公开(公告)号：US06207850B1

公开(公告)日：2001-03-27

申请号：US09433362

申请日：1999-11-03

申请人： Zhaozhong Jiang ,  Rene B. LaPierre ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken ,  William A. Weber

发明人： Zhaozhong Jiang ,  Rene B. LaPierre ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken ,  William A. Weber

IPC分类号： C07C6806

CPC分类号： C07C29/1285 ,  C07C68/065 ,  C07C69/96 ,  C07C31/202

摘要： A method is provided for co-producing dialkyl carbonate and alkanediol by reacting alkylene carbonate with alkanol in the presence of a IIIA metal oxide catalyst, preferably alumina.

摘要翻译： 提供了一种通过在IIIA金属氧化物催化剂，优选氧化铝的存在下使碳酸亚烷基酯与链烷醇反应来共同生产碳酸二烷基酯和链烷二醇的方法。

公开(公告)号：US06258962B1

公开(公告)日：2001-07-10

申请号：US09332725

申请日：1999-06-14

申请人： J. Scott Buchanan ,  Clarence D. Chang ,  Robert A. Crane ,  Lorenzo C. DeCaul ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken

发明人： J. Scott Buchanan ,  Clarence D. Chang ,  Robert A. Crane ,  Lorenzo C. DeCaul ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  Hye Kyung Cho Timken

IPC分类号： C07D32100

CPC分类号： C07D319/06 ,  C07D317/36

摘要： A process for the synthesis of alkylene carbonates, such as ethylene carbonate, by reacting alkylene oxides with carbon dioxide in the presence of a porous solid support catalyst containing an alkali or alkaline earth metal component.

摘要翻译： 在含有碱金属或碱土金属组分的多孔固体载体催化剂存在下，通过使环氧烷与二氧化碳反应来合成碳酸亚烷基酯如碳酸亚乙酯的方法。

公开(公告)号：US07084292B2

公开(公告)日：2006-08-01

申请号：US09887642

申请日：2001-06-22

申请人： J. Scott Buchanan ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  William A. Weber

发明人： J. Scott Buchanan ,  Zhaozhong Jiang ,  Jose G. Santiesteban ,  William A. Weber

IPC分类号： C07C69/96

CPC分类号： C07C68/065 ,  B01J2219/00006 ,  C07D317/36 ,  C07D317/38 ,  C08G64/307 ,  C08G64/34 ,  Y02P20/125 ,  Y02P20/127 ,  Y02P20/584 ,  C07C69/96

摘要： An integrated process for the production of a dialkyl carbonate and a diol from an alkylene oxide, carbon dioxide and an aliphatic monohydric alcohol is described in which an alkylene oxide is first reacted with carbon dioxide in the presence of a homogeneous carbonation catalyst to provide a corresponding cyclic carbonate and the cyclic carbonate is then reacted with an aliphatic monohydric alcohol in the presence of the homogeneous carbonation catalyst and/or a heterogeneous transesterification catalyst and recycling the homogeneous carbonation catalyst to provide a corresponding dialkyl carbonate and diol.

公开(公告)号：US06407279B1

公开(公告)日：2002-06-18

申请号：US09444231

申请日：1999-11-19

申请人： J. Scott Buchanan ,  Zhaozhong Jiang ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban

发明人： J. Scott Buchanan ,  Zhaozhong Jiang ,  Jocelyn A. Kowalski ,  Jose G. Santiesteban

IPC分类号： C07C6996

CPC分类号： C07C68/065 ,  C07C29/1285 ,  Y02P20/125 ,  C07C69/96 ,  C07C31/202

摘要： An integrated process for the production of a dialkyl carbonate and a diol from an alkylene oxide, carbon dioxide and an aliphatic monohydric alcohol is described in which an alkylene oxide is first reacted with carbon dioxide in the presence of a carbonation catalyst to provide a corresponding cyclic carbonate and impurities and the cyclic carbonate, which contains the impurities, is then reacted with an aliphatic monohydric alcohol in the presence of a transesterification catalyst to provide a corresponding dialkyl carbonate and diol.

摘要翻译： 描述了一种用于从烯化氧，二氧化碳和脂族一元醇生产碳酸二烷基酯和二醇的综合方法，其中烯化氧首先在碳酸化催化剂存在下与二氧化碳反应以提供相应的环状 然后将含有杂质的环状碳酸酯与脂肪族一元醇在酯交换催化剂存在下反应，得到相应的碳酸二烷基酯和二醇。

公开(公告)号：US06573396B2

公开(公告)日：2003-06-03

申请号：US09976608

申请日：2001-10-12

申请人： J. Scott Buchanan ,  Jose G. Santiesteban ,  Zhaozhong Jiang

发明人： J. Scott Buchanan ,  Jose G. Santiesteban ,  Zhaozhong Jiang

IPC分类号： C07C6996

CPC分类号： C07C68/065 ,  Y02P20/127 ,  C07C69/96

摘要： A process for the production of a dialkyl carbonate and a diol from a cyclic carbonate and an aliphatic monohydric alcohol wherein the cyclic carbonate and aliphatic monohydric alcohol are reacted in the presence of a transesterification catalyst to form a crude product stream which contains a dialkyl carbonate, a diol, a hydroxy alkyl carbonate, which is formed as an intermediate of the two step transesterification reaction, unreacted aliphatic monohydric alcohol and unreacted cyclic carbonate. The dialkyl carbonate and unreacted aliphatic monohydric alcohol are separated from the crude product stream and then the hydroxy alkyl carbonate is diminished, reduced or eliminated from the crude product stream, prior to the separation and purification steps needed to recover the diol, resulting in improved yields and product purity.

摘要翻译： 一种由环状碳酸酯和脂族一元醇生产碳酸二烷基酯和二醇的方法，其中环状碳酸酯和脂肪族一元醇在酯交换催化剂的存在下反应，形成含有碳酸二烷基酯的粗产物流， 作为两步酯交换反应的中间体形成的二醇，羟基烷基碳酸酯，未反应的脂肪族一元醇和未反应的环状碳酸酯。 将碳酸二烷基酯和未反应的脂肪族一元醇与粗产物流分离，然后在回收二醇所需的分离和纯化步骤之前，从粗产物流中减少，还原或消除羟基烷基碳酸酯，从而提高产率 和产品纯度。

公开(公告)号：US07148391B1

公开(公告)日：2006-12-12

申请号：US10294428

申请日：2002-11-14

申请人： John Scott Buchanan ,  Ronald J. Cimini ,  Frank Wenyih Lai ,  Jose G. Santiesteban ,  David A. Stachelczyk ,  David L. Stern ,  Hye-Kyung C. Timken ,  William A. Weber ,  Robert A. Crane

发明人： John Scott Buchanan ,  Ronald J. Cimini ,  Frank Wenyih Lai ,  Jose G. Santiesteban ,  David A. Stachelczyk ,  David L. Stern ,  Hye-Kyung C. Timken ,  William A. Weber ,  Robert A. Crane

IPC分类号： C07C5/52

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/44 ,  B01J29/48 ,  B01J29/70 ,  B01J29/74 ,  B01J29/78 ,  B01J35/002 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C10G45/64 ,  Y02P20/52

摘要： In a process for converting C9+ aromatic hydrocarbons to lighter aromatic products a feed comprising C9+ aromatic hydrocarbons is contacted under transalkylation reaction conditions with a catalyst composition comprising (i) a first molecular sieve selected from the group consisting of ZSM-12, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07; and (ii) a second molecular sieve having a constraint index ranging from 3 to 12. At least the first molecular sieve has a hydrogenation component associated therewith and the first and second molecular sieves are contained in the same catalyst bed. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene.

摘要翻译： 在将C 9+芳烃转化成较轻芳香族产物的方法中，包含C 9+芳烃的进料在烷基转移反应条件下与催化剂组合物接触，所述催化剂组合物包含（i） 选自ZSM-12，丝光沸石和具有12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07的d间距最大值的X射线衍射图的多孔结晶无机氧化物材料的第一分子筛 ; 和（ii）约束指数为3至12的第二分子筛。至少第一分子筛具有与之相关的氢化组分，并且第一和第二分子筛包含在相同的催化剂床中。 在烷基转移反应条件下将C 9+芳烃转化成含有二甲苯的反应产物。

公开(公告)号：US07485763B2

公开(公告)日：2009-02-03

申请号：US11592832

申请日：2006-11-03

申请人： John Scott Buchanan ,  Ronald J. Cimini ,  Robert A. Crane ,  Wenyih F. Lai ,  Jose G. Santiesteban ,  David A. Stachelczyk ,  David L. Stern ,  Hye-Kyung C. Timken ,  William A. Weber

发明人： John Scott Buchanan ,  Ronald J. Cimini ,  Robert A. Crane ,  Wenyih F. Lai ,  Jose G. Santiesteban ,  David A. Stachelczyk ,  David L. Stern ,  Hye-Kyung C. Timken ,  William A. Weber

IPC分类号： C07C6/12

CPC分类号： B01J29/80 ,  B01J29/40 ,  B01J29/44 ,  B01J29/48 ,  B01J29/70 ,  B01J29/74 ,  B01J29/78 ,  B01J35/002 ,  B01J37/0009 ,  B01J2229/20 ,  B01J2229/42 ,  C07C6/126 ,  C10G45/64 ,  Y02P20/52

摘要： In a process for converting C9+ aromatic hydrocarbons to lighter aromatic products a feed comprising C9+ aromatic hydrocarbons is contacted under transalkylation reaction conditions with a catalyst composition comprising (i) a first molecular sieve selected from the group consisting of ZSM-12, mordenite and a porous crystalline inorganic oxide material having an X-ray diffraction pattern including d-spacing maxima at 12.4±0.25, 6.9±0.15, 3.57±0.07 and 3.42±0.07; and (ii) a second molecular sieve having a constraint index ranging from 3 to 12. At least the first molecular sieve has a hydrogenation component associated therewith and the first and second molecular sieves are contained in the same catalyst bed. The C9+ aromatic hydrocarbons are converted under the transalkylation reaction conditions to a reaction product containing xylene.

摘要翻译： 在将C9 +芳族烃转化为较轻芳香族产物的方法中，在烷基转移反应条件下，将C9 +芳香烃进料与含有（i）选自ZSM-12，丝光沸石和多孔 具有在12.4±0.25,6.9±0.15,3.57±0.07和3.42±0.07的d间距最大值的X射线衍射图的结晶无机氧化物材料; 和（ii）约束指数为3至12的第二分子筛。至少第一分子筛具有与之相关的氢化组分，并且第一和第二分子筛包含在相同的催化剂床中。 C9 +芳烃在烷基转移反应条件下转化为含有二甲苯的反应产物。

公开(公告)号：US20090214407A1

公开(公告)日：2009-08-27

申请号：US12321751

申请日：2009-01-23

申请人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

发明人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

IPC分类号： B01D53/62 ,  B01D53/047 ,  B01D53/22 ,  C01B31/20

CPC分类号： B01D53/02 ,  B01D53/228 ,  B01D67/0051 ,  B01D69/141 ,  B01D71/028 ,  B01D2253/204 ,  B01D2256/10 ,  B01D2257/504 ,  B01D2325/12 ,  B01D2325/20 ,  B01J20/226 ,  Y02C10/04 ,  Y02C10/08 ,  Y02C10/10

摘要： The present invention relates to the selective separation of carbon dioxide (“CO2”) from nitrogen (“N2”) in streams containing both carbon dioxide and nitrogen utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in a process to separate carbon dioxide from combustion gas (e.g., flue gas) streams preferably for sequestration of at least a portion of the carbon dioxide produced in combustion processes.

摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料在含有二氧化碳和氮气的物流中从氮气（“N2”）中选择性分离二氧化碳（“CO 2”）。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选的实施方案中，本发明用于将二氧化碳从燃烧气体（例如烟道气）流中分离出来，优选用于封存燃烧过程中产生的二氧化碳的至少一部分。

公开(公告)号：US20090211440A1

公开(公告)日：2009-08-27

申请号：US12322363

申请日：2009-01-30

申请人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

发明人： Sebastian C. Reyes ,  Jose G. Santiesteban ,  Zheng Ni ,  Charanjit S. Paur ,  Pavel Kortunov ,  John Zengel ,  Harry W. Deckman

IPC分类号： B01D53/00 ,  B01D53/04 ,  B01D53/22

CPC分类号： B01D53/228 ,  B01D53/02 ,  B01D53/0462 ,  B01D53/047 ,  B01D67/0051 ,  B01D69/141 ,  B01D71/028 ,  B01D2253/108 ,  B01D2253/204 ,  B01D2256/16 ,  B01D2256/24 ,  B01D2257/702 ,  B01D2325/12 ,  B01J20/226 ,  C01B3/503 ,  C01B3/56 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/048 ,  Y10S95/902

摘要： The present invention relates to the selective separation of hydrogen (“H2”) hydrocarbons in streams containing both hydrogen and hydrocarbons (e.g. methane, ethylene, ethane, propylene, propane, etc.) utilizing a zeolitic imidazolate framework (“ZIF”) material. Preferably, the stream to be separated is fed to the present process in a substantially gaseous phase. In preferred embodiments, the current invention is utilized in either a pressure swing adsorption process, a temperature swing adsorption process, or a membrane separations process to separate hydrogen from hydrocarbons present in hydrogen production streams or petrochemical/petroleum refining product streams and intermediate streams.

摘要翻译： 本发明涉及使用沸石咪唑化物骨架（“ZIF”）材料选择性分离含氢和烃（例如甲烷，乙烯，乙烷，丙烯，丙烷等）的物流中的氢（“H 2”）烃。 优选地，待分离的物流以基本上气相的方式进料到本方法中。 在优选实施方案中，本发明用于变压吸附法，变温吸附法或膜分离方法，以将氢气与存在于氢生产流或石化/石油精炼产物流和中间物流中的烃分离。

公开(公告)号：US07332640B2

公开(公告)日：2008-02-19

申请号：US10699258

申请日：2003-10-31

申请人： Sebastian C. Reyes ,  David H. Olson ,  Haiming Liu ,  Karl G. Strohmaier ,  Jose G. Santiesteban

发明人： Sebastian C. Reyes ,  David H. Olson ,  Haiming Liu ,  Karl G. Strohmaier ,  Jose G. Santiesteban

IPC分类号： C07C7/12

CPC分类号： C07C7/13 ,  C07C11/06 ,  C07C9/08

摘要： The present invention is related to a method for kinetically separating a light hydrocarbon mixture comprising at least two components by preferentially adsorbing a first component on a zeolite adsorbent comprising 8-member rings of tetrahedra as the pore opening controlling hydrocarbon diffusion and alkali metal cations balancing a framework charge, wherein a second component is not preferentially adsorbed. The novel process comprises contacting the light hydrocarbon mixture with a zeolite adsorbent having a SiO2/Al2O3 ratio greater than about 50 and less than 200 and further having a diffusion rate at least 50 times greater for the first component as compared to the second component, and then recovering at least one of the first component or the second component.

摘要翻译： 本发明涉及一种用于动态分离含有至少两种组分的轻质烃混合物的方法，该轻质烃混合物优先吸附在包含八元环四面体的沸石吸附剂上的第一组分，作为开孔控制烃扩散和碱金属阳离子平衡 框架电荷，其中第二组分不被优先吸附。 该新方法包括使轻质烃混合物与沸石吸附剂接触，所述沸石吸附剂具有大于约50或更小的SiO 2 / Al 2 O 3 并且与第二组分相比，第一组分的扩散速率至少为50倍，然后回收第一组分或第二组分中的至少一种。