摘要:
A process for the preparation of mono-fatty acid or hydroxymono-fatty acid esters of isopropylidene derivatives of a polyglycerol is disclosed. A C6-C22 fatty acid or -hydroxy fatty acid is reacted with isopropylideneglycerol glycidyl ether or diisopropylidenetriglycerol glycidyl ether in a molar ratio of 0.5:1 to 1:0.5 at temperatures of 373473 K. in the presence of a catalyst. The monoisopropylidenediglycerol mono-fatty acid ester or monoisopropylidenediglycerol hydroxy mono-fatty acid ester or diisopropylidenetetraglycerol mono-fatty acid ester or diisopropylidenetetraglycerol hydroxy mono-fatty acid ester obtained is optionally purified by distillation, fractional distillation and/or ion exchange.
摘要:
A process for preparing a nonionic surfactant includes the steps of: cleaving at least one of the isopropylidene groups of an isopropylidene polyglycerol C.sub.6 -C.sub.22 -fatty acid or mono- or polyhydroxy fatty acid ester, by hydrolysis or ketal exchange, in the presence of acid, at a temperature in the range of about 20.degree. C. to about 100.degree. C., and at atmospheric, reduced or superatmospheric pressure, thereby regenerating hydroxyl groups on the polyglycerol; and recovering the resultant polyol ester nonionic surfactant. Such polyol ester surfactants are useful as emulsifiers, especially for preparing skin care or cosmetic formulations and paints and wood-preservation agents.
摘要:
The present invention relates to an underseal composition for motor vehicles, comprising a finely divided vinyl chloride homopolymer, copolymer, terpolymer or graft polymer, a plasticizer, a stabilizer, and a filler comprising calcium carbonate particles, wherein at least a part of said filler is provided with a surface coating formed by a surface treatment agent which comprises at least one saturated or unsaturated carboxylic acid, fatty acid or substituted fatty acid, said carboxylic acid or fatty acid having from 2 to 32 carbon atoms and containing at least one polar group in addition to at least one --COOH group, or a salt of said carboxylic acid or fatty acid. The underseal composition has improved rheological properties.
摘要:
The present invention relates to a polyvinyl chloride- based unplasticized molding composition which includes vinyl chloride homo-, co- and/or ter-polymer and/or mixtures or alloys thereof having a vinyl chloride or PVC content of more than 70% by weight, preferably more than 85% by weight, and 15 to 0% by weight of at least one impact-modifying polymer, which unplasticized molding composition includes, per 100 parts by weight of the PVC mixture if appropriate, pigments, colorants, lubricants, blowing agents, flame retardants, fillers, reinforcing fibers or other processing auxiliaries and the following additives:(a) 0.01 to 3 parts by weight of at least one calcium carboxylate,(b) 0.01 to 3 parts by weight of at least one zinc carboxylate,(c) 0.01 to 3 parts by weight of at least one organic co-stabilizer selected from at least one .beta.-diketone, at least one organic phosphite and/or at least one dihydropyridine, and(d) 0.01 to 5 parts by weight of at least one surface-modified alkaline earth metal oxide, at least one alkaline earth metal hydroxide and/or at least one partly hydrated alkaline earth metal oxide.The invention furthermore relates to the use of the molding composition and the process for its preparation.
摘要:
A process for the preparation of polyglycerols which are low in cyclic components comprises reacting glycerol or diglycerol or a higher polyglycerol with epichlorohydrin at elevated temperatures; adding base corresponding to the organically bound chlorine content of the reaction mixture, at a temperature of 50.degree.-120.degree. C., to the unseparated reaction mixture obtained; desalting the resultant reaction mixture and recovering glycerol, diglycerol and higher polyglycerols by fractional distillation.
摘要:
Disclosed is a composition and method for preserving wood and construction materials made of wood. The composition comprises more than about 65% by weight of at least one difficulty volatile organic-chemical solvent having a flash point higher than about 30.degree. C. and of between about 0.35% by weight and 10.0% by weight of a specific fungicidal agent which is soluble, or at least partly soluble, in the organic-chemical solvent. The specific fungicidal agent is a mixture of N,N-dimethyl-N'-phenyl-N'-(fluoro dichloro methylthio) sulfamide and N,N-dimethyl-N'-(p-tolyl)-N'-(fluoro dichloro methylthio) sulfamide, in the proportion, by weight, of between about 25:10 and 10:30 and preferably between about 15:10 and 10:15. If desired, between about 0.1% by weight and 7.0% by weight of a soluble insecticidal agent may be added to the composition.
摘要:
Vertically oriented cathode grids or cathode plates, adjacently situated at closely spaced intervals in a cathode box, are cleaned by spraying jets of liquid onto the cathode surfaces at an angle of about 10.degree.-50.degree. and at a pressure of about 60 to 140 atmospheres, while moving the liquid jets uniformly along the cathode surfaces. A device for performing this process comprises a bar shaped spraying means comprising spraying nozzles which are connected to pressure resistent feeding means for the liquid. The spraying means is connected to a guiding system comprising a bar shaped first guiding means, a second guiding means including a guiding bar and a guiding cylinder and a third guiding means and moving means mounted on a support which can be moved over the cathode box and which further comprises means for aligning the guiding system and the spraying means to the cathode box in such a way that the spraying means can be moved uniformly along the cathode surfaces by means of the guiding means and the moving means.
摘要:
The present invention relates to a washing agent, cleansing agent and/or toiletry containing at least one ionic and/or amphoteric surfactant and at least one C.sub.8 to C.sub.18 fatty acid monoester of diglycerol and/or C.sub.8 to C.sub.18 fatty acid diester of tetraglycerol as a constituent of the mixture, 2 to 30% by weight, perferably 10 to 20% by weight, of at least one fatty acid monoester of diglycerol and/or fatty acid diester of tetraglycerol, relative to the total surfactant content (100% by weight), being present in the surfactant mixture. The agent is employed together with certain compositions, in particular with a solvent, additives and the like. The invention also relates to the preparation of the washing agent, cleansing agent and/or toiletry and to its use as a shower preparation, bubble bath preparation, liquid hand cleanser or hair shampoo.
摘要:
A process for the preparation of fatty acid or hydroxy fatty acid esters of isopropylidene derivatives of a polyglycerol involves reacting C.sub.1 -C.sub.4 -alkyl esters of C.sub.6 -C.sub.22 -fatty acids or mono- or polyhydroxy fatty acids in alkaline medium with one or more hydroxyl-containing isopropylidene derivatives of a polyglycerol. The resultant fatty acid or hydroxy fatty acid esters of mono- and/or diisopropylidene derivatives of polyglycerol are useful as intermediates for the preparation of nonionic surfactants, as solvents or solubilizing agents and for cosmetic formulations and skin care preparations.
摘要:
A process for preparation of polyglycerol is provided, comprising the steps of (a) reacting glycerol or diglycerol with hydrogen chloride at between about 340.degree. K. and about 410.degree. K. to yield a mixture that comprises an .alpha.-monochlorohydrin of glycerol or an .alpha.-monochlorohydrin of diglycerol, (b) mixing the .alpha.-monochlorohydrins and an alkali metal glycerolate or an alkali metal diglycerolate at a temperature of between about 320.degree. K. and 410.degree. K. to yield a mixture of alkali metal chloride and glycerol and/or diglycerol and polyglyerol, (c) separating the alkali metal chloride from the glycerols and (d) separating the polyglycerol from glycerol and/or diglycerol.