摘要:
A method of reducing nitrogen oxides in exhaust gas of an internal combustion engine by selective catalytic reduction (SCR) comprises contacting the exhaust gas also containing ammonia and oxygen with a catalytic converter comprising a catalyst (2) comprising at least one crystalline small-pore molecular sieve catalytically active component (ZM,I)having a maximum ring opening of eight tetrahedral basic building blocks, which crystalline small-pore molecular sieve catalytically active component (ZM,I) comprising mesopores.
摘要:
Provided is a method for reducing N 2 O emissions in an exhaust gas comprising contacting an exhaust gas containing NH 3 and an inlet NO concentration with an SCR catalyst composition containing small pore zeolite having a silica-to-alumina ratio (SAR) of about 3 to about 15 and having about 1 - 5 wt. % of an exchanged transition metal.
摘要:
A system for filtering particulate matter (PM) from exhaust gas emitted from a positive ignition engine or a compression ignition engine, said system comprising a filter having inlet surfaces, outlet surfaces, and a porous structure between the inlet surfaces and the outlet surfaces; a selective catalytic reduction (SCR) washcoat com¬ prising a small pore zeolite promoted with at least one metal select¬ ed from the group consisting of Cr, Co, Cu, Fe, Hf, La, Ce, In, V, Mn, Ni, Zn, Ga, Ag, Au, Pt, Pd and Rh, wherein the washcoat provides a wash- coated filter for filtering the particulate matter; and a NOx absorber disposed upstream of the washcoat.
摘要:
A synthetic alumino silicate zeolite catalyst containing at least one catalytically active transition metal selected from the group consisting of Cu, Fe, Hf, La, Au, In, V, lanthanides and Group VIII transition metals, which alumino silicate zeolite is a small pore aluminosilicate zeolite having a maximum ring size of eight tetrahedral atoms, wherein the mean crystallite size of the aluminosilicate zeolite determined by scanning electron microscope is >0.50 micrometer.
摘要:
Die vorliegende Erfindung betrifft einen metalldotierten bzw. metallausgetauschten Zeolithen, wobei das Dotierungsmetall im Zeolithen isoliert in Form einzelner Atome, d.h. als monomere und/oder als dimere Spezies vorliegt. Weiter betrifft die vorliegende Erfindung ein Verfahren zur Herstellung eines derartigen metallausgetauschten Zeolithen. Verwendung finden die erfindungsgemäßen metalldotierten Zeolithe insbesondere bei der Reduktion von Stickoxiden.
摘要:
Die vorliegende Erfindung betrifft einen Katalysator, der einen kleinporigen, Eisen und Kupfer enthaltenden Zeolithen mit einer maximalen Ringgröße von acht tetraedrischen Atomen umfasst, dadurch gekennzeichnet, dass die Kanalweite des kleinporige Zeolithen in mindestens einer Dimension > 3,8 Å (0,38 nm) ist.
摘要:
A method is disclosed for making a new crystalline molecular sieve designated SSZ-98. SSZ-98 has the ERI framework type and is synthesized using a N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent.
摘要:
A catalysed honeycomb wall-flow filter for treating exhaust gas comprising particulate matter emitted from an internal combustion engine, which filter comprising a honeycomb substrate having a first end and a second end and comprising an array of interconnecting porous walls defining an array of longitudinally extending first channels and second channels, wherein the first channels are bordered on their sides by the second channels and have a larger hydraulic diameter than the second channels, wherein the first channels are end-plugged at a first end of the honeycomb substrate and the second channels are end-plugged at a second end of the honeycomb substrate, wherein channel wall surfaces of the first channels comprise an on-wall-type catalytic washcoat. The invention also relates to an exhaust system comprising the catalysed filter and to methods of making it.
摘要:
An exhaust system for internal combustion engines, and a catalyzed substrate for use in an exhaust system, is disclosed. The exhaust system comprises a lean NO x trap and the catalyzed substrate. The catalyzed substrate has a first zone and a second zone, wherein the first zone comprises a platinum group metal loaded on a support and the second zone comprises copper or iron loaded on a zeolite. The first zone or second zone additionally comprises a base metal oxide or a base metal loaded on an inorganic oxide. Also provided are methods for treating an exhaust gas from an internal combustion engine using the exhaust system. The exhaust system is capable of storing NH 3 generated in rich purging, reacting the NH 3 with slip NO x from the ΝΟχ trap, controlling H 2 S released from NO x trap desulfation, and oxidizing slip hydrocarbons and carbon monoxide. When the catalyzed substrate is a filter substrate, it is also capable of removing soot from exhaust system.
摘要:
The present invention relates to a copper containing ZSM-34, OFF and/or ERI zeolitic material having a silica to alumina mole ratio ranging from about 4 to about 50 and a copper content, reported as CuO, ranging from about 1 to about 10 wt.-%, based on the total weight of the calcined zeolitic material, and having an alkali metal content, reported as the metal oxide, of less than about 0.7 wt.-%.