Preparation of fatty acid esters of isopropylidene derivatives of
polyglycerol
    1.
    发明授权
    Preparation of fatty acid esters of isopropylidene derivatives of polyglycerol 失效
    聚甘油异丙叉衍生物脂肪酸酯的制备

    公开(公告)号:US5403941A

    公开(公告)日:1995-04-04

    申请号:US045091

    申请日:1993-04-12

    CPC分类号: C07D317/24

    摘要: A process for the preparation of mono-fatty acid or hydroxymono-fatty acid esters of isopropylidene derivatives of a polyglycerol is disclosed. A C6-C22 fatty acid or -hydroxy fatty acid is reacted with isopropylideneglycerol glycidyl ether or diisopropylidenetriglycerol glycidyl ether in a molar ratio of 0.5:1 to 1:0.5 at temperatures of 373473 K. in the presence of a catalyst. The monoisopropylidenediglycerol mono-fatty acid ester or monoisopropylidenediglycerol hydroxy mono-fatty acid ester or diisopropylidenetetraglycerol mono-fatty acid ester or diisopropylidenetetraglycerol hydroxy mono-fatty acid ester obtained is optionally purified by distillation, fractional distillation and/or ion exchange.

    摘要翻译: 公开了制备聚甘油的异丙叉衍生物的单脂肪酸或羟基单脂肪酸酯的方法。 在催化剂存在下,将C 6 -C 22脂肪酸或羟基脂肪酸与异丙基甘油缩水甘油醚或二异亚丙基甘油缩水甘油醚以摩尔比为0.5:1至1:0.5的温度反应。 所获得的单异亚丙基二甘油单脂肪酸酯或单异亚丙基二甘油羟基单脂肪酸酯或二异亚丙基三甘油单脂肪酸酯或二异亚丙基三甘油羟基单脂肪酸酯任选地通过蒸馏,分馏和/或离子交换进行纯化。

    Underseal composition, and process for the production thereof
    3.
    发明授权
    Underseal composition, and process for the production thereof 失效
    下层组合物及其生产方法

    公开(公告)号:US5135967A

    公开(公告)日:1992-08-04

    申请号:US593505

    申请日:1990-10-04

    摘要: The present invention relates to an underseal composition for motor vehicles, comprising a finely divided vinyl chloride homopolymer, copolymer, terpolymer or graft polymer, a plasticizer, a stabilizer, and a filler comprising calcium carbonate particles, wherein at least a part of said filler is provided with a surface coating formed by a surface treatment agent which comprises at least one saturated or unsaturated carboxylic acid, fatty acid or substituted fatty acid, said carboxylic acid or fatty acid having from 2 to 32 carbon atoms and containing at least one polar group in addition to at least one --COOH group, or a salt of said carboxylic acid or fatty acid. The underseal composition has improved rheological properties.

    摘要翻译: 本发明涉及一种用于机动车辆的下部组合物,其包含细碎的氯乙烯均聚物,共聚物,三元共聚物或接枝聚合物,增塑剂,稳定剂和包含碳酸钙颗粒的填料,其中至少部分所述填料为 其具有由表面处理剂形成的表面涂层,所述表面处理剂包含至少一种饱和或不饱和羧酸,脂肪酸或取代的脂肪酸,所述羧酸或具有2至32个碳原子的脂肪酸并含有至少一个极性基团 加至至少一个-COOH基团,或所述羧酸或脂肪酸的盐。 下层组合物具有改善的流变性能。

    Unplasticized polyvinyl chloride-based molding composition, process for
its preparation and its use
    4.
    发明授权
    Unplasticized polyvinyl chloride-based molding composition, process for its preparation and its use 失效
    不溶性聚氯乙烯基成型组合物及其制备方法及其用途

    公开(公告)号:US5124373A

    公开(公告)日:1992-06-23

    申请号:US571263

    申请日:1990-08-23

    CPC分类号: C08K5/098 C08K9/04 C08L27/06

    摘要: The present invention relates to a polyvinyl chloride- based unplasticized molding composition which includes vinyl chloride homo-, co- and/or ter-polymer and/or mixtures or alloys thereof having a vinyl chloride or PVC content of more than 70% by weight, preferably more than 85% by weight, and 15 to 0% by weight of at least one impact-modifying polymer, which unplasticized molding composition includes, per 100 parts by weight of the PVC mixture if appropriate, pigments, colorants, lubricants, blowing agents, flame retardants, fillers, reinforcing fibers or other processing auxiliaries and the following additives:(a) 0.01 to 3 parts by weight of at least one calcium carboxylate,(b) 0.01 to 3 parts by weight of at least one zinc carboxylate,(c) 0.01 to 3 parts by weight of at least one organic co-stabilizer selected from at least one .beta.-diketone, at least one organic phosphite and/or at least one dihydropyridine, and(d) 0.01 to 5 parts by weight of at least one surface-modified alkaline earth metal oxide, at least one alkaline earth metal hydroxide and/or at least one partly hydrated alkaline earth metal oxide.The invention furthermore relates to the use of the molding composition and the process for its preparation.

    摘要翻译: 本发明涉及一种聚氯乙烯基未增塑的模塑组合物,其包括氯乙烯均聚物,共聚物和/或三聚物和/或其混合物或合金,其氯乙烯或PVC含量大于70重量% 优选大于85重量%,和15至0重量%的至少一种冲击改性聚合物,其未增塑的成型组合物包含100重量份的PVC混合物,如果合适的话,颜料,着色剂,润滑剂,发泡剂 阻燃剂,填料,增强纤维或其它加工助剂和以下添加剂:(a)0.01至3重量份的至少一种羧酸钙,(b)0.01至3重量份的至少一种羧酸锌,( c)0.01至3重量份的至少一种选自至少一种β-二酮,至少一种有机亚磷酸酯和/或至少一种二氢吡啶的有机共稳定剂,和(d)0.01至5重量份的 至少一个表面修饰a 碱土金属氧化物,至少一种碱土金属氢氧化物和/或至少一种部分水合的碱土金属氧化物。 本发明还涉及成型组合物的用途及其制备方法。

    Process for preparing polyglycerols
    5.
    发明授权
    Process for preparing polyglycerols 失效
    制备聚甘油的方法

    公开(公告)号:US4960953A

    公开(公告)日:1990-10-02

    申请号:US328316

    申请日:1989-03-24

    CPC分类号: C07C41/26 C07C41/03 C07C41/42

    摘要: A process for the preparation of polyglycerols which are low in cyclic components comprises reacting glycerol or diglycerol or a higher polyglycerol with epichlorohydrin at elevated temperatures; adding base corresponding to the organically bound chlorine content of the reaction mixture, at a temperature of 50.degree.-120.degree. C., to the unseparated reaction mixture obtained; desalting the resultant reaction mixture and recovering glycerol, diglycerol and higher polyglycerols by fractional distillation.

    摘要翻译: 制备环状组分低的聚甘油的方法包括在升高的温度下使甘油或双甘油或更高级的聚甘油与表氯醇反应; 在50〜120℃的温度下,将与反应混合物的有机结合氯含量相对应的碱添加到得到的未分离反应混合物中; 脱盐得到的反应混合物,并通过分馏回收甘油,双甘油和更高级的聚甘油。

    Wood preserving composition and method of using same
    6.
    发明授权
    Wood preserving composition and method of using same 失效
    木材防腐剂组合物及其使用方法

    公开(公告)号:US4337093A

    公开(公告)日:1982-06-29

    申请号:US165791

    申请日:1980-07-03

    摘要: Disclosed is a composition and method for preserving wood and construction materials made of wood. The composition comprises more than about 65% by weight of at least one difficulty volatile organic-chemical solvent having a flash point higher than about 30.degree. C. and of between about 0.35% by weight and 10.0% by weight of a specific fungicidal agent which is soluble, or at least partly soluble, in the organic-chemical solvent. The specific fungicidal agent is a mixture of N,N-dimethyl-N'-phenyl-N'-(fluoro dichloro methylthio) sulfamide and N,N-dimethyl-N'-(p-tolyl)-N'-(fluoro dichloro methylthio) sulfamide, in the proportion, by weight, of between about 25:10 and 10:30 and preferably between about 15:10 and 10:15. If desired, between about 0.1% by weight and 7.0% by weight of a soluble insecticidal agent may be added to the composition.

    摘要翻译: 公开了一种用于保护由木材制成的木材和建筑材料的组合物和方法。 该组合物包含大于约65重量%的闪点高于约30℃的至少一种难挥发性有机化学溶剂和约0.35重量%至10.0重量%的特定杀真菌剂,其中 在有机溶剂中是可溶的或至少部分可溶的。 具体的杀真菌剂是N,N-二甲基-N'-苯基-N' - (氟二氯甲硫基)磺酰胺和N,N-二甲基-N' - (对甲苯基)-N' - (氟二氯 甲硫基)磺酰胺,其重量比为约25:10至10:30,优选约15:10至10:15。 如果需要,可以向组合物中加入约0.1重量%至7.0重量%的可溶性杀虫剂。

    Process and device for cleaning cathode surfaces
    7.
    发明授权
    Process and device for cleaning cathode surfaces 失效
    用于清洁阴极表面的工艺和装置

    公开(公告)号:US4166754A

    公开(公告)日:1979-09-04

    申请号:US760850

    申请日:1977-01-21

    IPC分类号: B08B3/02 C25B15/00 B08B9/00

    CPC分类号: C25B15/00 B08B3/02

    摘要: Vertically oriented cathode grids or cathode plates, adjacently situated at closely spaced intervals in a cathode box, are cleaned by spraying jets of liquid onto the cathode surfaces at an angle of about 10.degree.-50.degree. and at a pressure of about 60 to 140 atmospheres, while moving the liquid jets uniformly along the cathode surfaces. A device for performing this process comprises a bar shaped spraying means comprising spraying nozzles which are connected to pressure resistent feeding means for the liquid. The spraying means is connected to a guiding system comprising a bar shaped first guiding means, a second guiding means including a guiding bar and a guiding cylinder and a third guiding means and moving means mounted on a support which can be moved over the cathode box and which further comprises means for aligning the guiding system and the spraying means to the cathode box in such a way that the spraying means can be moved uniformly along the cathode surfaces by means of the guiding means and the moving means.

    摘要翻译: 通过以大约10°-50°的角度和大约60到140个大气压的压力将喷射的液体喷射到阴极表面上来清洁在阴极盒中以相互间隔开的相邻位置的垂直取向的阴极栅极或阴极板 同时沿着阴极表面均匀地移动液体射流。 用于执行该过程的装置包括条形喷射装置,包括喷射喷嘴,喷嘴连接到用于液体的耐压输送装置。 喷射装置连接到包括杆形的第一引导装置的引导系统,包括引导杆和引导筒的第二引导装置和安装在可以在阴极盒上移动的支撑件上的第三引导装置和移动装置,以及 其还包括用于将引导系统和喷射装置对准到阴极盒的装置,使得喷射装置可以借助于引导装置和移动装置沿着阴极表面均匀地移动。

    Process for the preparation of polyglycerols
    10.
    发明授权
    Process for the preparation of polyglycerols 失效
    聚甘油的制备方法

    公开(公告)号:US4973763A

    公开(公告)日:1990-11-27

    申请号:US403831

    申请日:1989-09-05

    CPC分类号: C07C41/01 C07C41/16

    摘要: A process for preparation of polyglycerol is provided, comprising the steps of (a) reacting glycerol or diglycerol with hydrogen chloride at between about 340.degree. K. and about 410.degree. K. to yield a mixture that comprises an .alpha.-monochlorohydrin of glycerol or an .alpha.-monochlorohydrin of diglycerol, (b) mixing the .alpha.-monochlorohydrins and an alkali metal glycerolate or an alkali metal diglycerolate at a temperature of between about 320.degree. K. and 410.degree. K. to yield a mixture of alkali metal chloride and glycerol and/or diglycerol and polyglyerol, (c) separating the alkali metal chloride from the glycerols and (d) separating the polyglycerol from glycerol and/or diglycerol.

    摘要翻译: 提供了一种制备聚甘油的方法,其包括以下步骤:(a)在约340℃至约410℃之间使甘油或双甘油与氯化氢反应,得到包含甘油的α-单氯醇或 二甘油的α-单氯醇,(b)在约320℃至410℃之间的温度下混合α-单氯醇和碱金属甘油酸酯或碱金属二甘油酸酯,得到碱金属氯化物和甘油的混合物, (c)从甘油中分离出碱金属氯化物,和(d)从甘油和/或双甘油中分离出聚甘油。