公开(公告)号：US20230332309A1

公开(公告)日：2023-10-19

申请号：US18248840

申请日：2021-10-14

申请人： KYOTO UNIVERSITY ,  NATIONAL UNIVERSITY CORPORATION YOKOHAMA NATIONAL UNIVERSITY ,  DE NORA PERMELEC LTD

发明人： Yoshiharu UCHIMOTO ,  Tomoki UCHIYAMA ,  Shigenori MITSUSHIMA ,  Yoshiyuki KURODA ,  Kensaku NAGASAWA ,  Yoshinori NISHIKI

IPC分类号： C25B11/077 ,  C25B11/061 ,  B01J23/889 ,  B01J37/14 ,  C25B1/04

CPC分类号： C25B11/0773 ,  C25B11/061 ,  B01J23/889 ,  B01J37/14 ,  C25B1/04

摘要： The present invention provides an alkaline water electrolysis anode such that even when electric power having a large output fluctuation, such as renewable energy, is used as a power source, the electrolysis performance is unlikely to be deteriorated and excellent catalytic activity is retained stably over a long period of time. The alkaline water electrolysis anode is an alkaline water electrolysis anode 10 provided with an electrically conductive substrate 2 at least a surface of which contains nickel or a nickel base alloy and a catalyst layer 6 disposed on the surface of the electrically conductive substrate 2, the catalyst layer 6 containing a metal composite oxide having a quadruple perovskite oxide structure, wherein the metal composite oxide contains calcium (Ca), manganese (Mn), and nickel (Ni), and has an atom ratio of Ca/Mn/Ni/O of (1.0)/(6.6 to 7.0)/(0.1 to 0.4)/12.0.

公开(公告)号：US12012662B2

公开(公告)日：2024-06-18

申请号：US18307289

申请日：2023-04-26

申请人： OHIO STATE INNOVATION FOUNDATION

发明人： Umit Ozkan ,  Seval Gunduz ,  Dhruba Jyoti Deka

IPC分类号： C25B1/27 ,  C01G49/00 ,  C01G51/00 ,  C01G53/00 ,  C04B35/26 ,  C04B35/58 ,  C25B1/00 ,  C25B9/19 ,  C25B9/23 ,  C25B11/047 ,  C25B11/051 ,  C25B11/069 ,  C25B11/077 ,  C25B13/04 ,  C25B13/07

CPC分类号： C25B11/069 ,  C01G49/009 ,  C01G51/70 ,  C01G53/70 ,  C04B35/2633 ,  C04B35/2641 ,  C04B35/58042 ,  C25B1/00 ,  C25B1/27 ,  C25B9/19 ,  C25B9/23 ,  C25B11/047 ,  C25B11/051 ,  C25B11/0773 ,  C25B13/04 ,  C25B13/07 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2006/40 ,  C04B2235/3274 ,  C04B2235/3852

摘要： Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.

公开(公告)号：US11731920B2

公开(公告)日：2023-08-22

申请号：US16532276

申请日：2019-08-05

申请人： Battelle Energy Alliance, LLC

发明人： Dong Ding ,  Wei Wu ,  Hanping Ding ,  Bin Hua

IPC分类号： C25B1/02 ,  C25B1/27 ,  C25B3/03 ,  C25B3/23 ,  C07C2/24 ,  B01J31/26 ,  C01C1/04 ,  C25B9/19 ,  C25B11/042 ,  C25B11/046 ,  C25B11/077 ,  C25B13/04 ,  C25B13/07 ,  C25B9/23

CPC分类号： C07C2/24 ,  B01J31/26 ,  C01C1/0411 ,  C25B1/27 ,  C25B3/03 ,  C25B9/19 ,  C25B9/23 ,  C25B11/042 ,  C25B11/046 ,  C25B11/0773 ,  C25B13/04 ,  C25B13/07 ,  B01J2231/20

摘要： A method of a hydrocarbon product and ammonia comprises introducing C2H6 to a positive electrode of an electrochemical cell comprising the positive electrode, a negative electrode, and a proton-conducting membrane between the positive electrode and the negative electrode. The proton-conducting membrane comprising an electrolyte material having an ionic conductivity greater than or equal to about 10−2 S/cm at one or more temperatures within a range of from about 150° C. to about 600° C. N2 is introduced to the negative electrode of the electrochemical cell. A potential difference is applied between the positive electrode and the negative electrode of the electrochemical cell. A system for co-producing higher hydrocarbons and NH3, and an electrochemical cell are also described.

公开(公告)号：US20240352604A1

公开(公告)日：2024-10-24

申请号：US18303767

申请日：2023-04-20

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Mohamed Jaffer Sadiq MOHAMED ,  Muhammad Ashraf GONDAL

IPC分类号： C25B11/077 ,  C25B1/04 ,  C25B11/052 ,  C25B11/065 ,  C25B11/067

CPC分类号： C25B11/0773 ,  C25B1/04 ,  C25B11/052 ,  C25B11/065 ,  C25B11/067

摘要： An electrode includes a transparent substrate, and a layer of a nanostructured material at least partially covering a surface of the transparent substrate. The nanostructured material includes defective perovskite nanostructures (DPNSs) in the form of nanoplates having an average particle size in a range of 10 to 100 nanometers (nm), an interplanar spacing d(101) of the (101) plane in a range of 0.3 to 0.4 nm, and an interplanar spacing d(104) of the (104) plane in a range of 0.2 to 0.3 nm. A method of making the electrode.

公开(公告)号：US20230407499A1

公开(公告)日：2023-12-21

申请号：US18036213

申请日：2021-11-23

申请人： HANWHA SOLUTIONS CORPORATION

发明人： Gil Ho KIM ,  Chi Woo ROH ,  Kyu Ho SONG

IPC分类号： C25B11/077 ,  C25B1/04 ,  C25B11/031 ,  C25B9/19 ,  C25B11/061

CPC分类号： C25B11/0773 ,  C25B1/04 ,  C25B11/031 ,  C25B9/19 ,  C25B11/061

摘要： Provided are an oxidation catalyst for anion exchange membrane water electrolysis exhibiting excellent catalytic activity and electrical conductivity, a uniform particle size distribution and a large surface area, and excellent durability, and a preparation method thereof, an anode for anion exchange membrane water electrolysis and an anion exchange membrane water electrolysis system, each including the oxidation catalyst.

公开(公告)号：US11761101B2

公开(公告)日：2023-09-19

申请号：US17938410

申请日：2022-10-06

申请人： KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

发明人： Muhammad Ali Ehsan ,  Abdul Rehman

IPC分类号： C25B11/077 ,  C23C16/448 ,  C25B1/04 ,  C25B1/55 ,  C25B11/087 ,  C25B11/052 ,  C25B9/50

CPC分类号： C25B11/0773 ,  C23C16/4486 ,  C25B1/04 ,  C25B1/55 ,  C25B9/50 ,  C25B11/052 ,  C25B11/087

摘要： A CaTiO3—TiO2 composite electrode and method of making is described. The composite electrode comprises a substrate with an average 2-12 μm thick layer of CaTiO3—TiO2 composite particles having average diameters of 0.2-2.2 μm. The method of making the composite electrode involves contacting the substrate with an aerosol comprising a solvent, a calcium complex, and a titanium complex. The CaTiO3—TiO2 composite electrode is capable of being used in a photoelectrochemical cell for water splitting.

公开(公告)号：US20230183090A1

公开(公告)日：2023-06-15

申请号：US17923556

申请日：2021-04-14

申请人： THE UNIVERSITY OF WARWICK

发明人： Shanwen Tao

IPC分类号： C01G25/00 ,  H01M8/1016 ,  H01M10/0562 ,  C25B11/077 ,  C01G51/00

CPC分类号： C01G25/006 ,  H01M8/1016 ,  H01M10/0562 ,  C25B11/0773 ,  C01G51/66 ,  H01M2300/0071 ,  H01M2300/0091 ,  C01P2002/50 ,  C01P2006/40 ,  C01P2002/34 ,  C01P2002/77 ,  C01P2002/72 ,  C01P2002/86

摘要： A solid ionic conducting material for use in an electrochemical device comprises an oxyhydroxide or hydrated oxide derived from of an oxide with a perovskite, Brownmillerite, layered oxide, and/or K4CdCl6 structure, the elemental composition of the initial oxide being selected to provide suitable conduction properties for the derived anhydrous or hydrated oxyhydroxide or hydrated oxide. A method of making such a solid ionic conducting material, including treatment with water, and an electrochemical device incorporating such a solid ionic conducting material (optionally as an electrolyte) are also disclosed.

公开(公告)号：US20240175149A1

公开(公告)日：2024-05-30

申请号：US18551193

申请日：2022-03-25

申请人： ASAHI KASEI KABUSHIKI KAISHA

发明人： Hideaki NIIRO ,  Yuichi FUJII

IPC分类号： C25B11/077 ,  C01G53/00 ,  C25B1/04 ,  C25B9/19 ,  C25B9/77 ,  C25B11/052

CPC分类号： C25B11/0773 ,  C01G53/70 ,  C25B1/04 ,  C25B9/19 ,  C25B11/052 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2006/40 ,  C25B9/77

摘要： An electrode including LaNixMyO3-z on a substrate, and having an initial double layer capacitance of more than 0.6 F/cm2, where x+y is 0.8 or more and 1.2 or less, y is 0.001 or more and 0.6 or less, z is −0.5 or more and 0.5 or less, and M includes at least one of Nb, Ta, Sb, Ti, Mn, or Zr.

公开(公告)号：US11788196B2

公开(公告)日：2023-10-17

申请号：US18176676

申请日：2023-03-01

申请人： Jiangnan University

发明人： Tianxi Liu ,  Kaibin Chu ,  Feili Lai

IPC分类号： C25B11/077 ,  C25B1/27 ,  C01B35/12

CPC分类号： C25B11/0773 ,  C01B35/128 ,  C25B1/27 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2002/72 ,  C01P2002/77 ,  C01P2004/03 ,  C01P2006/40

摘要： The present disclosure discloses an ABO3 type high-entropy perovskite Bax(FeCoNiZrY)0.2O3-δ electrocatalytic material and a preparation method thereof, belonging to the technical field of electrocatalytic materials. The electrocatalytic material is prepared by taking hydrated cobalt nitrate, hydrated ferric nitrate, hydrated nickel nitrate, barium nitrate, hydrated yttrium nitrate, hydrated zirconium nitrate and polyacrylonitrile staple fibers as raw materials through processes of liquid phase chelation, gelation, calcination, etc. The prepared high-entropy perovskite Bax(FeCoNiZrY)0.2O3-δ electrocatalytic material can release more electrochemical active sites due to its special nanostructure, thus showing better electrocatalytic activity. Meanwhile, by adjusting the stoichiometric ratio of A/B-site metals, the electronic structure change of five metals in a catalytic center and the change of an oxygen vacancy content are realized, and the purpose of adjusting and optimizing the nitrogen reduction performance is achieved, so that the electrocatalytic material has excellent electrocatalytic conversion of nitrogen gas into ammonia gas.

公开(公告)号：US20230287585A1

公开(公告)日：2023-09-14

申请号：US18307289

申请日：2023-04-26

申请人： OHIO STATE INNOVATION FOUNDATION

发明人： Umit Ozkan ,  Seval Gunduz ,  Dhruba Jyoti Deka

IPC分类号： C25B11/069 ,  C25B1/00 ,  C25B13/04 ,  C01G51/00 ,  C01G53/00 ,  C04B35/58 ,  C04B35/26 ,  C25B9/19 ,  C25B11/051 ,  C25B11/077 ,  C25B1/27 ,  C25B11/047 ,  C01G49/00 ,  C25B9/23 ,  C25B13/07

CPC分类号： C25B11/069 ,  C25B1/00 ,  C25B13/04 ,  C01G51/70 ,  C01G53/70 ,  C04B35/58042 ,  C04B35/2633 ,  C25B9/19 ,  C04B35/2641 ,  C25B11/051 ,  C25B11/0773 ,  C25B1/27 ,  C25B11/047 ,  C01G49/009 ,  C25B9/23 ,  C25B13/07 ,  C04B2235/3274 ,  C01P2002/34 ,  C01P2002/50 ,  C01P2006/40 ,  C04B2235/3852

摘要： Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.