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    Polyurethane Elastomers Based on TDI Prepolymers Enriched in the 2,6-TDI Isomer Cured with Trimethylene Glycol Di-(para Amino Benzoate)
    1.
    发明申请
    Polyurethane Elastomers Based on TDI Prepolymers Enriched in the 2,6-TDI Isomer Cured with Trimethylene Glycol Di-(para Amino Benzoate) 审中-公开
    基于用三亚甲基二醇二（对氨基苯甲酸酯）固化的2,6-TDI异构体中富含的TDI预聚物的聚氨酯弹性体

    公开(公告)号：US20140309397A1

    公开(公告)日：2014-10-16

    申请号：US13860986

    申请日：2013-04-11

    申请人： ANDERSON DEVELOPMENT COMPANY

    发明人： ROBERT A. CZEISZPERGER ,  JORDAN M. DUCKETT ,  STEPHEN D. SENEKER

    IPC分类号： C08G18/32

    CPC分类号： C08G18/4825 ,  C08G18/10 ,  C08G18/12 ,  C08G18/3206 ,  C08G18/4202 ,  C08G18/4238 ,  C08G18/4277 ,  C08G18/4804 ,  C08G18/4854 ,  C08G18/7621 ,  C08G2380/00 ,  C08G18/3243

    摘要： Polyurethane/urea elastomer compositions which retain their dimensions at elevated temperatures. These polyurethane/urea elastomers surprisingly have improved green strength or dimensional stability upon demolding at typical mold temperatures of 80 to 130 C and remain dimensionally stable throughout the post cure process which is typically overnight at about 100 C. They are useful in indirect food contact or dry food contact applications since the compositions use trimethylene glycol di(p-aminobenzoate) as a chain extender or curative. The polyurethane/urea elastomers may be prepared by reacting toluene diisocyanate prepolymers with trimethylene glycol di(p-aminobenzoate). The toluene diisocyanate prepolymers are reaction products of toluene diisocyanate containing at least 25% by weight of the 2,6-isomer, preferentially at least 35%, more preferentially at least 45%, and most preferentially 60% with polyols such as polyoxyalkylene polyether polyols like polytetramethylene glycol, polypropylene glycol and polyethylene glycol, polyester polyols, polycaprolactone polyols, polycarbonate polyols, polybutadiene polyols or mixtures thereof.

    摘要翻译： 在高温下保持其尺寸的聚氨酯/脲弹性体组合物。 这些聚氨酯/脲弹性体令人惊奇地在80-130℃的典型模具温度下脱模时具有改善的生坯强度或尺寸稳定性，并且在整个后固化过程中保持尺寸稳定，其通常在约100℃过夜。它们可用于间接食品接触或 干食品接触应用，因为组合物使用三聚乙二醇二（对氨基苯甲酸酯）作为扩链剂或固化剂。 聚氨酯/尿素弹性体可以通过使甲苯二异氰酸酯预聚物与三亚甲基二醇二（对氨基苯甲酸酯）反应来制备。 甲苯二异氰酸酯预聚物是甲苯二异氰酸酯的反应产物，其含有至少25重量％的2,6-异构体，优选至少35重量％，更优选至少45重量％，最优选60重量％的多元醇，例如聚氧化烯聚醚多元醇 如聚四亚甲基二醇，聚丙二醇和聚乙二醇，聚酯多元醇，聚己内酯多元醇，聚碳酸酯多元醇，聚丁二烯多元醇或其混合物。

    Stable and storable polyester-polyether co-prepolymers
    2.
    发明授权
    Stable and storable polyester-polyether co-prepolymers 失效
    稳定和可储存的聚酯 - 聚醚共预聚物

    公开(公告)号：US4182898A

    公开(公告)日：1980-01-08

    申请号：US871330

    申请日：1978-01-20

    申请人： Edward J. Fujiwara ,  Michelle D. Pate

    发明人： Edward J. Fujiwara ,  Michelle D. Pate

    IPC分类号： C08G18/12 ,  C08G18/40 ,  C07C125/04 ,  C08G18/48

    CPC分类号： C08G18/4018 ,  C08G18/12 ,  Y10S528/906

    摘要： Polyurethanes having improved properties are obtained from polyester-polyether co-prepolymers. These co-prepolymers are homogeneous, clear liquids of varying viscosity and can be reacted with curing agents to yield clear homogeneous elastomers of various hardness. Cast elastomers prepared from such co-prepolymers have physical properties at least as good as premium polyester urethanes currently available, and have hydrolytic stability and low temperature properties better than such premium polyester urethanes and comparable to premium polyether urethanes, with the cost being comparable to the lower cost of the conventional polyester systems.

    摘要翻译： 具有改进性能的聚氨酯由聚酯 - 聚醚共预聚物获得。 这些共预聚物是具有不同粘度的均匀，透明的液体，并可与固化剂反应，得到各种硬度的透明均匀的弹性体。 由这种共预聚物制备的铸塑弹性体具有至少与目前可获得的优质聚酯聚氨酯一样好的物理性能，并且具有比这些优质聚酯聚氨酯更好的水解稳定性和低温性能，并且与优质聚醚聚氨酯相当，成本可与 降低传统聚酯体系的成本。

    Chrome catalyst
    3.
    发明授权
    Chrome catalyst 失效
    铬催化剂

    公开(公告)号：US4008359A

    公开(公告)日：1977-02-15

    申请号：US542164

    申请日：1975-01-20

    申请人： Jeffrey G. Meyer ,  Glennis L. Phipps

    发明人： Jeffrey G. Meyer ,  Glennis L. Phipps

    IPC分类号： C08F4/62 ,  C08F10/00 ,  C08F10/02 ,  C08F4/78 ,  C08F10/06

    CPC分类号： C08F10/00 ,  C08F10/02

    摘要： This invention comprises the novel composition formed by mixing (A) a chromium tris-diorgano-orthophosphate of the general formula Cr[OP(O) (OR).sub.2 ].sub.3 wherein R can be an alkyl, alkoxyalkyl or cycloalkyl group of one to about eight carbon atoms and the chlorinated and brominated derivatives thereof, (B) an alkyl aluminum compound of the general formula R'.sub.2 R"Al in which each R' and R" can be an alkyl group of 1 to 6 carbon atoms and each R" can also be a hydrogen atom, and (C) a halogenated olefin of four to about eight carbon atoms containing at least four halogen atoms at least two of which are attached to doubly bonded carbon atoms.This invention also comprises the use of this novel combination as a catalyst for the polymerization of ethylene alone or with propylene and other olefins. This invention also comprises the polymer products prepared by said method.

    摘要翻译： 本发明包括通过混合（A）通式Cr [OP（O）（OR）2] 3的三 - 二有机 - 正磷酸铬，其中R可以是一个至约二个烷基的烷基，烷氧基烷基或环烷基 八个碳原子及其氯化和溴化衍生物，（B）通式R'2R''Al的烷基铝化合物，其中每个R'和R“可以是1至6个碳原子的烷基， R“也可以是氢原子，和（C）含有至少四个卤素原子的四至八个碳原子的卤代烯烃，其中至少两个连接到双键碳原子上。

    NOVEL BORATE DERIVATIVES AND THEIR APPLICATIONS
    5.
    发明申请
    NOVEL BORATE DERIVATIVES AND THEIR APPLICATIONS 审中-公开
    新型硼酸衍生物及其应用

    公开(公告)号：US20120289733A1

    公开(公告)日：2012-11-15

    申请号：US13469544

    申请日：2012-05-11

    申请人： Glenn L. HEISE ,  Malgorzata Myslinska

    发明人： Glenn L. HEISE ,  Malgorzata Myslinska

    IPC分类号： C07F5/02 ,  C07F5/04

    CPC分类号： C07F5/022 ,  C07F5/025 ,  C07F5/04

    摘要： Borates, compositions comprising chiral (cyclic and acyclic) and achiral (cyclic and acyclic) borates; chiral (cyclic and acyclic) and achiral (cyclic and acyclic) biborates; and methods for their synthesis. Additionally, a significantly improved synthetic protocol for the synthesis of wide range of boronates starting from borates or biborates and Grignard or organolithium reagents that can be used for kilo lab and commercial scale production.

    摘要翻译： 硼酸盐，包含手性（环状和非环状）和非手性（环状和非环状）硼酸盐的组合物; 手性（环状和非环状）和非手性（环状和非环状）双酚B; 及其合成方法。 另外，用于合成广泛范围的硼酸盐的合成方案可从硼酸盐或双酚硼酸盐和可用于千克实验室和商业规模生产的Grignard或有机锂试剂开始。

    Nickel bis-diorgano-orthophosphates their preparation and use
    7.
    发明授权
    Nickel bis-diorgano-orthophosphates their preparation and use 失效
    尼克尔双相异构磷酸酯它们的制备和使用

    公开(公告)号：US4117022A

    公开(公告)日：1978-09-26

    申请号：US839117

    申请日：1977-10-03

    申请人： Jeffrey G. Meyer

    发明人： Jeffrey G. Meyer

    IPC分类号： B01J31/14 ,  B01J31/18 ,  C07C2/30 ,  C08F4/70 ,  C08F10/00 ,  C07C3/21

    CPC分类号： B01J31/185 ,  B01J31/143 ,  C07C2/30 ,  C08F10/00 ,  C08F4/7098 ,  B01J2231/122 ,  B01J2231/20 ,  B01J2531/847 ,  C07C2531/02 ,  C07C2531/14

    摘要： This invention comprises novel organic-solvent-soluble nickel bis-diorgano-orthophosphates and their preparation by the reaction of certain simple salts or esters of divalent nickel with certain non-aromatic triorgano orthophosphates free of aliphatic unsaturation and separation of the novel compounds. The simple salts or esters include preferably the halides, nitrates and acetates of divalent nickel.This invention further comprises the use of these novel compounds, preferably in solution, as catalysts. When used in conjunction with alkyl aluminum halides, controlled oligomerization of ethylene, propylene and other olefins is achieved with the formation of polymers with low degrees of polymerization, e.g. 2 to 10, preferably no more than about 6 mers. When certain vanadium catalysts are added to these combined catalysts, high polymers of such monomers are achieved with significant residual aliphatic unsaturation.

    Curing agents
    9.
    发明授权
    Curing agents 失效
    固化剂

    公开(公告)号：US3933675A

    公开(公告)日：1976-01-20

    申请号：US457488

    申请日：1974-04-03

    申请人： Joseph Theodore Willett

    发明人： Joseph Theodore Willett

    IPC分类号： C08G18/10 ,  C08G71/04

    CPC分类号： C08G18/10

    摘要： Improved curing agents having long pot life for use with urethane elastomers are prepared by reacting orthochloroaniline, an ester of anthranilic acid, and formaldehyde in selected molar ratios in an acid medium.

    摘要翻译： 通过在酸性介质中使选择摩尔比的邻氯苯胺，邻氨基苯甲酸酯和甲醛以选定的摩尔比反应制备具有长期适用于氨基甲酸酯弹性体的改进的固化剂。