公开(公告)号：US20240247094A1

公开(公告)日：2024-07-25

申请号：US18561328

申请日：2021-08-30

申请人： Dow Global Technologies LLC

发明人： Xiaolian Hu ,  Chao Zhang ,  Ling Zhong ,  Xiangyang Tai ,  Yanli Feng

IPC分类号： C08G18/10 ,  C08G18/42 ,  C08G18/48 ,  C08G18/76 ,  C08G101/00 ,  D06N3/00 ,  D06N3/14

CPC分类号： C08G18/10 ,  C08G18/4238 ,  C08G18/4812 ,  C08G18/4825 ,  C08G18/4829 ,  C08G18/7671 ,  D06N3/0047 ,  D06N3/0063 ,  D06N3/0097 ,  D06N3/145 ,  D06N3/146 ,  D06N3/147 ,  C08G2101/00 ,  C08G2110/0083 ,  D06N2203/068 ,  D06N2205/023 ,  D06N2205/045 ,  D06N2209/10 ,  D06N2209/1664 ,  D06N2211/103 ,  D06N2211/106 ,  D06N2213/03

摘要： A waterborne polyurethane dispersion for the polyurethane foam of synthetic leather application, derived from (1) a prepolymer derived from the reaction of reactants comprising at least one aromatic isocyanate compound, an ethylene oxide-capped polyether triol, at least one polyether diol, and at least one polyester diol; (2) water; and (3) surfactant, is disclosed. The waterborne polyurethane dispersion can be used to prepare a synthetic leather product having superior wrinkle resistance, hand-feeling and peel strength. A synthetic leather article prepared with said waterborne polyurethane dispersion is also disclosed.

公开(公告)号：US20240003079A1

公开(公告)日：2024-01-04

申请号：US18252062

申请日：2021-01-18

申请人： Dow Global Technologies LLC

发明人： Xiaolian Hu ,  Chao Zhang ,  Biao Ma ,  Nan Wang ,  Yanli Feng

IPC分类号： D06N3/14 ,  C08G18/12 ,  C08G18/32 ,  C08G18/61 ,  C08G18/65 ,  C08J5/18 ,  D06N3/00

CPC分类号： D06N3/145 ,  C08G18/12 ,  C08G18/3228 ,  C08G18/61 ,  C08G18/6529 ,  C08J5/18 ,  D06N3/0059 ,  D06N3/0011 ,  D06N3/0047 ,  D06N3/0065 ,  D06N3/0097 ,  D06N3/147 ,  C08J2375/12 ,  D06N2203/068 ,  D06N2205/045 ,  D06N2209/103 ,  D06N2209/108

摘要： An internally emulsified polyurethane dispersion, which is prepared by using a combined chain extender system of a hydrophilic amino siloxane compound and a polyetheramine compound, is provided. The internally emulsified polyurethane dispersion can be used to prepare a synthetic leather product having good anti-stickiness, wrinkle resistance, color fastness and superior mechanical properties. A laminated synthetic leather article prepared with said internally emulsified polyurethane dispersion as well a method for preparing the synthetic leather article are also provided.

公开(公告)号：US20180223474A1

公开(公告)日：2018-08-09

申请号：US15943770

申请日：2018-04-03

申请人： Eastman Kodak Company

发明人： Mridula Nair ,  Mary Christine Brick ,  Joseph Salvatore Sedita

IPC分类号： D06N3/00

CPC分类号： D06N3/0006 ,  D06N3/0022 ,  D06N3/0036 ,  D06N3/0038 ,  D06N3/0047 ,  D06N3/0059 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/0068 ,  D06N2201/082 ,  D06N2201/10 ,  D06N2203/042 ,  D06N2203/044 ,  D06N2203/048 ,  D06N2203/061 ,  D06N2203/066 ,  D06N2203/068 ,  D06N2205/04 ,  D06N2205/10 ,  D06N2209/0853 ,  D06N2211/122 ,  D06N2211/125

摘要： A foamed, opacifying element has a porous substrate composed of woven yarn strands composed of a thermoplastic polymer-coated multifilament core. It has a dry foamed composition on an opposing surface of the substrate, which includes: (a) 0.1-40 weight % of porous particles; (b) 10-80 weight %; (c) 0.2-50 weight % of one or more additives selected from the group consisting of dispersants, plasticizers, flame retardants, optical brighteners, thickeners, biocides, fungicides, tinting colorants, metal flakes, and inert inorganic or organic fillers; (d) less than 5 weight % of water; and (e) at least 0.002 weight % of an opacifying colorant different from all of the one or more additives of (c), which opacifying colorant absorbs electromagnetic radiation having a wavelength of 380-800 nm. The elements have a light-blocking value (LBV) of at least 4 and can have a bending stiffness that is greater than 0.15 milliNewtons-meter.

公开(公告)号：US20180057983A1

公开(公告)日：2018-03-01

申请号：US15558568

申请日：2016-04-04

申请人： Carl Freudenberg KG

发明人： Steffen Traser ,  Steffen Kremser

IPC分类号： D04H1/68 ,  A41D27/06 ,  D06M17/10

CPC分类号： D04H1/68 ,  A41D27/06 ,  A41D31/00 ,  D04H1/488 ,  D04H1/49 ,  D04H1/66 ,  D06M17/10 ,  D06N3/0043 ,  D06N3/0047 ,  D06N3/005 ,  D06N3/0068 ,  D06N3/146 ,  D06N3/183 ,  D06N2209/123 ,  D06N2211/10

摘要： A thermofusible sheet material which can be used as a fusible interlining in the textile industry, has a carrier layer made from a textile material to which a polyurethane foam coating is applied. The polyurethane foam has a pore structure in which more than 50% of the pores have a diameter, measured according to DIN ASTM E 1294, which is in the range of 5 to 30 μm.

公开(公告)号：US20180051152A1

公开(公告)日：2018-02-22

申请号：US15239938

申请日：2016-08-18

申请人： Eastman Kodak Company

发明人： Mridula Nair ,  Mary Christine Brick ,  Joseph Salvatore Sedita

IPC分类号： C08J9/16

CPC分类号： D06N3/123 ,  C08J9/0061 ,  C08J9/0066 ,  C08J9/30 ,  C08J2333/08 ,  C08J2333/20 ,  C08J2401/08 ,  D06N3/0047 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/02 ,  D06N2209/0853 ,  D06N2209/1678 ,  D06N2211/125

摘要： Foamable aqueous compositions can be foamed and applied to porous substrates to make light-blocking dry opacifying elements. Such compositions have 0.05-15 weight % of porous particles; at least 20 weight % of a binder; at least 0.0001 weight % of additives (including a surfactant); water; and at least 0.001 weight % of an opacifying colorant. Each porous particle includes a continuous polymeric phase and discrete pores; a mode particle size of 2-50 μm; and a porosity of 20-70 volume %. The continuous polymeric phase Tg is >80° C. and has a polymer viscosity of 80-500 centipoises at an ethyl acetate shear rate of 100 sec−1 at a concentration of 20 weight % at 25° C. The dry opacifying element light blocking value is at least 4 and has a luminous reflectance >40% as measured by the color space Y tristimulus value. The foamed aqueous composition has a foam density of 0.1-0.5 g/cm3.

公开(公告)号：US20180051150A1

公开(公告)日：2018-02-22

申请号：US15239915

申请日：2016-08-18

申请人： Eastman Kodak Company

发明人： Mridula Nair ,  Mary Christine Brick ,  Ellen M. Pyszczek

IPC分类号： C08J9/00

CPC分类号： C08J9/0061 ,  C08J9/0066 ,  C08J9/30 ,  C08J2333/08 ,  C08J2333/20 ,  C08J2401/08 ,  C08J2401/28 ,  D06N3/0047 ,  D06N3/0063 ,  D06N3/0065 ,  D06N3/02 ,  D06N3/123 ,  D06N2209/0853 ,  D06N2209/1678 ,  D06N2211/125

摘要： Foamable aqueous compositions can be foamed and applied to porous substrates to make light-blocking dry opacifying elements. Such compositions have 0.05-15 weight % of porous particles; at least 20 weight % of a binder; at least 0.0001 weight % of additives (including a surfactant); water; and at least 0.001 weight % of an opacifying colorant. Each porous particle includes a continuous polymeric phase and discrete pores; a mode particle size of 2-50 μm; and a porosity of 20-70 volume %. The continuous polymeric phase Tg is >80° C. and has a polymer viscosity of 80-500 centipoises at an ethyl acetate shear rate of 100 sec−1 at a concentration of 20 weight % at 25° C. The dry opacifying element light blocking value is at least 4 and has a luminous reflectance>40% as measured by the Y tristimulus value. The foamed aqueous composition has a foam density of 0.1-0.5 g/cm3.

公开(公告)号：US20160208433A1

公开(公告)日：2016-07-21

申请号：US14908111

申请日：2014-08-12

申请人： DOW GLOBAL TECHNOLOGIES LLC

发明人： David J. Honkomp

IPC分类号： D06N3/00 ,  D06N3/14

CPC分类号： D06N3/0047 ,  B05D3/007 ,  B05D5/00 ,  B05D7/00 ,  C08G18/00 ,  C08G18/08 ,  C08G18/242 ,  C08G18/36 ,  C08G18/4812 ,  C08G18/4837 ,  C08G18/6696 ,  C08G18/7664 ,  C08G2101/0008 ,  C08G2101/0066 ,  C08J9/02 ,  C08J9/12 ,  C08J9/14 ,  C08J9/141 ,  C08J9/142 ,  C08J9/143 ,  C08J9/144 ,  C08J9/145 ,  C08J9/146 ,  C08J9/147 ,  C08J9/148 ,  C08J9/149 ,  C08J9/22 ,  C08J9/30 ,  C08J2201/00 ,  C08J2203/00 ,  C08J2203/12 ,  C08J2203/14 ,  C08J2203/142 ,  C08J2203/144 ,  C08J2203/146 ,  C08J2203/16 ,  C08J2203/162 ,  C08J2203/164 ,  C08J2203/166 ,  C08J2375/04 ,  C08J2475/04 ,  D06N3/0043 ,  D06N3/005 ,  D06N3/0086 ,  D06N3/0088 ,  D06N3/12 ,  D06N3/14 ,  D06N3/146 ,  D06N7/0071 ,  D06N7/0086 ,  D06N2203/068 ,  D06N2205/04 ,  D06N2205/045 ,  D06N2211/066 ,  D06N2213/06 ,  D10B2503/00 ,  D10B2503/04 ,  D10B2503/041

摘要： Textiles backed with a polyurethane cushion are produced by applying a layer of frothed polyurethane-forming mixture to a surface of the textile. The mixture contains both water and a physical blowing agent. The layer expands due to the action of the water and the physical blowing agent and cures to form an attached cushion having a density of 176 g/L or less.

摘要翻译： 用聚氨酯衬垫支撑的纺织品通过将一层起泡聚氨酯的混合物施加到纺织品的表面上来制备。 混合物含有水和物理发泡剂。 该层由于水和物理发泡剂的作用而膨胀，并固化形成密度为176g / L或更小的附着垫。

公开(公告)号：US20150284902A1

公开(公告)日：2015-10-08

申请号：US14433916

申请日：2012-10-16

申请人： Debkumar BHATTACHARJEE ,  Weichao GU ,  Ning KANG ,  Bo LIU ,  Yunfei YAN ,  Hongliang ZHANG ,  Chao Zhang

发明人： Debkumar Bhattacharjee ,  Ning Kang ,  Hong Liang Zhang ,  Yunfei Yan ,  Weichao Gu ,  Bo Liu ,  Chao Zhang

IPC分类号： D06N3/00 ,  D06N3/14 ,  C08J9/00 ,  C08J9/30 ,  C08J9/36

CPC分类号： D06N3/0047 ,  C08G18/10 ,  C08G18/12 ,  C08G18/283 ,  C08G18/4812 ,  C08G18/4825 ,  C08G18/4829 ,  C08G18/6674 ,  C08G18/706 ,  C08J9/0028 ,  C08J9/0033 ,  C08J9/30 ,  C08J9/365 ,  C08J2375/08 ,  D06N3/0061 ,  D06N3/0063 ,  D06N3/0077 ,  D06N3/14 ,  D06N3/146 ,  D06N2211/28 ,  Y10T428/24438 ,  C08G18/3228

摘要： Described herein are methods of preparing PUD based, poromeric, synthetic leathers having improved embossing characteristics, the methods comprising: preparing a polyurethane prepolymer, wherein the prepolymer comprises at least one isocyanate resin, and at least two polyols; preparing a first mixture comprising the polyurethane prepolymer, water, a chain extender, and a first surfactant that comprises at least one surfactant; preparing a second mixture comprising the first mixture, a thickening agent, and a second surfactant the comprises at least one surfactant, frothing the second mixture and thereby forming a frothed second mixture; applying the frothed second mixture to a fabric and thereby forming a coated fabric; optionally adjusting the thickness of the frothed third mixture on the fabric; and drying the coated fabric.

摘要翻译： 本文描述了制备具有改进的压花特性的基于PUD的多孔体合成革的方法，所述方法包括：制备聚氨酯预聚物，其中所述预聚物包含至少一种异氰酸酯树脂和至少两种多元醇; 制备包含聚氨酯预聚物，水，扩链剂和包含至少一种表面活性剂的第一表面活性剂的第一混合物; 制备包含第一混合物，增稠剂和第二表面活性剂的第二混合物，其包含至少一种表面活性剂，起泡第二混合物，从而形成发泡的第二混合物; 将发泡的第二混合物施加到织物上，从而形成涂布织物; 可选地调节织物上发泡的第三混合物的厚度; 并干燥涂层织物。

公开(公告)号：US20140182783A1

公开(公告)日：2014-07-03

申请号：US13733191

申请日：2013-01-03

申请人： June-Chiarn Lee ,  Peng-Tu Yeh

发明人： June-Chiarn Lee ,  Peng-Tu Yeh

IPC分类号： B05D7/00

CPC分类号： B05D1/34 ,  B05D2252/02 ,  C08G18/10 ,  C08G18/80 ,  C08G2150/60 ,  C09D175/04 ,  D06N3/0047 ,  D06N3/0097 ,  D06N3/14 ,  D06N2211/28 ,  Y02P20/582

摘要： A two-liquid process for synthesizing polyurethane with high heat-resistance and high abrasion-resistance is disclosed, which utilizes a semi-reactive polymer A solution containing hydroxyl groups and a semi-reactive polymer B solution containing poly-isocyanate groups. The polymer A and B solution are mixed for performing a second reaction and then coated on a substrate by a coating machine, and the coating layer is cured to form a polyurethane film. The semi-reactive polymer A and B solution are pre-polymerized in advance. The required polyurethane resin expands on the semi-reactive polymer A and B with a whole range of new functionality and construction styles through polymerization to produce high heat-resistant and high abrasion-resistant polyurethane film through coating facility under the working temperature about 80° C. A fabric is coupled during coating step for polyurethane leather. The two-liquid process is without using solvent as carrier. The environmental problem of air and water pollution can be resolved.

摘要翻译： 公开了一种用于合成具有高耐热性和高耐磨性的聚氨酯的双液体方法，其利用含有羟基的半反应性聚合物A溶液和含有聚异氰酸酯基团的半反应性聚合物B溶液。 将聚合物A和B溶液混合以进行第二反应，然后通过涂布机涂布在基材上，并使涂层固化以形成聚氨酯膜。 半反应性聚合物A和B溶液预先进行预聚合。 所需的聚氨酯树脂在半反应性聚合物A和B上通过聚合在整个范围内具有全新的功能和结构形式，通过涂覆设备在约80℃的工作温度下生产高耐热和高耐磨性的聚氨酯膜 在聚氨酯皮革的涂布步骤中将织物连接在一起。 双液体方法不使用溶剂作为载体。 空气和水污染的环境问题可以解决。

公开(公告)号：US20240102234A1

公开(公告)日：2024-03-28

申请号：US17766576

申请日：2020-09-17

申请人： DIC Corporation

发明人： Miwa Ueguchi ,  Tomohiro Tetsui

IPC分类号： D06N3/14 ,  C08J9/30 ,  D06N3/00

CPC分类号： D06N3/14 ,  C08J9/30 ,  D06N3/0006 ,  D06N3/0036 ,  D06N3/0047 ,  D06N3/0088 ,  C08J2375/04 ,  D06N2205/023 ,  D06N2205/045 ,  D06N2211/28

摘要： A task to be achieved by the invention is to provide a foamed sheet having excellent retention of foam, hand feeling, and peel strength. The present invention provides a foamed sheet which is formed from a water dispersion of a urethane resin (X), wherein the water dispersion has a urethane resin (X) content of 50 to 80% by mass, and the water dispersion contains no organic solvent. Further, the present invention provides a synthetic leather having at least a substrate (i) and a polyurethane layer (ii), wherein the polyurethane layer (ii) is formed from the above-mentioned foamed sheet. The foamed sheet preferably has a density of 200 to 1,000 kg/m3.