公开(公告)号：US20160130732A1

公开(公告)日：2016-05-12

申请号：US14897924

申请日：2014-07-24

申请人： TOHO TENAX CO., LTD.

发明人： Yoshinori SUZUKI

IPC分类号： D01F9/22

CPC分类号： D01F9/22 ,  C01B32/05 ,  C01B32/26 ,  D01F9/14 ,  D01F9/32 ,  D10B2101/12

摘要： A carbonization method of carbonizing precursor fibers that are being conveyed includes carbonization performed using a plurality of carbonization furnaces for heating fibers arranged in the direction in which the fibers are conveyed. The plurality of carbonization furnaces include at least one carbonization furnace that heats the fibers using plasma when the fibers are passing through the inside of the at least one carbonization furnace. A carbon fiber production method includes a carbonization process of carbonizing precursor fibers that are being conveyed. The carbonization process is performed with the above carbonization method.

摘要翻译： 正在输送的碳化前体纤维的碳化方法包括使用多个碳化炉进行碳化，所述碳化炉用于加热沿着纤维被输送的方向布置的纤维。 多个碳化炉包括至少一个碳化炉，其在纤维通过至少一个碳化炉的内部时使用等离子体加热纤维。 碳纤维的制造方法包括碳化前体纤维的碳化处理。 通过上述碳化法进行碳化处理。

公开(公告)号：US20130157171A1

公开(公告)日：2013-06-20

申请号：US13819023

申请日：2011-08-24

申请人： Kazuma Kurokawa ,  Tetsuya Akamatsu

发明人： Kazuma Kurokawa ,  Tetsuya Akamatsu

IPC分类号： H01M4/86

CPC分类号： H01M4/8605 ,  H01B1/24 ,  H01M4/8652 ,  H01M8/0234 ,  H01M8/0239 ,  H01M8/0243 ,  H01M8/0245 ,  Y02E60/50 ,  Y02P70/56

摘要： A conductive sheet comprises an aromatic polyamide pulp, a fluoroplastic fused to the aromatic polyamide pulp, and a carbon-based conductive material; wherein the conductive sheet has a static contact angle of water on a first surface that is greater than the static contact angle of water on a second surface that in the opposite surface to the first surface, and the difference between the static contact angle of water on the first surface and the static contact angle of water on the second surface is 20°-180°; or wherein the injection pressure of water on the first surface of the conductive sheet is less than the injection pressure of water on the second surface that is the opposite surface to the first surface, and the difference between the injection pressure of water on the first surface and the injection pressure of water on the second surface is 20-50 kPa.

摘要翻译： 导电片包括芳族聚酰胺纸浆，与芳族聚酰胺纸浆熔合的氟塑料和碳基导电材料; 其中所述导电片具有在第一表面上的水的静态接触角，其大于在与所述第一表面相反的表面中的第二表面上的水的静态接触角，以及水的静态接触角之间的差 第二表面水面的第一表面和静态接触角为20°-180°; 或者其中导电片的第一表面上的水的注射压力小于在与第一表面相反的表面的第二表面上的水的注射压力，以及第一表面上的水的注射压力之间的差 第二表面上的水的注入压力为20-50kPa。

公开(公告)号：US08236273B2

公开(公告)日：2012-08-07

申请号：US12747386

申请日：2008-12-10

申请人： Taro Oyama ,  Rie Kawahito ,  Hiroshi Kimura

发明人： Taro Oyama ,  Rie Kawahito ,  Hiroshi Kimura

IPC分类号： D01F9/12

CPC分类号： D01F9/225

摘要： There is disclosed a method of producing a pre-oxidation fiber in the production of the pre-oxidation fiber by subjecting a polyacrylic precursor fiber to pre-oxidation processing in an oxidizing atmosphere, including shrinking the precursor fiber as a pretreatment of pre-oxidation at a load of 0.58 g/tex or less in the temperature range of 220 to 260° C. under conditions in which the degree of cyclization (I1620/I2240) of the precursor fiber measured by a Fourier transform infrared spectrophotometer (FT-IR) does not exceed 7%, initially-drawing the precursor fiber at a load of 2.7 to 3.5 g/tex in an oxidizing atmosphere at 230 to 260° C. in the ranges of the degree of cyclization of not exceeding 27% and of the density of not exceeding 1.2 g/cm3, and then subjecting the pre-oxidation fiber to pre-oxidation treatment. A carbon fiber of high strength and high elasticity that is appropriate for composite materials that exhibit high composite performance is obtained by continuously subjecting this pre-oxidation fiber to carbonization treatment.

摘要翻译： 公开了通过在氧化气氛中对聚丙烯酸前驱体纤维进行预氧化处理来制造预氧化纤维的方法，包括将前体纤维收缩为预氧化的预处理 在通过傅立叶变换红外分光光度计（FT-IR）测量的前体纤维的环化度（I1620 / I2240）的条件下，在220〜260℃的温度范围内的负载为0.58g / tex以下 不超过7％，首先在230〜260℃的氧化性气氛中，在2.7〜3.5g / tex的负荷下拉伸前体纤维，其环化度不超过27％，密度为 不超过1.2g / cm 3，然后对预氧化纤维进行预氧化处理。 通过对该预氧化纤维进行碳化处理，可以获得适用于复合性高的复合材料的高强度，高弹性的碳纤维。

公开(公告)号：US20060154039A1

公开(公告)日：2006-07-13

申请号：US10543137

申请日：2004-01-28

申请人： Yoshinori Suzuki ,  Yutaka Miura ,  Katsura Horikoshi ,  Mitsuhiro Yada

发明人： Yoshinori Suzuki ,  Yutaka Miura ,  Katsura Horikoshi ,  Mitsuhiro Yada

IPC分类号： D04H13/00

CPC分类号： C08J5/24 ,  C08G59/1461 ,  Y10T428/249924 ,  Y10T428/2913 ,  Y10T428/2933

摘要： The present invention discloses: a composition comprising (A) an epoxy group-containing vinyl ester resin having, in the molecule, 0.8 to 0.3 equivalent of epoxy group and 0.2 to 0.7 equivalent of an ethylenically unsaturated group, (B) a radical-polymerizable monomer, (C) a curing agent, and (D) a carbon fiber impregnated with 0.5 to 5% by mass of (d) a vinyl ester resin as a sizing agent, obtained by an addition reaction of an epoxy resin and an ethylenically unsaturated carboxylic acid, and a carbon fiber-reinforced resin composite material produced by curing the above composition.

公开(公告)号：US09181640B2

公开(公告)日：2015-11-10

申请号：US13583137

申请日：2011-02-28

申请人： Hiroshi Tsunekawa ,  Takao Saeki ,  Akio Yoshida

发明人： Hiroshi Tsunekawa ,  Takao Saeki ,  Akio Yoshida

IPC分类号： D02G3/02 ,  D02G3/16 ,  D06M15/59 ,  B29B9/14 ,  D02G3/26 ,  D06M101/40 ,  B29C47/00 ,  B29K105/12 ,  C08K9/08 ,  C08K7/06 ,  C08L77/00 ,  B29B9/06

CPC分类号： D02G3/16 ,  B29B9/06 ,  B29B9/14 ,  B29C47/0011 ,  B29K2105/12 ,  C08K7/06 ,  C08K9/08 ,  C08L77/00 ,  D02G3/26 ,  D06M15/59 ,  D06M2101/40 ,  D10B2101/12 ,  Y10T428/1334 ,  Y10T428/2918

摘要： Disclosed is a carbon-fiber chopped strand, and a manufacturing method of the same. The carbon-fiber chopped strand is composed of single filaments composed of 30,000-120,000 carbon fibers, and a sizing agent content 1-10% by weight that bundles the single filaments; the ratio of maximum diameter (Dmax) in the cross section and minimum diameter (Dmin) is 1.0-1.8, a length along a fiber direction is 3-10 mm, and a repose angle of 10-30°.

摘要翻译： 公开了一种碳纤维短切丝及其制造方法。 碳纤维切断线由30,000〜120,000个碳纤维构成的单丝，以及将单根丝捆成1〜10重量％的上浆剂; 横截面的最大直径（Dmax）和最小直径（Dmin）的比率为1.0-1.8，沿纤维方向的长度为3-10mm，休止角为10-30°。

公开(公告)号：US08211537B2

公开(公告)日：2012-07-03

申请号：US12594278

申请日：2008-04-11

申请人： Yasuyuki Yokoe ,  Toru Kaneko ,  Hiroshi Numata ,  Takeshi Shimada

发明人： Yasuyuki Yokoe ,  Toru Kaneko ,  Hiroshi Numata ,  Takeshi Shimada

IPC分类号： B32B27/04 ,  B32B27/20 ,  B32B27/26 ,  B32B27/38 ,  C08L63/00 ,  B29C70/02

CPC分类号： C08J5/24 ,  C08G59/504 ,  C08J3/241 ,  C08J2363/00 ,  C08K5/41 ,  C08L63/00 ,  C08L2205/14 ,  Y10T156/10 ,  Y10T428/24994 ,  Y10T428/249948 ,  Y10T428/24995 ,  Y10T428/249952 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/2938 ,  Y10T428/31511 ,  Y10T428/31515 ,  C08L2666/02

摘要： The present invention discloses a resin composition and a prepreg produced using the resin composition. The resin composition comprises, as essential components: 100 parts by mass of a component (A) which is an epoxy resin; 41 to 80 parts by mass of a component (B) which is thermoplastic resin particles; and 20 to 50 parts by mass (in terms of diaminodiphenylsulfone) of a component (C) which is diaminodiphenylsulfone microencapsulated with a coating agent. The thermoplastic resin particles (B) comprise at least thermoplastic resin particles (B1) having an average particle diameter of 1 to 50 μm and thermoplastic resin particles (B2) having an average particle diameter of 2 to 100 μm at a mass ratio of 3:1 to 1:3. The average particle diameter ratio D2/D1 of the average particle diameter D2 of the thermoplastic resin particles (B2) to the average particle diameter D1 of the thermoplastic resin particles (B1) is 2 or more.

摘要翻译： 本发明公开了使用该树脂组合物制造的树脂组合物和预浸料坯。 作为必要成分，树脂组合物含有作为环氧树脂的成分（A）100质量份， 41〜80质量份作为热塑性树脂粒子的成分（B） 和20〜50质量份（以二氨基二苯砜换算）作为用包衣剂微胶囊化的二氨基二苯砜的组分（C）。 热塑性树脂颗粒（B）至少包含平均粒径为1至50μm的热塑性树脂颗粒（B1）和平均粒径为2至100μm的热塑性树脂颗粒（B2），质量比为3： 1比1：3。 热塑性树脂粒子（B2）的平均粒径D2与热塑性树脂粒子（B1）的平均粒径D1的平均粒径比D2 / D1为2以上。

公开(公告)号：US08129017B2

公开(公告)日：2012-03-06

申请号：US12740043

申请日：2008-10-31

申请人： Hidekazu Yoshikawa ,  Taro Oyama ,  Hiroshi Kimura

发明人： Hidekazu Yoshikawa ,  Taro Oyama ,  Hiroshi Kimura

IPC分类号： B32B9/00

CPC分类号： D02J1/08 ,  D01F9/22 ,  D01F11/16 ,  D02J1/22 ,  D02J1/222 ,  Y10T428/2918

摘要： A carbon fiber strand obtained by bundling 20,000-30,000 carbon fibers each having, in the surface thereof, creases which are parallel to the fiber-axis direction. In an examination with a scanning probe microscope, the creases in the carbon fiber surface are apart from each other at a distance of 120-160 nm and have a depth of 12-23 nm, excluding 23 nm. The carbon fibers have an average fiber diameter of 4.5-6.5 nm, specific surface area of 0.9-2.3 m2/g, and density of 1.76 g/cm3 or higher. The carbon strand has a tensile strength of 5,900 MPa or higher and a tensile modulus of 300 GPa or higher. When would on a bobbin at a tension of 9.8 N, the strand on the bobbin has a width of 5.5 mm or larger. When the carbon fiber strand is examined by a strand splitting evaluation method in which the strand is caused to run through three stainless-steel rods while applying a tension of 9.8 N thereto, no strand splitting is observed.

摘要翻译： 通过将20,000-30,000个碳纤维捆扎在其表面上而获得的碳纤维股线，其平行于纤维轴线方向的折痕。 在使用扫描探针显微镜的检查中，碳纤维表面的折痕在120-160nm的距离处彼此分开，并且深度为12-23nm，不包括23nm。 碳纤维的平均纤维直径为4.5-6.5nm，比表面积为0.9-2.3m2 / g，密度为1.76g / cm 3以上。 碳线的拉伸强度为5900MPa以上，拉伸弹性模量为300GPa以上。 当绕线轴处于9.8N的张力时，线轴上的绞线宽度为5.5mm或更大。 当通过线分裂评估方法检查碳纤维股线时，其中使股线穿过三根不锈钢棒，同时施加9.8N的张力，不观察到股线分裂。

公开(公告)号：US20110104489A1

公开(公告)日：2011-05-05

申请号：US12674995

申请日：2008-09-17

申请人： Michael Wolki ,  Bernd Wohlmann ,  Mathias Kaiser ,  Rudolf Emmerich ,  Frank Henning

发明人： Michael Wolki ,  Bernd Wohlmann ,  Mathias Kaiser ,  Rudolf Emmerich ,  Frank Henning

IPC分类号： D02G3/02 ,  C01B31/02 ,  D02G3/22

CPC分类号： B01D71/021 ,  B01D67/0067 ,  B01D69/08 ,  B01D69/081 ,  B01D2323/42 ,  B01D2325/40 ,  D01D5/24 ,  D01F9/225 ,  Y10T428/2918

摘要： A process for the production of hollow carbon fibres by the treatment of a stabilised carbon fibre precursor in an application device using high-frequency electromagnetic waves. The application device includes structure supplying the electromagnetic waves to a outcoupling region and a hollow outer conductor terminating in the outcoupling region. For the treatment, a field of the high-frequency electromagnetic waves is generated and a field strength in the range from 15 to 40 kV/m is set in the outcoupling region of the application device. The stabilised carbon fibre precursor is conveyed continuously as an inner conductor through the hollow outer conductor, thereby forming a coaxial conductor having an outer and an inner conductor, and through the subsequent outcoupling region. An inert gas atmosphere is created in the coaxial conductor and in the outcoupling region by passing through an inert gas.

摘要翻译： 一种通过在使用高频电磁波的应用装置中处理稳定的碳纤维前体来生产中空碳纤维的方法。 应用装置包括将电磁波提供给输出耦合区域和终止于输出耦合区域的中空外部导体的结构。 为了处理，产生高频电磁波的场，并且在应用装置的输出耦合区域中设定在15至40kV / m范围内的场强。 稳定的碳纤维前体作为内导体通过中空外导体连续输送，从而形成具有外导体和内导体的同轴导体，并通过随后的外耦合区域。 在同轴导体和外耦合区域中通过惰性气体产生惰性气体气氛。

公开(公告)号：US07335018B2

公开(公告)日：2008-02-26

申请号：US10276331

申请日：2002-03-20

申请人： Masanao Yamaguchi

发明人： Masanao Yamaguchi

IPC分类号： F27B9/28

CPC分类号： D01F9/32

摘要： A heat treatment apparatus for oxidation having an oven for oxidation having a heat treatment chamber having a plurality of slits through which fiber strands running horizontally leave or returned strands enter and capable of sending hot air vertically from above the fiber strands to allow the fiber strands to have oxidation, and a device for feeding hot air into the heat treatment chamber, and a plurality of returning rollers which are provided at the two outsides of the oven for oxidation and which return the fiber strands entering and leaving through said slits, into the oven for oxidation, wherein each gap formed between fiber strands and each side wall of heat treatment chamber parallel to the running direction of fiber strands running in the heat treatment chamber, or each gap formed between fiber strands and each channeling-preventing plate interposed between the side wall and the fiber strands in parallel to the running direction of fiber strands is set at 150 mm or less. The slits may be provided with a device for injecting hot air into the heat treatment chamber.

摘要翻译： 一种用于氧化的热处理装置，具有具有多个狭缝的热处理室的热处理装置，通过该狭缝，水平运行的纤维束离开或返回的线进入并能够从纤维线上方垂直地发送热空气，以使纤维束 具有氧化，以及用于将热空气供给到热处理室中的装置，以及多个返回辊，其设置在炉的两个外部以进行氧化，并且使通过所述狭缝进入和离开的纤维束返回到烘箱中 用于氧化，其中在纤维束和热处理室的每个侧壁之间形成的每个间隙平行于在热处理室中运行的纤维束的运行方向，或者每个间隙形成在纤维束之间，每个间隙介于侧面 并且与纤维束的运行方向平行的纤维束设定为150mm以下。 狭缝可以设置有用于将热空气注入到热处理室中的装置。

公开(公告)号：US20050271874A1

公开(公告)日：2005-12-08

申请号：US10523511

申请日：2003-10-24

申请人： Kouichi Sakajiri ,  Takao Saeki ,  Shinichi Muto ,  Isao Nishimura ,  Toshitsugu Matsuki

发明人： Kouichi Sakajiri ,  Takao Saeki ,  Shinichi Muto ,  Isao Nishimura ,  Toshitsugu Matsuki

IPC分类号： B29B15/12 ,  D06M15/55 ,  D02G3/00

CPC分类号： D06M15/55 ,  B29K2063/00 ,  D06M2101/40 ,  D06M2200/40 ,  D06M2200/50 ,  Y10T428/2913

摘要： A sizing agent for carbon fiber consisting of a reaction products containing an unsaturated urethane compound as the principal component obtained by reacting an unsaturated alcohol with an isocyanate compound is disclosed in claim 1.

摘要翻译： 权利要求1中公开了一种由含有不饱和氨基甲酸酯化合物作为主要成分的反应产物所组成的碳纤维上浆剂作为不饱和醇与异氰酸酯化合物的反应。