhesion and followability to a substrate and at least including (A) an acrylic copolymer having a hydrogen atom bonded to a silicon atom, (B) a compound having at least two aliphatic unsaturated bonds in one molecule thereof, (C) a fluoroolefin copolymer including vinylidene fluoride as main component, and (D) a catalyst for hydrosilylation reaction.
摘要翻译: 一种可固化的聚合物组合物,其可快速固化以形成具有优异的粘合性和对基材的追随性的固化制品,并且至少包括(A)具有与硅原子键合的氢原子的丙烯酸共聚物,(B)具有至少两个 一个分子中的脂族不饱和键,(C)以偏氟乙烯为主成分的氟烯烃共聚物,(D)氢化硅烷化反应用催化剂。
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公开(公告)号:US06359030B1
公开(公告)日:2002-03-19
申请号:US09529984
申请日:2000-04-24
IPC分类号: C08L8300
CPC分类号: C09D127/16 , C08L33/12 , C08L2666/04
摘要: An aqueous-dispersing composition of synthetic resin (A) having an intrinsic viscosity “&eegr;” of from 0.3 to 2.0 measured at 35° C. in a methyl ethyl ketone solvent or a mixture of that aqueous dispersion and an aqueous dispersion of synthetic resin (B) having an intrinsic viscosity “&eegr;” of not less than 0.6 which is larger by 0.3 or more than the intrinsic viscosity “&eegr;” of the synthetic resin (A) when the intrinsic viscosity is measured at 35° C. in a methyl ethyl ketone solvent. The aqueous-dispersing composition and the mixture have improved film forming property and can give a coating film being excellent in chemical resistance, water resistance, mechanical properties and further hot water resistance.
摘要翻译: 在甲基乙基酮溶剂或该水性分散体与合成树脂的水分散体的混合物中,在35℃下测定的特性粘度“η”为0.3〜2.0的合成树脂(A)的水分散组合物( B),特性粘度“η”不小于0.6,当特性粘度在35℃下在甲基乙基中测定时,该特性粘度“η”大于合成树脂(A)的特性粘度“eta” 酮溶剂。 水性分散组合物和混合物具有改进的成膜性,并且可以得到耐化学性,耐水性,机械性能和耐热水性更好的涂膜。
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