Coating powder for high temperature resistant coatings
    3.
    发明授权
    Coating powder for high temperature resistant coatings 失效
    高温涂料用涂料粉末

    公开(公告)号:US6034178A

    公开(公告)日:2000-03-07

    申请号:US163962

    申请日:1998-09-30

    IPC分类号: C09D183/04 C08L83/06

    摘要: A coating powder for producing a high temperature resistant coating has a resin system which comprises (A) between about 50 and about 93 wt % based on total of (A) plus (B) of a silicone resin and (B) between about 7 and about 50 wt % based on total weight of (A) plus (B) of a polyhydroxyl component. The silicone resin (A) of the coating powder has organic substitutents selected from the group consisting of phenyl, methyl, C.sub.2 through C.sub.6 alkyl and mixtures thereof. The silicone resin has a viscosity of between about 500 and about 10,000 cps at 150.degree. C., a condensable hydroxyl content of between about 2 and about 4.5 wt %, and a glass transition temperature (T.sub.g) of about 55.degree. C. or above. The silicone resin preferably contains about 0.2% or less of organic solvents. The polyhydroxyl component (B) is a polyhydroxyl compound or blends of polyhydroxyl compounds with average hydroxyl equivalent weight of between 100 and 500, containing an average of at least three hydroxyl groups per molecule, and of number average molecular weight between 300 and 20,000. The blend of the silicone resin (A) and polyhydroxyl component (B) should have a combined glass transition temperature (T.sub.g) of at least about 50.degree. C.

    摘要翻译: 用于生产耐高温涂层的涂料粉末具有树脂体系,其包含(A)基于(A)加(B)总硅氧烷树脂的总重量为约50至约93重量%,和(B)约7至 基于(A)加(B)多羟基组分的总重量为约50重量%。 涂层粉末的有机硅树脂(A)具有选自苯基,甲基,C 2至C 6烷基及其混合物的有机取代基。 硅树脂在150℃下的粘度为约500至约10,000cps,约2至约4.5重量%的可冷凝羟基含量和约55℃或更高的玻璃化转变温度(Tg) 。 有机硅树脂优选含有约0.2%以下的有机溶剂。 多羟基组分(B)是多羟基化合物或平均羟基当量重量为100-500的多羟基化合物的共混物,每分子平均含有至少三个羟基,数均分子量在300至20,000之间。 有机硅树脂(A)和多羟基组分(B)的共混物应具有至少约50℃的组合玻璃化转变温度(Tg)

    Flexible, weatherable, acrylic coating powder
    5.
    发明授权
    Flexible, weatherable, acrylic coating powder 失效
    柔性,耐候性,丙烯酸涂层粉

    公开(公告)号:US6022927A

    公开(公告)日:2000-02-08

    申请号:US990936

    申请日:1997-12-15

    摘要: Coating powder compositions comprise A) between about 60 and about 90 wt %, relative to total weight of A) plus B) plus C), of an acrylic polymer having a weight average molecular weight of between about 1000 and about 30,000, a carboxylic acid equivalent weight of from about 300 to about 1000 and a glass transition temperature of about 45.degree. C. or above and B) between about 5 and about 30 wt %, relative to total weight of A) plus B) plus C) of an adduct prepared from i) between about 20 and about 50 wt %, relative to total weight of i) plus ii), of a curing agent reactive with carboxylic acid groups and ii) between about 50 and about 80 wt %, relative to total weight of i) plus ii), of a polyester resin formed primarily from linear aliphatic diols and dicarboxylic acids, the polyester having functional groups reactive with said curing agent i), and C) between about 2 and about 30 wt % relative to the total weight of A) plus B) plus C) of a curing agent reactive with carboxylic acid groups. The sum of un-reacted functional groups of adduct B) plus curing agent C) is at a stoichiometric equivalent relative to said carboxylic acid functionality of said acrylic polymer A) of between about 0.5 and about 1.5. Using sufficient amounts of an appropriate cure catalyst, the composition may be fused and cured at temperatures of 300.degree. F. or below, even 250.degree. C. or below, making the coating composition suitable for coating wood and wood products.

    摘要翻译: 涂料粉末组合物包含相对于重量平均分子量为约1000至约30,000的丙烯酸类聚合物的A)+ B)+ C)的总重量为约60至约90重量%的羧酸 约300至约1000的当量,玻璃化转变温度约45℃或更高,B)约5至约30重量%,相对于A)加B)加C)加合物的总重量 从i)制备约20至约50重量%,相对于i)加ii)的总重量,与羧酸基团反应的固化剂和ii)约50至约80重量%,相对于 i)加ii),主要由直链脂族二醇和二羧酸形成的聚酯树脂,具有与所述固化剂i)反应的官能团的聚酯,和C)相对于所述固化剂的总重量为约2至约30重量% A)加B)加C)与羧酸反应的固化剂g 。。 加合物B)加固化剂C)的未反应的官能团的总和相对于所述丙烯酸类聚合物A)的所述羧酸官能度为约0.5至约1.5的化学计量当量。 使用足够量的合适的固化催化剂,组合物可以在300°F或更低,甚至250℃或更低的温度下熔融和固化,使涂料组合物适合涂布木材和木制品。

    Coating powder for high temperature resistant coatings
    6.
    发明授权
    Coating powder for high temperature resistant coatings 失效
    高温涂料用涂料粉末

    公开(公告)号:US5998560A

    公开(公告)日:1999-12-07

    申请号:US126186

    申请日:1998-07-30

    摘要: A coating powder for providing a high temperature resistance coating has a silicone resin binder system which is either substantially all silicone resin or an --OH-- functional silicone resin adduct plus blocked, multi --NCO functional curative. The coating powder is pigmented with titanium dioxide which is either non-coated or coated with a sufficiently low level of an inorganic oxide such that when slurried in water, the pH is 7 or above. The coating powder preferably contains at least 40 phr mica and/or calcium metasilicate, preferably between 2 and about 20 phr aluminum. The coating powder may also contain zinc to protect the underlying substrate from corrosion and high-temperature pigments, particularly ceramic pigments.

    摘要翻译: 用于提供耐高温涂层的涂层粉末具有硅树脂粘合剂体系,其基本上是所有硅树脂或-OH官能的硅树脂加合物加封闭的多-NCO功能性固化剂。 涂层粉末用二氧化钛着色,二氧化钛是未涂覆的或涂覆有足够低水平的无机氧化物,使得当在水中浆化时,pH为7或更高。 涂层粉末优选含有至少40phr云母和/或偏硅酸钙,优选2至约20phr的铝。 涂层粉末还可以含有锌以保护下面的基材免受腐蚀和高温颜料,特别是陶瓷颜料。

    Photoimageable composition having improved photoinitiator system
    7.
    发明授权
    Photoimageable composition having improved photoinitiator system 失效
    具有改进的光引发剂体系的可光成像组合物

    公开(公告)号:US5939238A

    公开(公告)日:1999-08-17

    申请号:US88561

    申请日:1998-06-02

    摘要: The invention provides a negative-acting photoimageable composition comprising A) between about 30 and about 80 wt % based on total weight of A) plus B) of a binder polymer having acid functionality sufficient to render said photoimageable composition developable in alkaline aqueous solution, B) between about 20 and about 70 wt % based on total weight of A) plus B) of an addition-polymerizeable, non-gaseous .alpha.,.beta.-ethylenically unsaturated compound(s) capable of forming a high polymer by free-radical initiated chain-propagating addition polymerization, at least about 50 mole percent of the .alpha.,.beta.-ethylenically unsaturated moieties of B) being methacrylic moieties, and C) between about 0.1 and about 20 wt % based on total weight of A) plus B) of a photoinitiator chemical system, the photoinitiator chemical system comprising between about 0.005 and about 3 wt % relative to total weight of A) plus B) of triphenyphosphine and between about 0.005 and about 2 wt % relative to total weight of A) plus B) of n-phenylglycine.

    摘要翻译: 本发明提供一种负性光学成像组合物,其包含A)约30至约80重量%,基于A)和B)的总重量,其具有足以使所述可光成像组合物在碱性水溶液中显影的酸官能度的粘合剂聚合物B )约20至约70重量%,基于A)加B)的能够由自由基引发的链形成高聚物的可加成聚合的非气态α,β-烯属不饱和化合物的总重量 - 活化加成聚合,B)的α-,β-烯属不饱和部分的至少约50摩尔%为甲基丙烯酸部分,和C)约0.1至约20重量%,基于A)加B)的总重量 光引发剂化学系统,光引发剂化学体系相对于A)加B)三苯膦的总重量为约0.005至约3重量%,相对于t为约0.005至约2重量% A)加B)的正 - 苯基甘氨酸的重量。

    Salt pelletizing method
    8.
    发明授权
    Salt pelletizing method 失效
    盐造粒法

    公开(公告)号:US5935496A

    公开(公告)日:1999-08-10

    申请号:US909891

    申请日:1997-08-12

    申请人: Kurt J. Waatti

    发明人: Kurt J. Waatti

    CPC分类号: B01J49/0086 C01D3/22

    摘要: A water soluble dicarboxylic acid or an alkali metal salt thereof acts as a mold release agent for salt pellets when a salt-contacting surface of a roll-type briquetting press is coated with from about 0.02 to about 5 mg/cm.sup.2 of a powder of the acid or alkali metal salt just prior to a charge of salt. The coating is achieved by spraying an air stream entraining the powder onto the press rolls or by spraying a solution of the release agent onto the rolls and evaporating the solvent to leave the powder on the rolls. The acid has from 6 to 10 carbon atoms; adipic acid being preferred. Salt pellets having a layer of the powder on their surface may be used in water softening systems wherein the pellets sit in a brine reservoir and supply salt for the recharging of an ion exchange resin. There is no formation of an unsightly scum on the surface of the brine and on the sides of the reservoir.

    摘要翻译: 当水溶性二羧酸或其碱金属盐作为盐粒的脱模剂时,当辊式压块机的盐接触表面涂覆约0.02至约5mg / cm 2的粉末时, 酸盐或碱金属盐就在盐的充电之前。 通过将夹带粉末的空气流喷射到压辊上或通过将脱模剂的溶液喷雾到辊上并蒸发溶剂以将粉末留在辊上来实现涂层。 该酸具有6至10个碳原子; 己二酸是优选的。 在其表面具有一层粉末的盐粒料可用于水软化系统中,其中颗粒位于盐水储存器中并供应盐以便为离子交换树脂再充电。 在盐水表面和储层两侧不形成难看的浮渣。

    Polyurethane binder for a magnetic recording medium
    10.
    发明授权
    Polyurethane binder for a magnetic recording medium 失效
    用于磁记录介质的聚氨酯粘合剂

    公开(公告)号:US5891578A

    公开(公告)日:1999-04-06

    申请号:US966690

    申请日:1997-11-10

    摘要: A polyurethane prepared from a functionalized polyol has superior hydrolytic stability and dispersive capacity which makes it useful as a binder for magnetic particles in a magnetic recording medium. The functionalized polyol may be one of the group consisting of a polyesterdiol, a polyetherdiol, a polycaprolactone diol and a polycarbonate diol, each of which incorporates a functional group having the formula: ##STR1## wherein M is a methylene group or nitrogen, R and R.sup.1 are the same or different alkylene groups having from 1 to 7 carbon atoms, R.sup.2 is an alkylene group having from 1 to 7 carbon atoms, and R.sup.3 and R.sup.4 are the same or different alkyl groups having from 1 to 7 carbon atoms, and X is an anion of a Br.o slashed.nsted acidin an amount such that the polyurethane contains from about 8 to about 32 gram moles of the functional group per 1.times.10.sup.6 grams of the polyurethane. The polyurethane may be made by heating a mixture of a Br.o slashed.nsted acid salt of a carboxylic acid terminated aminoester, a stoichiometric excess of a glycol, and a dicarboxylic acid to make a functionalized polyesterdiol and curing a mixture of said polyesterdiol and a diisocyanate.

    摘要翻译: 由官能化多元醇制备的聚氨酯具有优异的水解稳定性和分散能力,使其可用作磁记录介质中的磁性颗粒的粘合剂。 官能化多元醇可以是聚酯二醇,聚醚二醇,聚己内酯二醇和聚碳酸酯二醇之一,它们各自含有下式的官能团:其中M是亚甲基或氮, R和R 1是具有1至7个碳原子的相同或不同的亚烷基,R 2是具有1至7个碳原子的亚烷基,并且R 3和R 4是相同或不同的具有1至7个碳原子的烷基, 并且X是Br + 526 nsted酸的阴离子,其量使得每1×10 6克聚氨酯含有约8至约32克摩尔官能团。 聚氨酯可以通过加热羧酸封端的氨基酯的Br + 526起始酸盐,化学计量过量的二醇和二羧酸的混合物制成官能化的聚酯二醇并固化所述聚酯二醇和二异氰酸酯的混合物 。