Abstract:
Reaction schemes involving acids and bases; reactors comprising spatially varying chemical composition gradients (e.g., spatially varying pH gradients), and associated systems and methods, are generally described.
Abstract:
Systems and methods are provided for capturing CO2 from a combustion source using molten carbonate fuel cells (MCFCs). At least a portion of the anode exhaust can be recycled for use as part of anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO2 from the combustion source exhaust and/or modifications in how the fuel cells can be operated.
Abstract:
In various aspects, systems and methods are provided for integration of molten carbonate fuel cells with a methanol synthesis process. The molten carbonate fuel cells can be integrated with a methanol synthesis process in various manners, including providing synthesis gas for use in producing methanol. Additionally, integration of molten carbonate fuel cells with a methanol synthesis process can facilitate further processing of vent streams or secondary product streams generated during methanol synthesis.
Abstract:
A method in which a parent hydrocarbon-rich material is processed so as to produce both a carbon-rich solid material that has a higher carbon to hydrogen ratio than that of the parent material and a carbon-deficient combustible gas that has a lower carbon to hydrogen ratio than the parent material. In the process, the material is activated by exposing it to a hot gas stream having elevated levels of one or both of carbon dioxide and water vapor. The combustible gas is combusted to produce heat. At least about 80% of the heat is used in one ore more endothermic steps that include drying coal or biomass.
Abstract:
Systems and methods are provided for capturing CO2 from a combustion source using molten carbonate fuel cells (MCFCs). The fuel cells are operated to have a reduced anode fuel utilization. Optionally, at least a portion of the anode exhaust is recycled for use as a fuel for the combustion source. Optionally, a second portion of the anode exhaust is recycled for use as part of an anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO2 from the combustion source exhaust and/or modifications in how the fuel cells are operated.
Abstract:
Systems and methods are provided for capturing CO2 from a combustion source using molten carbonate fuel cells (MCFCs). The fuel cells are operated to have a reduced anode fuel utilization. Optionally, at least a portion of the anode exhaust is recycled for use as a fuel for the combustion source. Optionally, a second portion of the anode exhaust is recycled for use as part of an anode input stream. This can allow for a reduction in the amount of fuel cell area required for separating CO2 from the combustion source exhaust and/or modifications in how the fuel cells are operated.
Abstract:
In various aspects, systems and methods are provided for operating a molten carbonate fuel cell assembly at increased power density. This can be accomplished in part by performing an effective amount of an endothermic reaction within the fuel cell stack in an integrated manner. This can allow for increased power density while still maintaining a desired temperature differential within the fuel cell assembly.
Abstract:
In various aspects, systems and methods are provided for integration of molten carbonate fuel cells with processes for synthesis of nitrogen-containing compounds. The molten carbonate fuel cells can be integrated with a synthesis process in various manners, including providing hydrogen for use in producing ammonia. Additionally, integration of molten carbonate fuel cells with a methanol synthesis process can facilitate further processing of vent streams or secondary product streams generated during synthesis of nitrogen-containing compounds.
Abstract:
The disclosure relates to a method to produce electricity in a cement clinker production utilizing a kiln and/or a precalciner as combustion chambers to generate electricity, the method including:a. supplying fuel to the precalciner and/or the kiln in a quantity corresponding to at least 110% of a heat value requirement for clinker production operation of the precalciner and/or the rotary kiln per unit weight of clinker, respectively;b. bypassing a portion of hot flue gases from at least one of (i) the kiln and/or (ii) the precalciner;c. leading hot flue gases to a heat recovery steam generator producing steam;d. producing electricity with a power island including a steam turbine equipped with an electrical generator.
Abstract:
A method and an apparatus for manufacturing of cement includes cement raw meal being preheated in a preheater, calcined in a calciner by contact with hot gases which are introduced into the calciner via a gas inlet and being diverted from the calciner via a gas outlet, and where calcined cement raw meal is diverted from the calciner, burned into cement clinker in a kiln and subsequently cooled in a clinker cooler. At least a portion of the calcined cement raw meal diverted from the calciner is heated further in a separate system to a temperature which exceeds the calcination temperature and is subsequently recirculated to the calciner. That at least a portion of the gases which are diverted via the gas outlet of the calciner is removed from the plant with a view to storage underground or other additional treatment.