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    MANUFACTURE OF TERTIOBUTYL HYDROPEROXYDE FROM RENEWABLE MATERIALS, TERTIOBUTYL HYDROPEROXIDE THUS OBTAINED, AND USES THEREOF
    1.
    发明申请
    MANUFACTURE OF TERTIOBUTYL HYDROPEROXYDE FROM RENEWABLE MATERIALS, TERTIOBUTYL HYDROPEROXIDE THUS OBTAINED, AND USES THEREOF 失效
    由可再生材料制备的TERTIOBUTYL HYDROPEROXYDE，获得的TERTIOBUTYL HYDROPEROXIDE THA及其用途

    公开(公告)号：US20110178324A1

    公开(公告)日：2011-07-21

    申请号：US13121300

    申请日：2009-09-24

    Applicant: Serge Hub ,  Phillppe Maj

    Inventor： Serge Hub ,  Phillppe Maj

    IPC: C07C409/04 ,  C07C407/00 ,  C07C69/96 ,  C12P7/00

    CPC classification number: C07C409/04 ,  C07C407/00 ,  C07C407/003 ,  C12P7/16 ,  Y02E50/10

    Abstract: The present application relates to a method for manufacturing tert-butyl hydroperoxide that includes the following steps: a) fermenting renewable raw materials and optionally purifying the same to produce a mixture containing at least butanol; b) dehydrating the butanol into butane; c) converting the butane into isobutene and optionally hydrating the isobutene to produce tert-butanol; d) reacting the product of step c) with hydrogen peroxide so as to produce tert-butyl hydroperoxide; and e) isolating the tert-butyl hydroperoxide. The invention also relates to tert-butyl hydroperoxide containing carbon atoms from renewable resources, to the compositions containing said tert-butyl hydroperoxide, and also relates to the use thereof as a polymerization initiator.

    Abstract translation: 本发明涉及一种叔丁基过氧化氢的制备方法，其包括以下步骤：a）发酵可再生原料，任选地对其进行纯化以产生至少含有丁醇的混合物; b）将丁醇脱水成丁烷; c）将丁烷转化成异丁烯并任选地使异丁烯水合以产生叔丁醇; d）使步骤c）的产物与过氧化氢反应，生成叔丁基过氧化氢; 和e）分离叔丁基过氧化氢。 本发明还涉及含有来自可再生资源的碳原子的叔丁基过氧化氢，含有所述叔丁基过氧化氢的组合物，还涉及作为聚合引发剂的用途。

    Process for producing 2,5-dimethyl-2,5-dihydroperoxyhexane
    4.
    发明授权
    Process for producing 2,5-dimethyl-2,5-dihydroperoxyhexane 失效
    2,5-二甲基-2,5-二氢过氧化己烷的制备方法

    公开(公告)号：US5856586A

    公开(公告)日：1999-01-05

    申请号：US776327

    申请日：1997-01-24

    Applicant: Eberhard Hagel ,  Werner Zeiss

    Inventor： Eberhard Hagel ,  Werner Zeiss

    IPC: B01J27/02 ,  C07B61/00 ,  C07C407/00 ,  C07C409/04 ,  C07C409/14 ,  C07C409/00

    CPC classification number: C07C409/04 ,  C07C407/00

    Abstract: Disclosed is a process for the preparation of 2,5-dimethyl-2,5-dihydroperoxyhexene by reaction of 2,5-dimethyl-1,5-hexadiene with hydrogen peroxide in an acidic medium. According to this process, the 2,5-dimethyl-2,5-dihydroperoxyhexane can be prepared with good yield and in a technically simple way.

    Abstract translation: PCT No.PCT / EP95 / 02987第 371日期1997年1月24日 102（e）日期1997年1月24日PCT提交1995年7月27日PCT公布。 出版物WO96 / 03372 日期1996年2月8日公开是通过在酸性介质中通过2,5-二甲基-1,5-己二烯与过氧化氢的反应来制备2,5-二甲基-2,5-二氢过氧化己烯的方法。 根据该方法，可以以良好的产率和技术上简单的方法制备2,5-二甲基-2,5-二氢过氧化己烷。

    Reaction of isobutane with oxygen
    6.
    发明授权
    Reaction of isobutane with oxygen 失效
    异丁烷与氧反应

    公开(公告)号：US5436375A

    公开(公告)日：1995-07-25

    申请号：US296633

    申请日：1994-08-26

    Applicant: Karen A. Thomas ,  Kyle L. Preston

    Inventor： Karen A. Thomas ,  Kyle L. Preston

    IPC: C07C27/00 ,  B01J10/00 ,  C07C27/12 ,  C07C27/26 ,  C07C29/50 ,  C07C31/12 ,  C07C407/00 ,  C07C409/04 ,  C07C27/10

    CPC classification number: C07C409/04 ,  B01J10/002 ,  C07C29/50 ,  C07C407/00 ,  B01J2219/00006

    Abstract: Tertiary butyl hydroperoxide and tertiary butyl alcohol are prepared from isobutane and oxygen in a vertical reactor by sparging a mixture of isobutane with oxygen to the bottom of the reactor, by charging a reaction mixture recycle stream to the reactor above the sparge point, by centrally charging a downwardly flowing stream of cooled fresh isobutane to the top of the reactor to induce central downflow of the fresh isobutane annular and upflow of the sparged mixture and the recycle stream, by withdrawing a liquid product stream adjacent the top of the reactor, by withdrawing a vapor product stream from the top of the reactor, by condensing entrained liquids in the vapor product, by recycling the condensed liquids and by recovering the liquid product stream.

    Abstract translation: 通过将异丁烷与氧气的混合物喷射到反应器的底部，通过将反应混合物循环物流通过中心充电将反应混合物循环物流加入到反应器中，由立式反应器中的异丁烷和氧气制备叔丁基过氧化氢和叔丁醇 冷却的新鲜异丁烷向下流动的反应器顶部，以通过撤回与反应器顶部相邻的液体产物流，引起新鲜异丁烷环形和喷射混合物和再循环料流向上流的中心向下流动 蒸气产物流从反应器的顶部通过将夹带的液体冷凝在蒸汽产物中，通过再循环冷凝液体并回收液体产物流。

    Allyl hydroperoxide chain transfer agents
    7.
    发明授权
    Allyl hydroperoxide chain transfer agents 失效
    ALLYL羟基链转移剂

    公开(公告)号：US5247033A

    公开(公告)日：1993-09-21

    申请号：US852131

    申请日：1992-04-28

    Applicant: Luc L. T. Vertommen ,  John Meijer

    Inventor： Luc L. T. Vertommen ,  John Meijer

    IPC: C07C409/04 ,  C07C409/08 ,  C07C409/14 ,  C07C409/16 ,  C07C409/18 ,  C07C409/20 ,  C07C409/38 ,  C07C409/40 ,  C07C409/42 ,  C08F2/38 ,  C08F4/28 ,  C08F4/32 ,  C08F4/34 ,  C08F4/36 ,  C08F10/00 ,  C08F12/00 ,  C08F12/08 ,  C08F18/04 ,  C08F20/10 ,  C08F20/18 ,  C08F36/04 ,  C08F218/02 ,  C08F220/10

    CPC classification number: C08F2/38 ,  C08F4/32 ,  C08F4/34 ,  C08F4/36

    Abstract: A polymerization method carried out in the presence of unsaturated hydroperoxides useful as molecular weight regulators, is disclosed. Also disclosed are polymers and oligomers made by this process and articles of manufacture comprising one or more polymers or oligomers made by this process. These molecular weight regulating hydroperoxides provide the ability to introduce an epoxy functionality to the oligomer or polymer as well as an additional functionality and a primary hydroxy group. Further, omega substituted or alpha, omega disubstituted polymers may be synthesized using the unsaturated hydroperoxides of the present invention.

    Abstract translation: PCT No.PCT / EP90 / 01781 Sec。 371日期：1992年4月28日 102（e）日期1992年4月28日PCT 1990年10月16日PCT PCT。 出版物WO91 / 07440 日本1991年5月30日。公开了在用作分子量调节剂的不饱和氢过氧化物存在下进行的聚合方法。 还公开了通过该方法制备的聚合物和低聚物以及包含通过该方法制备的一种或多种聚合物或低聚物的制品​​。 这些分子量调节氢过氧化物提供了向低聚物或聚合物以及另外的官能团和伯羟基引入环氧官能团的能力。 此外，ω取代的或α，ω二取代的聚合物可以使用本发明的不饱和氢过氧化物合成。

    Treatment of tertiary butyl hydroperoxide distillation fraction to remove acidic contaminants
    8.
    发明授权
    Treatment of tertiary butyl hydroperoxide distillation fraction to remove acidic contaminants 失效
    处理叔丁基过氧化氢蒸馏馏分去除酸性污染物

    公开(公告)号：US5151530A

    公开(公告)日：1992-09-29

    申请号：US765610

    申请日：1991-09-25

    Applicant: Edward T. Marquis ,  John R. Sanderson ,  Robert A. Meyer

    Inventor： Edward T. Marquis ,  John R. Sanderson ,  Robert A. Meyer

    IPC: C07C407/00 ,  C07C409/04 ,  C07D301/19 ,  C07D303/04

    CPC classification number: C07D301/19 ,  C07C407/00 ,  C07C407/003 ,  C07C409/04 ,  C07D303/04

    Abstract: The distillation product fraction obtained from an isobutane oxidation reaction product after the removal of unreacted isobutane will contain tertiary butyl hydroperoxide, tertiary butyl alcohol and carboxylic acid contaminants such as formic acid, acetic acid and isobutyric acid. It has been discovered that when the distillation product fraction is treated with about 1/2 to 1 equivalents of calcium oxide and/or calcium hydroxide based on the carboxylic acid content of the distillate product fraction, a portion of the carboxylic acid contaminants will precipitate thus partially purifying the distillation product fraction so that, thereafter, molybdenum precipitation will be substantially inhibited when the thus-treated distillation product fraction is used as a feedstock for an epoxidation reaction wherein tertiary butyl hydroperoxide is reacted with an olefin in the presence of a soluble molybdenum catalyst to provide an olefin epoxide and additional tertiary butyl hydroperoxide.

    Abstract translation: 在除去未反应的异丁烷之后由异丁烷氧化反应产物得到的蒸馏产物馏分将含有叔丁基过氧化氢，叔丁醇和羧酸污染物如甲酸，乙酸和异丁酸。 已经发现，当蒸馏产物馏分基于馏出物产物级分的羧酸含量用约1/2至1当量的氧化钙和/或氢氧化钙处理时，一部分羧酸污染物将沉淀，因此 部分纯化蒸馏产物部分，使得当将如此处理的蒸馏产物馏分用作环氧化反应的原料时，钼沉淀将基本上被抑制，其中叔丁基过氧化氢在可溶性钼存在下与烯烃反应 催化剂以提供烯烃环氧化物和另外的叔丁基过氧化氢。

    Tertiary butyl hydroperoxide concentration
    9.
    发明授权
    Tertiary butyl hydroperoxide concentration 失效
    叔丁基过氧化氢浓度

    公开(公告)号：US5104493A

    公开(公告)日：1992-04-14

    申请号：US645434

    申请日：1991-01-24

    Applicant: Victor M. Chong

    Inventor： Victor M. Chong

    IPC: C07C29/80 ,  C07C407/00 ,  C07C409/04

    CPC classification number: C07C409/04 ,  C07C29/80 ,  C07C407/00 ,  C07C407/003

    Abstract: The invention relates to a process for concentrating TBHP while avoiding flammability and explosion hazards by distilling a mixture of TBHP and TBA under reduced pressure of up to 300 mm Hg and separating a liquid TBHP concentrate containing at least 65 wt. % TBHP.

    Abstract translation: 本发明涉及通过在高达300mm Hg的减压下蒸馏TBHP和TBA的混合物并分离含有至少65wt。的液体TBHP浓缩物来集中TBHP同时避免易燃性和爆炸危险的方法。 ％TBHP。

    Removal of acidic contaminants from tertiary butyl hydroperoxide
    10.
    发明授权
    Removal of acidic contaminants from tertiary butyl hydroperoxide 失效
    从叔丁基氢过氧化物中除去酸性污染物

    公开(公告)号：US5093506A

    公开(公告)日：1992-03-03

    申请号：US400901

    申请日：1989-08-30

    Applicant: Edward T. Marquis ,  John R. Sanderson ,  Robert A. Meyer

    Inventor： Edward T. Marquis ,  John R. Sanderson ,  Robert A. Meyer

    IPC: C07C407/00 ,  C07C409/04 ,  C07D301/19 ,  C07D303/04

    CPC classification number: C07D301/19 ,  C07C407/00 ,  C07C407/003 ,  C07C409/04 ,  C07D303/04

    Abstract: The distillation product fraction obtained from an isobutane oxidation reaction product after the removal of unreacted isobutane will contain tertiary butyl hydroperoxide, tertiary butyl alcohol and carboxylic acid contaminants such as formic acid, acetic acid and isobutyric acid. It has been discovered that when the distillation product fraction is treated with about 1/2 to 1 equivalents of calcium oxide and/or calcium hydroxide based on the carboxylic acid content of the distillate product fraction, a portion of the carboxylic acid contaminants will precipitate thus partially purifying the distillation product fraction so that, thereafter, molybdenum precipitation will be substantially inhibited when the thus-treated distillation product fraction is used as a feedstock for an epoxidation reaction wherein tertiary butyl hydroperoxide is reacted with an olefin in the presence of a soluble molybdenum catalyst to provide an olefin epoxide and additional tertiary butyl hydroperoxide.

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