摘要:
Improved electrolytes for application in electrical storage devices, such as batteries and capacitors, electrochromic display and other applications requiring ionically conductive median are disclosed. The electrolytes of the invention contain organic cation salts, also called ionic liquids or molten salts. These improved electrolytes have useful characteristics such as high thermal stability and reduced flammability.
摘要:
The invention relates to an ethylene glycol mixture containing the following: a) 20-70 wt. % ethylene glycol; b) 1-10 wt. % ammonium pentaborate; c) 1-10 wt. % mannite; d) 0-1.0 wt. % 4-nitrobenzoic acid; e) 0-0.5 wt. % ammonium hypophosphite; f) 3-35 wt. % diethylene glycol monobutylether; and g) 2-10 wt. % of a mixture of dimeric and trimeric acids. The use of a mixture of dimeric and trimeric acids allows the water content of the electrolyte to be reduced. This reduces the residual current and improves the durability of the capacitor. The invention also relates to an Al-electrolyte capacitor with the inventive ethylene glycol mixture as the electrolyte, and to the use of the ethylene glycol mixture.
摘要:
Improved nonaqueous electrolytes for application in electrical storage devices such as electrochemical capacitors or batteries are disclosed. The electrolytes of the invention contain salts consisting of alkyl substituted, cyclic delocalized aromatic cations, and their perfluoro derivatives, and certain polyatomic anions having a van der Waals volume less than or equal to 100 ANGSTROM , preferably inorganic perfluoride anions and most preferably PF6 , the salts being dissolved in organic liquids, and preferably alkyl carbonate solvents, or liquid sulfur dioxide or combinations thereof, at a concentration of greater than 0.5M and preferably greater than 1.0M. Exemplary electrolytes comprise 1-ethyl-3-methylimidazolium hexafluorophosphate dissolved in a cyclic or acyclic alkyl carbonate, or methyl formate, or a combination thereof. These improved electrolytes have useful characteristics such as higher conductivity, higher concentration, higher energy storage capabilities, and higher power characteristics compared to prior art electrolytes. Stacked capacitor cells using electrolytes of the invention permit high energy, high voltage storage.
摘要:
Disclosed is a method for grafting a polymer onto the surface of a carbonate material with carboxyl, amine, and/or hydroxyl functions on its surface. Said material is placed in suspension in a solution including the polymer to be grafted, which has a carboxyl, amine, and/or hydroxyl function, said solution also being comprised of a polymer solvent. A process which stimulates the dehydration into a carboxyl function of an amine and/or hydroxyl function is then performed, and the polymer is grafted onto the carbonate material using ester or amide links. The invention can be used in the cathode or naode of an electrochemical generator, in polymer materials with low polar properties, in ink, and also as a conductive coating on flexible plastic used as an electrical contact, as electromagnetic shielding, or as static protection.
摘要:
An electrolyte comprises a composite of a polymer and a molten salt electrolyte immobilised within the polymer. The electrolyte is stable and ionically conducting at a temperature substantially equal to the melting point of the molten salt electrolyte. In this form, the electrolyte is suitable for use in electrochemical cells, supercapacitors or electrochromic windows and displays.
摘要:
An electrolytic solution wherein the solute is a salt of a quaternized derivative of an N,N,N'-trisubstituted amidine compound with a carboxylic or like acid, said amidine compound being exemplified by 1-methylimidazole, 1-methylbenzimidazole, 1,2-dimethylimidazoline, 1,2-dimethyl-1,4,5,6-tetrahydropyrimidine, 1,8-diazabicyclo[5.4.0]undecene-7, or 1,5-diazabicyclo[4.3.0]nonene-5; and an electro-chemical element and an electrolytic capacitor each prepared therefrom. The obtained electrolytic capacitor and electrochemical elements such as an electrochromic display element are excellent in the thermal stability of the electolytic solution, have a high specific conductivity, and neither corrode nor deteriorate metal, resins and rubbers.
摘要:
The copolymer described is a segmented copolymer consisting essentially of organic segments A which have a number i of reactive ends such that i is from 1 to 6 inclusive, and segments B which have a number j of reactive ends such that j is from 1 to 6 inclusive. The segments B have redox properties and each segment A is connected to at least one segment B by a group Y and vice versa, the group Y being an ether, thioether, secondary amine, tertiary amine, secondary amide, tertiary amide, imide, quaternary ammonium group, or a group having a carbon-carbon bond. The respective weighted molar mean of i and j is 2 or more. Application to electrochemical generators and electrochromic systems.
摘要:
The present invention relates to a process for the preparation of a composite material comprising a vinylidene difluoride (VDF)-containing copolymer and an electrically non-conductive polymeric material, to a composite material obtainable via said process, to its use in electrochemical cells and to an electrochemical cell comprising said composite.
摘要:
Hybrid semiconducting-dielectric materials and electronic or electro-optic devices using the hybrid semiconducting-dielectric materials. Hybrid semiconducting-dielectric materials comprise molecules that have a core section that provides an n-type semiconducting property and side chains that provide a dielectric property to a layer of hybrid semiconducting-dielectric material. Specific hybrid semiconducting-dielectric materials include tetracarboxylic diimide compounds having sidechains comprising fluorine substituted aliphatic or aromatic moieties linked to the tetracarboxylic diimide structure by an alkylene or heteroalkylene linking group.