Acrylonitrile copolymer binder and application thereof in lithium ion batteries

    公开(公告)号:US11603423B2

    公开(公告)日:2023-03-14

    申请号:US16326597

    申请日:2016-12-09

    摘要: The invention relates to an acrylonitrile copolymer binder and application thereof in lithium ion battery, belonging to the field of lithium ion battery. The technical problem to be solved by the invention is to provide an acrylonitrile copolymer binder comprising the following structural units in percentage by weight: 78-95% of acrylonitrile unit, 1-10% of acrylic ester unit and 2-15% of acrylamide unit. For the binder of the invention, acrylonitrile monomer is taken as the main body, and acrylic ester monomer, acrylamide monomer or acrylate salt monomer with strong polarity is added to acrylonitrile for copolymerization to enable the flexibility of a polymer membrane, the affinity of an electrolyte and the proper swelling degree in the electrolyte while keeping strong adhesion or intermolecular force of acrylonitrile polymer molecules, so as to fit the periodic volume changes of electrode active materials along with lithium ion intercalation/deintercalation in charging and discharging processes, thereby improving the energy density and cycle performance of the lithium ion battery.

    Hollow resin particles and application thereof

    公开(公告)号:US10774192B2

    公开(公告)日:2020-09-15

    申请号:US16322218

    申请日:2017-07-07

    摘要: Hollow resin particles, a production process for producing the same and application thereof. The hollow resin particles include a thermoplastic resin shell and a hollow part surrounded by the shell. The thermoplastic resin is a polymer produced from a polymerizable component containing 0.6 to 3.0 wt % of a crosslinkable monomer having at least two polymerizable carbon-carbon double bonds per molecule and 97 to 99.4 wt % of an uncrosslinkable monomer having one polymerizable carbon-carbon double bond per molecule. A blowing agent is encapsulated in the hollow resin particles. The blowing agent contains 50 to 100 wt % of an organic compound having a vapor pressure higher than 100 kPa at 25° C. Further, the encapsulation ratio of the blowing agent ranges from 3 to 13 wt % of the hollow resin particles.