公开(公告)号：US20100221555A1

公开(公告)日：2010-09-02

申请号：US12095565

申请日：2006-11-30

Applicant: Tomoyuki Imada ,  Masakazu Yoshizawa

Inventor： Tomoyuki Imada ,  Masakazu Yoshizawa

IPC: B32B17/06 ,  C08L79/04 ,  C08L63/00 ,  C08G14/09

CPC classification number: C08L61/34 ,  C08G59/5086 ,  C08G59/621 ,  C08J5/24 ,  C08J2361/06 ,  C08J2361/34 ,  C08L61/06 ,  H05K1/0326 ,  H05K1/0346 ,  H05K2203/124

Abstract: The present invention provides a phenol resin composition which imparts excellent heat resistance and flame retardancy in a cured article, the cured article, a resin composition for a copper-clad laminate, and a copper-clad laminate having both excellent heat resistance and flame retardancy. Disclosed is a phenol resin composition comprising a phenol resin (I) having a chemical structure (A) represented by structural formula (1) shown below in which an aromatic hydrocarbon group substituted with a carboxyl group is bonded to a triazine ring, as a partial structure in the molecular structure, and a curing agent (II) as essential components.

Abstract translation: 本发明提供一种在固化物，固化物，覆铜层压体用树脂组合物，耐热性和阻燃性优异的覆铜层压板中赋予耐热性和阻燃性优异的酚醛树脂组合物。 公开了一种酚醛树脂组合物，其包含具有下述结构式（1）表示的化学结构（A）的酚醛树脂（I），其中被羧基取代的芳族烃基与三嗪环结合，作为部分 分子结构中的结构，以及作为必需成分的固化剂（II）。

公开(公告)号：US5939515A

公开(公告)日：1999-08-17

申请号：US390

申请日：1998-01-29

Applicant: Erhard Guenther ,  Wolfgang Reuther

Inventor： Erhard Guenther ,  Wolfgang Reuther

IPC: C07D251/18 ,  C08G14/09 ,  C08G14/10 ,  C08G12/30

CPC classification number: C08G14/10 ,  C07D251/18

Abstract: Condensation of products obtained by condensation of a mixture comprising(A) from 90 to 99.9 mol % of a mixture consisting essentially of(a) from 30 to 100 mol % of melamine and(b) from 0 to 70 mol % of a substituted melamine of the formula I ##STR1## where X, X' and X" are as defined in the specification, or mixtures of melamines I, and(c) from 1 to 70 mol %, based on (a)+(b), of a substituted triazine of the formula II ##STR2## where R", Z' and Z" are as defined in the specification, or mixtures of triazines II, and(B) from 0.1 to 10 mol %, based on (A) (a), (A) (b) and (B), of phenols which are unsubstituted or are substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxyl, C.sub.1 -C.sub.4 -alkanes substituted by two or three phenol groups, di(hydroxyphenyl)sulfones or mixtures of these phenols,withformaldehyde or formaldehyde-supplying compounds in a molar ratio of melamine, substituted melamine I and triazine II to formaldehyde within the range from 1:1.15 to 1:4.5, are useful for making molded articles.

Abstract translation: PCT No.PCT / EP96 / 03352 Sec。 371日期1998年1月29日 102（e）1998年1月29日PCT PCT 1996年7月30日PCT公布。 公开号WO97 / 07149 日期1997年2月27日缩短由（A）90-99摩尔％的（A）30〜100摩尔％的三聚氰胺和（b）0〜70摩尔组成的混合物 基于（a）+（b）的式I的取代三聚氰胺的％，其中X，X'和X“如本说明书中所定义，或三聚氰胺I和（c）1至70摩尔％的混合物 ），其中R“，Z'和Z”如说明书中所定义的取代的三嗪或三嗪II和（B）的混合物为0.1-10mol％，基于（A） （a），（A）（b）和（B））未被取代或被选自C 1 -C 9 - 烷基和羟基的基团取代的酚，（C） 基团，二（羟基苯基）砜或这些酚的混合物与甲醛或甲醛供应化合物以三聚氰胺，取代的三聚氰胺I和三嗪II的摩尔比与1:1的甲醛反应。 15至1：4.5，可用于制造模塑制品。

公开(公告)号：US5198478A

公开(公告)日：1993-03-30

申请号：US833697

申请日：1992-02-11

Applicant: Garry Smith ,  Martin Bradley

Inventor： Garry Smith ,  Martin Bradley

IPC: B22C1/22 ,  C08G8/10 ,  C08G8/28 ,  C08G14/06 ,  C08G14/09 ,  C08G14/12 ,  C08K5/3415 ,  C08K5/544 ,  C08L61/04 ,  C08L61/06

CPC classification number: B22C1/2253 ,  C08G14/06 ,  C08G14/12 ,  C08G8/10 ,  C08G8/28

Abstract: A binder composition for producing articles of bonded particulate material such as foundry moulds or cores comprises an alkaline aqueous solution of a resol phenol-aldehyde resin, an oxyanion which can form a stable complex with the resin, and pyrrolidone or an N-substituted pyrrolidone, and the amount of alkali present in the solution is sufficient to substantially prevent stable complex formation between the resin and the oxyanion. Bonded articles are produced by passing carbon dioxide gas through articles formed from a mixture of particulate material and the binder composition so as to produce stable complex formation and curing of the resin.

公开(公告)号：US5322915A

公开(公告)日：1994-06-21

申请号：US910382

申请日：1992-07-08

Applicant: Juergen Weiser ,  Wolfgang Reuther ,  Rolf Fikentscher ,  Wolfgang Fath ,  Heinz Berbner ,  Hans D. Zettler ,  Heinz Voelker

Inventor： Juergen Weiser ,  Wolfgang Reuther ,  Rolf Fikentscher ,  Wolfgang Fath ,  Heinz Berbner ,  Hans D. Zettler ,  Heinz Voelker

IPC: C08G14/09 ,  C08G14/06 ,  C08G14/10

CPC classification number: C08G14/10

Abstract: A condensation polymer, obtainable by condensation of a mixture containing, as chief components,(A) from 90 to 99.9% molar of a mixture substantially consisting of(a) from 30 to 99% molar of melamine and(b) from 1 to 70% molar of a substituted melamine of the general formula I ##STR1## in which X, X', and X" are selected from the group consisting of --NH.sub.2, --NHR, and --NRR', and only one or two of X, X', and X" denote(s) --NH.sub.2, and R and R' are selected from the group consisting of hydroxy-C.sub.2 -C.sub.10 -alkyl, hydroxy-C.sub.2 -C.sub.4 -alkyl-(oxa-C.sub.2 -C.sub.4 -alkyl).sub.n, where n is an integer from 1 to 5, and amino-C.sub.2 -C.sub.12 -alkyl, or mixtures of melamines I, and(B) from 0.1 to 10% molar, based on (A) and (B), of unsubstituted phenols or phenols substituted by radicals selected from the group consisting of C.sub.1 -C.sub.9 -alkyl and hydroxy, or of C.sub.1 -C.sub.4 -alkanes substituted by two or three phenol groups, di(hydroxyphenyl)sulfones, or mixtures of said phenols,with formaldehyde or formaldehyde-liberating compounds, the molar ratio of melamine to formaldehyde ranging from 1:1.15 to 1:4.5.

Abstract translation: 缩合聚合物，其可通过以主要组分（A）为90至99.9％摩尔的混合物缩合获得，该混合物基本上由（a）30至99％摩尔的三聚氰胺和（b）1至70 ％摩尔的通式I的取代三聚氰胺（I）其中X，X'和X“选自-NH 2，-NHR和-NRR'，并且只有一个或 X，X'和X“中的两个表示（s）-NH 2，R和R'选自羟基-C 2 -C 10 - 烷基，羟基-C 2 - C 4 - 烷基 - （氧杂-C2 -C 1-4 - 烷基）n，其中n为1至5的整数，氨基-C 2 -C 12 - 烷基或三聚氰胺I和（B）的混合物为0.1至10摩尔％，基于（A）和（ B）的未取代的酚或被选自C 1 -C 9 - 烷基和羟基的基团或被两个或三个苯酚基取代的C 1 -C 4烷烃取代的酚，二（羟基苯基）砜或所述 酚，与甲醛或甲醛释放化合物，摩尔 三聚氰胺与甲醛的比例范围为1：1.15至1：4.5。

公开(公告)号：US5216112A

公开(公告)日：1993-06-01

申请号：US745422

申请日：1991-08-15

Applicant: Shinji Ando ,  Yukio Fukui ,  Shigeru Iimuro

Inventor： Shinji Ando ,  Yukio Fukui ,  Shigeru Iimuro

IPC: C08G14/09 ,  C08G61/02

CPC classification number: C08G61/02

Abstract: A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.

公开(公告)号：US6060575A

公开(公告)日：2000-05-09

申请号：US300138

申请日：1999-04-27

Applicant: Chin-Ping Yang ,  Sheng-Huei Hsiao

Inventor： Chin-Ping Yang ,  Sheng-Huei Hsiao

IPC: C08G14/09 ,  C08G73/10 ,  C08G73/14 ,  C07D209/48 ,  C07D307/80

CPC classification number: C08G73/1071 ,  C08G73/1039 ,  C08G73/1053 ,  C08G73/14

Abstract: The present invention provides a series of easily processable poly(ether-imide)s that are organic-soluble and can afford colorless films, their organic solutions and their manufacturing process. The poly(ether-imide) is prepared from a dianhydride and a diamine, wherein the dianhydride is a bis(ether anhydride) having tert-butyl group, i. e. 1,4-bis(3,4-dicarboxyphenoxy)-2-tert-butylbenzene dianhydride.

Abstract translation: 本发明提供了一系列易于加工的聚（醚 - 酰亚胺），其是有机可溶性的并且可以提供无色膜，它们的有机溶液及其制备方法。 聚（醚 - 酰亚胺）由二酐和二胺制备，其中二酐是具有叔丁基的双（醚酐），即 e。 1,4-二（3,4-二羧基苯氧基）-2-叔丁基苯二酐。

公开(公告)号：US5888400A

公开(公告)日：1999-03-30

申请号：US879452

申请日：1997-06-20

Applicant: Edzard Tholema ,  Wolfgang Zarges ,  Harro Traubel

Inventor： Edzard Tholema ,  Wolfgang Zarges ,  Harro Traubel

IPC: C14C3/18 ,  B01F17/00 ,  C08G8/18 ,  C08G10/00 ,  C08G10/02 ,  C08G14/00 ,  C08G14/09 ,  B01D11/04

CPC classification number: C08G14/00 ,  C08G10/00 ,  C08G8/18

Abstract: A process for preparing low-salt preparations of condensation products based onA) sulphonated aromatics,B) aldehydes and/or ketones and optionallyC) one or more compounds selected from the group consisting of nonsulphonated aromatics, urea and urea derivatives,characterized in that inorganic acid present after the condensation is separated off in whole or in part from the condensation product, optionally in the form of its salts after neutralization, until the inorganic salt content is less than 10% by weight, relative to the preparation, leads to preparations which are outstandingly suitable as tanning agents, dispersants and liquefiers.

Abstract translation: 一种制备基于A）磺化芳族化合物的低盐制剂的方法，B）醛和/或酮和任选的C）一种或多种选自非磺化芳族化合物，脲和脲衍生物的化合物，其特征在于 在冷凝后存在的无机酸全部或部分地与缩合产物分离，任选地在中和后以其盐的形式，直到相对于制剂，无机盐含量小于10重量％，导致制剂 它们非常适合作为鞣剂，分散剂和液化剂。

公开(公告)号：US5319063A

公开(公告)日：1994-06-07

申请号：US5376

申请日：1993-01-15

Applicant: Shinji Ando ,  Yukio Fukui ,  Shigeru Iimuro

Inventor： Shinji Ando ,  Yukio Fukui ,  Shigeru Iimuro

IPC: C08G14/09 ,  C08G61/02 ,  C08G8/04 ,  C08G14/04

CPC classification number: C08G61/02

Abstract: A phenolic resin can be obtained by a condensation reaction between a specific trifunctional aromatic compound and a phenolic compound. This resin can be reacted with a curing agent such as a hexamine to give cured articles having excellent heat resistance, electrical properties, wear resistance and chemical resistance, and the phenolic resin is also much more excellent in curing reactivity as compared with conventional techniques.

Abstract translation: 可以通过特定的三官能芳族化合物和酚类化合物之间的缩合反应获得酚醛树脂。 该树脂可以与诸如六胺的固化剂反应，得到耐热性，电性能，耐磨性和耐化学性优异的固化物，与常规技术相比，酚醛树脂的固化反应性也更优异。

公开(公告)号：US6031064A

公开(公告)日：2000-02-29

申请号：US125546

申请日：1998-08-28

Applicant: Erhard Guenther ,  Wolfgang Reuther

Inventor： Erhard Guenther ,  Wolfgang Reuther

IPC: C08J9/00 ,  C08G12/30 ,  C08G14/06 ,  C08G14/09 ,  C08L61/26 ,  C08L61/34 ,  D01F6/76

CPC classification number: C08G12/30 ,  C08G14/06

Abstract: Condensation products obtained by condensation of(A) a mixture consisting of(a) a triazine of the general formula I ##STR1## and (b) a mixture consisting of(b1) a triazine of the general formula II ##STR2## (b2) a substituted melamine of the general formula III ##STR3## (B) phenols withformaldehyde or formaldehyde-donating compounds are useful for producing shaped articles, especially fibers and foams.

Abstract translation: PCT No.PCT / EP97 / 00981 Sec。 371日期1998年8月28日 102（e）1998年8月28日PCT PCT 1997年2月28日PCT公布。 公开号WO97 / 31958 日期1997年9月4日（A）由（a）通式I的三嗪和（b）的混合物的混合得到的缩合产物是由（b1）通式II（b2）的三嗪a 通式III（B）的取代三聚氰胺与甲醛或甲醛供给化合物的酚类可用于生产成型制品，特别是纤维和泡沫。

公开(公告)号：US5977289A

公开(公告)日：1999-11-02

申请号：US135891

申请日：1998-08-18

Applicant: Chin-Ping Yang ,  Sheng-Huei Hsiao

Inventor： Chin-Ping Yang ,  Sheng-Huei Hsiao

IPC: C08G14/09 ,  C08G73/10 ,  C08G73/14 ,  B05D3/12 ,  C08G69/26

CPC classification number: C08G73/1071 ,  C08G73/1039 ,  C08G73/1053 ,  C08G73/14

Abstract: The present invention provides a series of easily processable poly(ether-imide)s that are organic-soluble and can afford colorless films, their organic solutions and their manufacturing process. The poly(ether-imide) is prepared from a dianhydride and a diamine, wherein the dianhydride is a bis(ether anhydride) having tert-butyl group, i.e. 1,4-bis(3,4-dicarboxyphenoxy)-2-tert-butylbenzene dianhydride. The present invention is also directed to synthesis of this special dianhydride.

Abstract translation: 本发明提供了一系列易于加工的聚（醚 - 酰亚胺），其是有机可溶性的并且可以提供无色膜，它们的有机溶液及其制备方法。 聚（醚 - 酰亚胺）由二酐和二胺制备，其中二酐是具有叔丁基的双（醚酐），即1,4-双（3,4-二羧基苯氧基）-2-叔 - 丁苯二酐。 本发明还涉及该特殊二酐的合成。