公开(公告)号：US20080103203A1

公开(公告)日：2008-05-01

申请号：US11976565

申请日：2007-10-25

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Yuki Okamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Yuki Okamoto

IPC分类号： A61K31/201 ,  A61K47/04 ,  A61K47/12 ,  A61P31/10

CPC分类号： A61K8/361 ,  A01N37/02 ,  A01N37/06 ,  A01N59/00 ,  A61K8/19 ,  A61Q17/005 ,  A61Q19/10 ,  A01N25/30 ,  A01N2300/00

摘要： The skin disinfectant, which is able to sterilize skin by the action of a surfactant without damaging skin health conditions, contains water, from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. The surfactant is, for example, a fatty acid salt. When the skin disinfectant is applied onto skin, fungi and bacteria adhered or parasitic onto skin is sterilized by the action of the surfactant. At this time, the surfactant is not likely to give an irritation to skin due to the action of the water, from which polyvalent cations are removed and to which a sodium ion is added, and thus the skin health conditions tend not to be damaged. Accordingly, the skin disinfectant is useful as a remedy for, for example, a ringworm infectious disease.

摘要翻译： 能够通过表面活性剂的作用对皮肤进行消毒而不损害皮肤健康状况的皮肤消毒剂含有除去多价阳离子并加入钠离子的水和表面活性剂的水。 表面活性剂是例如脂肪酸盐。 当将皮肤消毒剂施用到皮肤上时，通过表面活性剂的作用对附​​着或寄生在皮肤上的真菌和细菌进行灭菌。 此时，由于除去多价阳离子并添加了钠离子的水的作用，表面活性剂不易对皮肤产生刺激，因此皮肤健康状况往往不被损坏。 因此，皮肤消毒剂可用作例如癣感染性疾病的补救措施。

公开(公告)号：US20080103079A1

公开(公告)日：2008-05-01

申请号：US11976416

申请日：2007-10-24

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto ,  Yuki Okamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto ,  Yuki Okamoto

IPC分类号： C11D17/00

CPC分类号： C11D3/046 ,  A61K8/19 ,  A61K8/361 ,  A61Q19/10

摘要： The cleaning agent, which is less likely to retain a surfactant on an object to be cleaned and not to restrict applicable objects to be cleaned, contains water from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. An example of the surfactant is a fatty acid salt. When the cleaning agent is applied to an object to be cleaned, stain adhered on the object is removed from the object by action of the surfactant. The surfactant hardly remains on the object due to the action of the water from which polyvalent cations are removed and to which a sodium ion is added. Accordingly, the cleaning agent can effectively wash a wide variety of objects, such as kitchens, tableware, food, washstands, bathrooms, toilets, vehicles, clothes and body skin, without damaging texture and deteriorating quality.

摘要翻译： 不易于将待清洁物体保持表面活性剂并且不限制可清洁物体的清洁剂含有除去多价阳离子并添加了钠离子的水和表面活性剂。 表面活性剂的实例是脂肪酸盐。 当将清洁剂施加到待清洁的物体上时，通过表面活性剂的作用将附着在物体上的污渍从物体上除去。 由于去除了多价阳离子的水的作用并且添加了钠离子，表面活性剂几乎不残留在物体上。 因此，清洁剂可以有效地洗涤诸如厨房，餐具，食品，洗手盆，浴室，卫生间，车辆，衣服和身体皮肤的各种物品，而不会损坏质地和劣化质量。

公开(公告)号：US20080058242A1

公开(公告)日：2008-03-06

申请号：US11892769

申请日：2007-08-27

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori ,  Daisuke Yamamoto

IPC分类号： C11D17/08

CPC分类号： C11D7/10

摘要： The cleaning fluid, which is easily mass-produced, low priced, and safe and is also free from chemical substances contains water from which polyvalent cations are removed and to which sodium ions are added. When the cleaning fluid is applied to an object to be cleaned, stain adhered onto the object can be removed by action of the water. The object washed with the cleaning fluid is free from remnant of chemical substances, as is often not the case when washed with a cleaning fluid using chemical-substances such as a surfactant, and is therefore safe. Furthermore, since water stain or scale hardly remains on the object washed, new stain is not easily attached. Accordingly, the cleaning fluid is particularly effective when it is used as a cleaning fluid for kitchen sinks, tableware, foods, washstands, bathrooms, toilets, vehicles and clothes.

摘要翻译： 容易批量生产，低价格且安全且不含化学物质的清洗液含有从其中除去多价阳离子并加入钠离子的水。 当将清洁流体施加到待清洁物体上时，通过水的作用可以去除粘附到物体上的污渍。 用清洗液清洗的物体没有残留的化学物质，因为使用化学物质如表面活性剂用清洁液洗涤时通常不是这种情况，因此是安全的。 此外，由于洗涤物体上几乎不残留有水渍或鳞屑，所以新的污渍不容易附着。 因此，当清洗液被用作厨房水槽，餐具，食品，洗手盆，浴室，卫生间，车辆和衣物的清洁液时，清洁液特别有效。

公开(公告)号：US20080057139A1

公开(公告)日：2008-03-06

申请号：US11892784

申请日：2007-08-27

申请人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori

发明人： Yuji Yoshinari ,  Masaki Takai ,  Makoto Hatori

IPC分类号： A61K33/00 ,  A61P17/00 ,  A61Q19/00

CPC分类号： A61Q19/007 ,  A61K8/19 ,  A61K9/08 ,  A61K33/00 ,  A61K47/02 ,  A61Q19/00 ,  A61K2300/00

摘要： The skin-care water, which is able to safely improve skin health conditions, such as dry skin, contains water from which polyvalent cations are removed and to which sodium ions are added, and may contain fragrant materials according to need. When the skin-care water is applied to skin, for example, by means of taking a bath, it improves moisture retention of skin, moisture content of skin, elasticity, texture density and the like without providing side effects, as is often not the case when a skin-care water containing chemical substances is used. Accordingly, the skin-care water is useful as a moisturizing agent for skin, and an improving agent for dry skin, itchy feeling, skin scale and atopic dermatitis.

摘要翻译： 能够安全地改善皮肤健康状况（例如皮肤干燥）的护肤水含有从其中除去多价阳离子并加入钠离子的水，并且可以根据需要含有芳香物质。 当皮肤护理用水例如通过洗澡时，可以改善皮肤的保湿性，皮肤含水量，弹性，质地密度等，而不会产生副作用 当使用含有化学物质的护肤水时。 因此，护肤水可用作皮肤的保湿剂，以及用于干性皮肤，瘙痒感，皮肤鳞片和特应性皮炎的改善剂。

公开(公告)号：US20080076822A1

公开(公告)日：2008-03-27

申请号：US11898147

申请日：2007-09-10

申请人： Yuji Yoshinari ,  Masaki Takai ,  Yuki Okamoto ,  Tomomi Fujimura

发明人： Yuji Yoshinari ,  Masaki Takai ,  Yuki Okamoto ,  Tomomi Fujimura

IPC分类号： A01N37/00 ,  A01N25/02 ,  A01P1/00

CPC分类号： A01N37/06 ,  A01N37/02

摘要： The disinfectant capable of realizing effective sterilization by using a surfactant contains water, from which polyvalent cations are removed and to which a sodium ion is added, and a surfactant. An example of the surfactant is a fatty acid salt. When the disinfectant is applied to an object to be treated, fungi and bacteria adhering thereto are sterilized by the action of the surfactant. The surfactant contained in the disinfectant hardly remains on the object owing to the effect of the water from which polyvalent cations are removed and to which a sodium ion is added, and then is not likely to be a source of nutrient for fungi and bacteria. Accordingly, on the object to which the disinfectant is applied, fungi and bacteria are sterilized and propagation thereof is suppressed, and thus a hygienic state of the object is easily maintained. The disinfectant is particularly effective when it is used for, for example, bathrooms, tabs of washing machines, kitchens, toilets, washstands, drainpipes and daily commodities.

摘要翻译： 能够通过使用表面活性剂实现有效灭菌的消毒剂含有除去多价阳离子并加入钠离子的水和表面活性剂。 表面活性剂的实例是脂肪酸盐。 当将消毒剂施用于待处理物体时，附着于其上的真菌和细菌通过表面活性剂的作用而灭菌。 由于消除了多价阳离子的水的作用并且添加了钠离子，因此消毒剂中所含的表面活性剂几乎不残留在物体上，因此不可能是真菌和细菌的营养源。 因此，在使用消毒剂的物体上，真菌和细菌被灭菌并且抑制其传播，从而容易地保持物体的卫生状态。 当消毒剂用于例如浴室，洗衣机，厨房，卫生间，洗手盆，排水管和日常商品的标签时，消毒剂特别有效。

公开(公告)号：US20060106181A1

公开(公告)日：2006-05-18

申请号：US11300290

申请日：2005-12-15

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C08F20/10 ,  C07C69/52

CPC分类号： C07C41/16 ,  C07C67/10 ,  Y02P20/582 ,  C07C69/78 ,  C07C43/215 ,  C07C43/15 ,  C07C43/1785 ,  C07C43/23

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

公开(公告)号：US5936130A

公开(公告)日：1999-08-10

申请号：US926481

申请日：1997-09-10

申请人： Tomoyuki Mori ,  Masaki Takai ,  Tomohiko Inoue ,  Kazuyuki Yokoyama

发明人： Tomoyuki Mori ,  Masaki Takai ,  Tomohiko Inoue ,  Kazuyuki Yokoyama

IPC分类号： C01G55/00 ,  B01J31/24 ,  B01J31/40 ,  C07C45/50 ,  C07C47/055

CPC分类号： B01J31/1845 ,  B01J31/2404 ,  B01J31/4046 ,  B01J31/4053 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/822 ,  B01J31/0235 ,  B01J31/04 ,  B01J31/26 ,  Y02P20/584

摘要： A process for producing a rhodium complex solution, which comprises contacting an aqueous solution of a water-soluble rhodium compound and an organic solvent solution of a water-insoluble tertiary organic phosphorus compound, preferably in the presence of a C.sub.2-8 carboxylic acid, in a gas atmosphere containing carbon monoxide, followed by two phase separation, and recovering an organic solvent phase containing a rhodium-tertiary organic phosphorus compound complex. As the above aqueous solution of a rhodium compound, an aqueous solution having rhodium extracted into an aqueous phase from a waste catalyst liquid separated from a hydroformylation reaction step by oxidation treatment in the presence of a recovery accelerator such as a carboxylic acid, an amine, ammonia or an inorganic acid, is used, whereby recycling of rhodium represented by hydroformylation reaction/recovery of the catalyst/regeneration of the catalyst, is made possible, and a cumbersome step of preparing a complex catalyst from an inorganic salt or the like, or a step of preparing a soluble salt from a metal or oxide by combustion in water of the recovered catalyst, can be omitted.

摘要翻译： 一种制备铑络合物溶液的方法，其包括使水溶性铑化合物的水溶液与水不溶性叔有机磷化合物的有机溶剂溶液，优选在C2-8羧酸存在下，在 含有一氧化碳的气体气氛，然后进行两相分离，并回收含有铑 - 叔有机磷化合物络合物的有机溶剂相。 作为上述铑化合物的水溶液，通过在回收促进剂如羧酸，胺等存在下，通过氧化处理，从加氢甲酰化反应步骤中分离出的废催化剂液体将含有铑的水溶液萃取到水相中， 氨或无机酸，从而可以通过加氢甲酰化反应/催化剂的回收/催化剂的再生来代替的铑的回收成为可能，并且从无机盐等制备复合催化剂的繁琐步骤，或 可以省略通过在回收的催化剂的水中燃烧而从金属或氧化物制备可溶性盐的步骤。

公开(公告)号：US5672766A

公开(公告)日：1997-09-30

申请号：US568970

申请日：1995-12-07

申请人： Tomoyuki Mori ,  Masaki Takai ,  Tomohiko Inoue

发明人： Tomoyuki Mori ,  Masaki Takai ,  Tomohiko Inoue

IPC分类号： C07C45/50

CPC分类号： C07C45/50

摘要： A method for producing aldehydes, which comprises reacting an olefinic unsaturated compound with carbon monoxide and hydrogen for hydroformylation in the presence of a rhodium-phosphite complex catalyst to obtain a reaction product solution containing the rhodium-phosphite complex catalyst and an aldehyde product, and separating from the reaction product solution at least one component selected from the group consisting of carbon monoxide, hydrogen, an unreacted olefinic unsaturated compound, the aldehyde product, a solvent, a medium-boiling by-product and a high-boiling by-product by a separating operation, wherein at least one separating operation is carried out substantially in the absence of water, and the temperature and the residence time in the separating operation are selected to be within such ranges that value P calculated from the following formula (1) would be at most 1: P=5.0.times.10.sup.3 .times.exp�-5000/(T.sub.1 +273)!.times..theta.T.sub.1(1) where T.sub.1 is the maximum temperature (.degree.C.) in the separating operation, and .theta.T.sub.1 is the residence time (minutes) of the liquid in the separating operation.

摘要翻译： 一种生产醛的方法，其包括使烯属不饱和化合物与一氧化碳和氢气在铑 - 亚磷酸盐配合物催化剂存在下进行加氢甲酰化反应，得到含有铑 - 亚磷酸盐配合物催化剂和醛产物的反应产物溶液，并分离 从反应产物溶液中选择一种或多种选自一氧化碳，氢气，未反应的烯属不饱和化合物，醛产物，溶剂，中沸腾副产物和高沸点副产物的至少一种组分 分离操作，其中基本上在没有水的情况下进行至少一个分离操作，并且将分离操作中的温度和停留时间选择为在下式（1）计算出的值P为 最多1：P = 5.0×103×exp [-5000 /（T1 + 273）]×θT1（1）其中T1是分离中的最高温度（℃） 操作，θT1是分离操作中液体的停留时间（分钟）。

公开(公告)号：US07423168B2

公开(公告)日：2008-09-09

申请号：US10649767

申请日：2003-08-28

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C69/76 ,  C07C41/06

CPC分类号： C07C41/16 ,  C07C41/06 ,  C07C67/10 ,  C07C69/78 ,  C07C43/15 ,  C07C43/215

摘要： A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent having a structure different from that of the allyl starting material compound in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a monodentate phosphite compound having a structure of the following formula (1): P(OR1)(OR2)(OR3)  (1) wherein R1, R2 and R3 are respectively independently an alkyl group which may have a substituent, carbon chains of R1, R2 and R3 may have at least one carbon-carbon double bond or triple bond, and at least two optional groups of R1, R2 and R3 may bond to each other to form at least one cyclic structure.

摘要翻译： 一种具有与烯丙基原料化合物不同的组成式的烯丙基化合物的制备方法，该方法包括使烯丙基原料化合物与具有与烯丙基原料化合物不同的结构的氧亲核剂在存在 含有至少一种含有选自属于周期表第8族至第10族的过渡金属的过渡金属的过渡金属化合物和具有下式（1）的结构的单齿亚磷酸酯化合物的催化剂： 在线公式描述=“在线公式”end =“lead”？> P（OR ^{2 ）（OR 2 < / SUP>）（1）<？in-line-formula description =“In-line Formulas”end =“tail”？>其中R 1，R 2，和 R 3分别独立地是可以具有取代基的烷基，R 1，R 2和R 3的碳链， / SUP>可能在l 东一个碳 - 碳双键或三键，并且R 1，R 2和R 3的至少两个任选基团可以键合到 彼此形成至少一个循环结构。}

公开(公告)号：US07173157B2

公开(公告)日：2007-02-06

申请号：US10650697

申请日：2003-08-29

申请人： Masaki Takai ,  Yoshiyuki Tanaka

发明人： Masaki Takai ,  Yoshiyuki Tanaka

IPC分类号： C07C41/06 ,  C07C69/76

CPC分类号： C08G63/52 ,  C07C41/16 ,  C07C67/10 ,  C07C209/66 ,  C07C2601/14 ,  C08G63/87 ,  C07C69/78 ,  C07C211/35 ,  C07C43/215 ,  C07C43/15

摘要： An allyl compound having a formula different from that of an allyl starting compound is prepared by a process of reacting the allyl starting compound with a nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of elements belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having the following formulae (I) to (III): wherein A1 to A3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R1 to R6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6Π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z1 to Z3 are respectively independently an optionally substituted alkylene group, an optionally substituted arylene group, an optionally substituted alkylene-arylene group or an optionally substituted diarylene group.

摘要翻译： 通过使烯丙基起始化合物与亲核剂在含有至少一种含有过渡金属的过渡金属的催化剂存在下反应的方法来制备具有与烯丙基起始化合物不同的烯丙基化合物， 由属于元素周期表第8至10族的元素和至少一种选自具有下式（I）至（III）的化合物的二齿配位的亚磷酸酯化合物组成：其中A 1〜 分别独立地为在邻位具有支链烷基的二亚芳基，R 1至R 6分别独立地为 可以具有取代基的烷基或可具有取代基的芳基（包括在环的上侧和下侧形成芳香族6Pi电子云的杂环化合物，以下相同），Z 1 到Z 3 分别独立地为任选取代的亚烷基，任选取代的亚芳基，任选取代的亚烷基 - 亚芳基或任选取代的亚芳基。