Abstract:
Uses are disclosed for a new crystalline molecular sieve designated SSZ-102 synthesized using an N,N'-dimethyl-1,4-diazabicyclo[2.2.2]octane dication as a structure directing agent. SSZ-102 has ESV framework topology.
Abstract:
Provided is novel catalyst for treating NOx in an exhaust gas, wherein the catalyst comprises a metal promoted high SAR zeolite having an AFX framework.
Abstract:
A method for converting an alcohol to a hydrocarbon fraction having a lowered benzene content, the method comprising: converting said alcohol to a hydrocarbon fraction by contacting said alcohol, under conditions suitable for converting said alcohol to said hydrocarbon fraction, with a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon fraction, and contacting said hydrocarbon fraction with a benzene alkylation catalyst, under conditions suitable for alkylating benzene, to form alkylated benzene product in said hydrocarbon fraction. Also described is a catalyst composition useful in the method, comprising a mixture of (i) a metal-loaded zeolite catalyst catalytically active for converting said alcohol to said hydrocarbon, and (ii) a benzene alkylation catalyst, in which (i) and (ii) may be in a mixed or separated state. A reactor for housing the catalyst and conducting the reaction is also described.
Abstract:
This invention relates to a process of preparing an improved catalyst comprising a clay derived zeolite. In particular, the invention comprises combining an yttrium compound with a zeolite produced by treating clay with a silica source and under alkaline conditions. The clay derived zeolite can be further combined with conventional matrix and/or binder precursors to form particulates suitable for use as catalysts in fluid catalytic cracking (FCC). Alternatively, the clay that is treated with the silica source and alkaline conditions can be in particulate form having sizes suitable for use in FCC, and the zeolite is produced in situ within the particulate. Yttrium compound is then combined with the zeolite in the particulate, e.g., via impregnation. It has been shown that the addition of the yttrium compound improves zeolite surface area retention, and zeolite stability in catalysts comprising clay derived zeolites.
Abstract:
A heterogeneous catalyst article having at least one combination of a first molecular sieve having a medium pore, large pore, or meso-pore crystal structure and optionally containing a first metal, and a second molecular sieve having a small pore crystal structure and optionally containing a second metal, and a monolith substrate onto or within which said catalytic component is incorporated, wherein the combination of the first and second molecular sieves is a blend, a plurality of layers, and/or a plurality of zones.
Abstract:
The invention is directed to a method of making a small crystal SSZ-32 zeolite, known as SSZ-32X. The catalyst is suitable for use in a process whereby a feed including straight chain and slightly branched paraffins having 10 or more carbon atoms is dewaxed to produce an isomerized product, with increased yield of isomerized material and decreased production of light ends.
Abstract:
Methods are provided for performing a conversion reaction using a catalyst steamed under mild steaming conditions. Steaming a conversion catalyst under mild steaming conditions can provide an increased conversion activity and/or an increased run length for the catalyst during conversion of an oxygenate feed to aromatic hydrocarbons, such as benzene or xylene. Suitable conversion catalysts can include alumina bound catalysts including a medium pore molecular sieve.
Abstract:
The present disclosure generally provides novel STT-type zeolite materials called PIDC- MM-0501, PIDC-MM-0502, and PIDC-MM-0805/0806 or PIDC-type zeolites and a method of making these zeolites. The present disclosure also provides for the use of these zeolite materials as a catalyst and a method of preparing said catalyst. The PIDC-MM-type zeolites or STT-type zeolite materials may be used as a catalyst, such as in Selective Catalytic Reduction (SCR) applications.
Abstract:
Embodiments of the present disclosure include a method of producing ethylebenzene by the catalytic alkylation of benzene with ethanol. In one embodiment of the present disclosure, a method of producing an alkylaromatic is disclosed which includes contacting an aromatic with ethanol in the presence of a catalyst at liquid phase alkylation conditions to form the alkylaromatic. In another embodiment of the present disclosure, a method of producing an alkylaromatic is disclosed.