摘要:
Method and composition for a dry mix utilizing a natural or synthetic rubber stock containing a non-reinforcing filler and about 0,1 to 10 phr of an aminoplast polymer optimally modified by about 5-20 molar per cent of a polyamine.
摘要:
COMPOSITONS CONTAINING RUBBER IN CONTACT WITH POLYESTER MATERIAL, ESPECIALLY VULCANISED COMPOSITION, ARE STABILISED AGAINST THERMAL DEGRADATION OF THE POLYESTER BY INCORPORATION OF A HALOGEN-SUBSTITUTED HETEROCYCLIC COMPOUND CONTAINING IN ONE AROMATIC HETEOCYCLIC RING ONE OR TWO GROUPS OF THE FORMULAE
-N=C(HALOGEN)-OR=N-C(HALOGEN)=
THE PREFERRED COMPOUNDS ARE 2-CHLORO-S-TRIAZINES HAVING ALKYL-SUBSTITUTED AMINO GROUPS, OR ESPECIALLY UNSUBSTITUTED AMINO GROUPS, IN THE 4-AND 6-POSITIONS.
摘要:
Vulcanizable compositions comprise rubber, a free sulphur vulcanizing system and a rubber reinforcing composition comprising a formaldehyde donor and a reactive phenolic composition comprising a resin obtained by reacting phenol with sulphur or a sulphur chloride, the proportion of phenol/sulphur resin being 1 to 15% by weight of the rubber. The rubber may be natural rubber, polyisoprene, polybutadiene, polychloroprene, butadiene/styrene copolymer, butadiene/acrylonitrile copolymer, isobutylene/isoprene copolymer or ethylene/propylene/diene terpolymer. The formaldehyde donor may be hexamethylene tetramine, paraform, anhydroformaldehyde aniline resoles or melamine/formaldehyde resins. The reactive phenolic composition is essentially not heat advancing or self hardening, but reacts with the formaldehyde donor to form a thermoset product. If the phenol/sulphur resin does not so react a novolak must also be added, or the resin co-condensed through formaldehyde with a trifunctional phenol. The resin may be prepared by reacting phenols containing at least two free o or p positions with sulphur or a sulphur chloride under alkaline conditions. The reactive phenolic compositions preferably also contain a novolak resin. In examples styrene/butadiene, acrylonitrile/ butadiene and natural rubbers are vulcanized with reactive phenolic compositions comprising hexamethylene tetramine and (1) a phenol/sulphur resin, (2) a cresol/sulphur resin, (3) a phenol/sulphur resin and a cashew nut shell oil modified phenolic novolak, (4) a cresol/sulphur resin and a phenol/formaldehyde novolak, (5) a phenol/sulphur resin reacted with formaldehyde, (6) a phenol/sulphur resin reacted with formaldehyde and modified with partially polymerized cashew nut shell oil, (7) a cyclopentenyl phenol/sulphur resin reacted with formaldehyde, and then with phenol and formaldehyde, and (8) a resorcinol/sulphur resin.
摘要:
WHEREINE EACH R'' IS SELECTED FROM THE CLASS CONSISTING OF, INDIVIDUALL, HYDROGEN, ALKYL, CYCLOALKYL, ARYL, AND CHLOROALKYL, AND, TOGETHER WITH THE ETHYLENE MOIETY OF THE OXYETHYLENE CHAIN OF UNIT 11, A SATURATED CYCLOALIPHATIC HYDROCARBON RING HAVING 4 TO 8 CARBON ATOMS, AND VULCANIZABLES THEREOF. THESE NOVEL VULCANIZABLE ELASTOMERIC COMPOSITIONS ARE USEFUL IN THE PRODUCTION OF MOLDED ARTICLES OF A VARIETY OF SHAPES AND FORMS AS, FOR EXAMPLE, FILMS, WIRE AND CABLE COATINGS, ARTICLES OF MANUFACTURE, AND THE LIKE, AND CAN BE VULCANIZED OR THERMOSET IN SUCH SHAPES AND FORMS.
-(O-CH(-R'')-CH(-R''))-
WHEREIN EACH R, INDIVIDUALLY, IS SELECTED FROM THE CLASS CONSISTING OF HYDROGEN, ALKYL, HALO, AND ALKOXY; A IS THE OXY GROUP; X IS AN INTEGER FROM 1 TO 4; Y IS AN INTEGER FROM 1 TO 4; Z IS AN INTEGER OF ZERO OR ONE; WITH THE PROVISOS THAT (A) THE SUM OF X+Y+Z IS AT LEAST 4 AND NOT GREATER THAN 7, AND (B) THE TOTAL NUMBER OR R VARIABLES WHICH ARE SUBSTITUENTS OTHER THAN HYDROGEN DOES NOT EXCEED 3, AND UP TO A MINOR MOLAR AMOUNT OF RECURRING UNITS OF THE FORMULA:
-(O-(C(-R)2)X-(A)Z-(C(-R)2)Y-CO)-
VULCANIZABLE ELASTOMERIC BLENDS HAVING IMPROVED PROCESSABILITY, ADDITIVE ACCEPTANCE, IMPROVED STRENGHTS IN THE VULCANIZED FORM, IMPROVED CREEP RESISTANCE IN THE UNVULCANIZED FORM, IMPROVED HANDLING AND FORMING CHARACTERISTICS IN THE UNVULCANIZED FORM AND/OR IMPROVED STIFFNESS, OR IN SOME CASES IMPROVED FLEXIBILITY, IN THE UNCURED AND CURED FORMAS, CONTAINING A VULCANIZABLE RUBBER GUMSTOCK HAVING SUBSTANTIAL, REIDUAL, ETHYLENIC UNSATURATION AND A CYCLIC ESTER POLYMER CONTAINING RECURRING UNITS OF THE FORMULA:
摘要:
A rubber composition is provided having a high degree of tack in the uncured state and incorporating a para-tertiary-butylphenolaldehyde novolak resin consisting essentially of recurring groups A and B of the
WHEREIN R1 is a alkyl; and R2 is a hydrocarbon radical having 1 to 4 carbon atoms; and wherein the molar ratio of B:A has a value in the range of 0.1 to 0.3.
摘要:
THERE IS PROVIDED AN IMPROVED COATING COMPOSITION PARTICULARLY USEFUL FOR HIGHWAY MARKING PAINTS AND CHARACTERIZED BY EXTREMELY FAST DRY TIME. THE COMPOSITION INCLUDES AS ESSENTIAL INGREDIENTS AN ISOCYANATE-MODIFIED POLYESTER SUCH AS TOLUENE DIISOCYANATE MODIFIED LINSEED OIL/GLYCEROL/PHTHALATE AND A CHLORINATED RUBBER.
摘要:
ADHESIVE DIPS CONTAINING TRIS(DIHYDROXYBENZYL) PHENOL ARE USED TO BOND TEXILE CORDS TO RUBBER. THE ADHESIVE DIPS ARE USEFUL FOR THE BONDING OF NYLON, RAYON, AND THE EXPECIALLY DIFFICULT TO BOND POLYESTER TIRE CORDS TO RUBBER, GIVING EXCELLENT ADHESIVE PROPERTIES.