公开(公告)号：WO2012061005A2

公开(公告)日：2012-05-10

申请号：PCT/US2011/056613

申请日：2011-10-18

申请人： CONOCOPHILLIPS COMPANY ,  ALEGRIA, Edgar Lotero ,  FJARE, Kristi ,  DAUGAARD, Daren ,  PLATON, Alexandru

发明人： ALEGRIA, Edgar Lotero ,  FJARE, Kristi ,  DAUGAARD, Daren ,  PLATON, Alexandru

IPC分类号： C10G1/00

CPC分类号： C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/4081 ,  C10G2300/44 ,  C10L1/04 ,  Y02P30/20

摘要： The present invention relates to a process for converting pyrolysis oil obtained by pyrolysis of biomass into fuel range hydrocarbon by alcoholysis of pyrolysis oil with subsequent hydrotreatment. The current invention provides straightforward methodology to prepare upgradable pyrolysis oil via alcoholysis. The invention uses hydrotreating technology for oxygen removal and hydrocarbon production. The resulting hydrocarbon products are 100% fungible with conventional transportation fuels.

摘要翻译： 本发明涉及通过热解油的醇解和随后的加氢处理将通过将生物质热解成燃料范围烃而获得的热解油转化的方法。 本发明提供了直接的方法来通过醇解制备可升级的热解油。 本发明采用加氢处理技术进行脱氧和生烃。 得到的碳氢化合物产品可与传统运输燃料100％互换。

公开(公告)号：WO2011139551A2

公开(公告)日：2011-11-10

申请号：PCT/US2011/033049

申请日：2011-04-19

申请人： CONOCOPHILLIPS COMPANY ,  BAO, Yun ,  SUGHRUE II, Edward L. ,  YAO, Jianhua ,  SHI, TiePan ,  FJARE, Kristi ,  MYERS, Lisa L. ,  BROWN, Ronald E.

发明人： BAO, Yun ,  SUGHRUE II, Edward L. ,  YAO, Jianhua ,  SHI, TiePan ,  FJARE, Kristi ,  MYERS, Lisa L. ,  BROWN, Ronald E.

CPC分类号： C10G3/50 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G3/49 ,  C10G45/02 ,  C10G45/30 ,  C10G45/44 ,  C10G45/46 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2400/02 ,  Y02P30/42

摘要： Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A process was designed to reduce the coke by co-feeding sugars/sugar derivatives with a saturated recycle stream containing hydrogenated products.

摘要翻译： 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高的氧含量和低的氢含量，因此焦化在沸石升级成液态烃燃料时成为问题。 设计了一种方法，通过将糖/糖衍生物与含有氢化产物的饱和循环流共同进料来减少焦炭。

公开(公告)号：WO2011075322A1

公开(公告)日：2011-06-23

申请号：PCT/US2010/058760

申请日：2010-12-02

申请人： CONOCOPHILLIPS COMPANY ,  LOTERO, Edgar ,  PLATON, Alexandru ,  DAUGAARD, Daren, E. ,  FJARE, Kristi

发明人： LOTERO, Edgar ,  PLATON, Alexandru ,  DAUGAARD, Daren, E. ,  FJARE, Kristi

IPC分类号： C07C1/00

CPC分类号： C10G1/00 ,  C10G1/002 ,  C10G1/006 ,  C10G1/02 ,  C10G2300/1014 ,  C10G2300/44 ,  Y02E50/13 ,  Y02P30/20

摘要： The present invention relates to a process for converting biomass to hydrocarbons and oxygenates. The process may include providing a biomass feedstock and de-oxygenating the biomass feedstock to form a solid-intermediate. The process may further include liquefaction of the solid intermediate, which may be carried out either by rapid heating followed by condensation or by liquefying by applying high pressure. The liquefaction of the solid intermediate may produce a mixture of hydrocarbons and oxygenates, which is generally termed as biocrude. Further, the biocrude is processed by one or more refining means for production of hydrocarbons that can be used as fuel.

摘要翻译： 本发明涉及将生物质转化成烃和含氧化合物的方法。 该方法可以包括提供生物质原料并使生物质原料脱氧以形成固体 - 中间体。 该方法还可以包括液化固体中间体，其可以通过快速加热然后冷凝或通过施加高压液化来进行。 固体中间体的液化可以产生烃和含氧化合物的混合物，其通常称为生物粗制物。 此外，生物粗制物由一种或多种精炼装置加工，用于生产可用作燃料的烃。

公开(公告)号：WO2013086001A1

公开(公告)日：2013-06-13

申请号：PCT/US2012/067955

申请日：2012-12-05

申请人： PHILLIPS 66 COMPANY ,  PANSARE, Sourabh S. ,  DUNN, Brian C. ,  LOTERO, Edgar ,  PLATON, Alexandru ,  GERRITSEN, Leendert Arie ,  MARSHALL, Stephen ,  FJARE, Kristi ,  BROWN, Ronald E.

发明人： PANSARE, Sourabh S. ,  DUNN, Brian C. ,  LOTERO, Edgar ,  PLATON, Alexandru ,  GERRITSEN, Leendert Arie ,  MARSHALL, Stephen ,  FJARE, Kristi ,  BROWN, Ronald E.

IPC分类号： C07C1/00

CPC分类号： C07C1/24 ,  B01D3/009 ,  C10G2300/1011 ,  C10G2300/304 ,  C10G2400/08 ,  C10G2400/30 ,  C10L1/04 ,  Y02P30/20

摘要： A single pass direct conversion of biomass derived oxygenates to longer chain hydrocarbons is described. The longer chain hydrocarbons include higher naphthene content which is quite useful in the distillate range fuels or more particularly, the jet and diesel range fuels. Naphthenes help the biomass derived hydrocarbons meet product specifications for jet and diesel while really helping cold flow properties.

摘要翻译： 描述了生物质衍生的含氧化合物对较长链烃的单程直接转化。 较长链烃包括较高的环烷烃含量，这在馏出物范围的燃料中是非常有用的，更具体地说，是喷气和柴油范围的燃料。 环烷烃帮助生物质衍生的碳氢化合物满足喷气和柴油的产品规格，同时真正帮助冷流动性能。

公开(公告)号：WO2013085944A1

公开(公告)日：2013-06-13

申请号：PCT/US2012/067847

申请日：2012-12-05

申请人： PHILLIPS 66 COMPANY ,  PANSARE, Sourabh S. ,  DUNN, Brian C. ,  LOTERO, Edgar ,  PLATON, Alexandru ,  GERRITSEN, Leendert Arie ,  MARSHALL, Stephen ,  FJARE, Kristi A. ,  BROWN, Ronald E.

发明人： PANSARE, Sourabh S. ,  DUNN, Brian C. ,  LOTERO, Edgar ,  PLATON, Alexandru ,  GERRITSEN, Leendert Arie ,  MARSHALL, Stephen ,  FJARE, Kristi A. ,  BROWN, Ronald E.

IPC分类号： C07C4/00

CPC分类号： C07C1/24 ,  B01D3/009 ,  C10G2300/1011 ,  C10G2300/304 ,  C10G2400/08 ,  C10G2400/30 ,  C10L1/04 ,  Y02P30/20

摘要： A single pass direct conversion of biomass derived oxygenates to longer chain hydrocarbons is described. The longer chain hydrocarbons include higher naphthene content which is quite useful in the distillate range fuels or more particularly, the jet and diesel range fuels. Naphthenes help the biomass derived hydrocarbons meet product specifications for jet and diesel while really helping cold flow properties.

摘要翻译： 描述了将生物质衍生的含氧化合物直接转化成长链烃的单程直接转化。 较长链烃包括较高的环烷烃含量，其在馏出物范围的燃料中更为有用，或者更特别的是喷气和柴油范围的燃料。 环烷烃帮助生物质衍生的碳氢化合物满足喷气和柴油的产品规格，同时真正帮助冷流动性能。

公开(公告)号：WO2013009419A1

公开(公告)日：2013-01-17

申请号：PCT/US2012/041874

申请日：2012-06-11

申请人： PHILLIPS 66 COMPANY ,  JIN, Hong ,  PHILLIPS, Cory B. ,  DAUGAARD, Daren E. ,  FJARE, Kristi A. ,  LEVINE, Robert A.

发明人： JIN, Hong ,  PHILLIPS, Cory B. ,  DAUGAARD, Daren E. ,  FJARE, Kristi A. ,  LEVINE, Robert A.

IPC分类号： C10L1/04

CPC分类号： C10L1/02 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/302 ,  C10L1/04 ,  Y02P30/20

摘要： A blended low sulfur bunker fuel composition comprising a renewable based fuel and a petroleum based fuel is described, along with methods of making. Embodiments of the invention comprise a novel low sulfur bunker fuels composition derived from blending various bio-oils with petroleum based heavy residual fuel oils and distillates where the final sulfur content and carbon intensity is controlled by the ratio of bio-oil to other heavy residual fuel oils and distillates. Embodiments of the invention also disclose processes of making a novel biomass derived low sulfur bunker fuels by blending various bio-oils with petroleum based heavy residual fuel oils and distillates.

摘要翻译： 描述了包含可再生的燃料和基于石油的燃料的混合低硫燃料组合物以及制备方法。 本发明的实施方案包括一种新型的低硫燃料燃料组合物，其衍生自将各种生物油与基于石油的重残余燃料油和馏出物混合，其中最终硫含量和碳强度由生物油与其他重残余燃料的比例控制 油和馏出物。 本发明的实施方案还公开了通过将各种生物油与石油基重残余燃料油和馏出物混合来制备新型生物质衍生的低硫燃料燃料的方法。

公开(公告)号：WO2012061005A3

公开(公告)日：2012-09-27

申请号：PCT/US2011056613

申请日：2011-10-18

申请人： PHILLIPS 66 CO ,  ALEGRIA EDGAR LOTERO ,  FJARE KRISTI ,  DAUGAARD DAREN ,  PLATON ALEXANDRU

发明人： ALEGRIA EDGAR LOTERO ,  FJARE KRISTI ,  DAUGAARD DAREN ,  PLATON ALEXANDRU

IPC分类号： C10L1/04

CPC分类号： C10G3/42 ,  C10G3/44 ,  C10G3/45 ,  C10G3/46 ,  C10G3/47 ,  C10G3/50 ,  C10G2300/1011 ,  C10G2300/4081 ,  C10G2300/44 ,  C10L1/04 ,  Y02P30/20

摘要： The present invention relates to a process for converting pyrolysis oil obtained by pyrolysis of biomass into fuel range hydrocarbon by alcoholysis of pyrolysis oil with subsequent hydrotreatment. The current invention provides straightforward methodology to prepare upgradable pyrolysis oil via alcoholysis. The invention uses hydrotreating technology for oxygen removal and hydrocarbon production. The resulting hydrocarbon products are 100% fungible with conventional transportation fuels.

摘要翻译： 本发明涉及通过热解油的醇解将随后的加氢处理通过将生物质热分解成燃料范围的烃来获得的热解油的方法。 本发明提供了通过醇解制备可升级裂解油的直接方法。 本发明采用加氢处理技术除氧和碳氢化合物生产。 所得烃产品与常规运输燃料100％可替代。

公开(公告)号：WO2011139551A3

公开(公告)日：2012-04-12

申请号：PCT/US2011033049

申请日：2011-04-19

申请人： CONOCOPHILLIPS CO ,  BAO YUN ,  SUGHRUE II EDWARD L ,  YAO JIANHUA ,  SHI TIEPAN ,  FJARE KRISTI ,  MYERS LISA L ,  BROWN RONALD E

发明人： BAO YUN ,  SUGHRUE II EDWARD L ,  YAO JIANHUA ,  SHI TIEPAN ,  FJARE KRISTI ,  MYERS LISA L ,  BROWN RONALD E

IPC分类号： C10G45/02 ,  C01B3/22 ,  C10G45/30 ,  C10G45/44 ,  C10G45/46

CPC分类号： C10G3/50 ,  C01B3/38 ,  C01B2203/0233 ,  C01B2203/0283 ,  C01B2203/062 ,  C01B2203/1058 ,  C01B2203/107 ,  C01B2203/1082 ,  C01B2203/1241 ,  C01B2203/1247 ,  C10G3/49 ,  C10G45/02 ,  C10G45/30 ,  C10G45/44 ,  C10G45/46 ,  C10G2300/1014 ,  C10G2300/202 ,  C10G2300/4081 ,  C10G2300/42 ,  C10G2400/02 ,  Y02P30/42

摘要： Technologies to convert biomass to liquid hydrocarbon fuels are currently being developed to decrease our carbon footprint and increase use of renewable fuels. Since sugars/sugar derivatives from biomass have high oxygen content and low hydrogen content, coke becomes an issue during zeolite upgrading to liquid hydrocarbon fuels. A process was designed to reduce the coke by co-feeding sugars/sugar derivatives with a saturated recycle stream containing hydrogenated products.

摘要翻译： 目前正在开发将生物质转化为液态碳氢化合物燃料的技术，以减少我们的碳足迹和增加可再生燃料的使用。 由于来自生物质的糖/糖衍生物具有高氧含量和低氢含量，因此在沸石升级成液态烃燃料时，焦炭成为问题。 设计了一种方法，通过将糖/糖衍生物与含有氢化产物的饱和循环物流共同进料来减少焦炭。

公开(公告)号：WO2012015575A1

公开(公告)日：2012-02-02

申请号：PCT/US2011/043199

申请日：2011-07-07

申请人： CONOCOPHILLIPS COMPANY ,  FJARE, Kristi ,  YAO, Jianhua ,  SUGHRUE, Edward L. ,  BAE, Jaehoon ,  SHI, TiePan ,  BAO, Yun ,  LOTERO, Edgar

发明人： FJARE, Kristi ,  YAO, Jianhua ,  SUGHRUE, Edward L. ,  BAE, Jaehoon ,  SHI, TiePan ,  BAO, Yun ,  LOTERO, Edgar

IPC分类号： C10G3/00 ,  C10L1/02

CPC分类号： C10G3/40 ,  B01D11/0288 ,  B01D11/0492 ,  C10G1/02 ,  C10G21/02 ,  C10G2300/1014 ,  C10G2300/205 ,  C10G2300/208 ,  C10G2300/44 ,  C10G2400/02 ,  C10G2400/04 ,  C10G2400/08 ,  C10L1/02 ,  C10L1/023 ,  C10L1/026 ,  Y02P30/20

摘要： This invention relates to a process for production of transportation fuels from biomass. More particularly, this invention relates to a process for using solvent to remove metal impurities and high molecular weight components from biomass derived biocrude to prevent potential catalyst poisoning and catalyst bed plugging in biocrude-to-transportation fuel upgrading process.

摘要翻译： 本发明涉及从生物质生产运输燃料的方法。 更具体地说，本发明涉及一种使用溶剂从生物质衍生的生物原料中除去金属杂质和高分子量组分的方法，以防止潜在的催化剂中毒和催化剂床堵塞在生物重运输燃料升级过程中。

公开(公告)号：WO2006115668A1

公开(公告)日：2006-11-02

申请号：PCT/US2006/011021

申请日：2006-03-27

申请人： CONOCOPHILLIPS COMPANY ,  ESPINOZA, Rafael, L. ,  JOTHIMURUGESAN, Kandaswamy ,  JIN, Yaming ,  ORTEGO, JR., J., Dale ,  FJARE, Kristi, A. ,  ORTEGO, Beatrice, C.

发明人： ESPINOZA, Rafael, L. ,  JOTHIMURUGESAN, Kandaswamy ,  JIN, Yaming ,  ORTEGO, JR., J., Dale ,  FJARE, Kristi, A. ,  ORTEGO, Beatrice, C.

IPC分类号： B01J21/04 ,  B01J31/00 ,  B01J23/00 ,  C07C27/00

CPC分类号： B01J37/0207 ,  B01J21/04 ,  B01J21/12 ,  B01J23/40 ,  B01J23/74 ,  B01J23/8913 ,  B01J32/00 ,  B01J35/006 ,  B01J35/023 ,  B01J35/10 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0009 ,  B01J37/0045 ,  B82Y30/00 ,  C01F7/442 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/64 ,  C01P2006/13 ,  C01P2006/14 ,  C01P2006/16 ,  C10G2/33 ,  C10G2/332 ,  C10G2300/70

摘要： A stabilized catalyst support having improved hydrothermal stability, catalyst made therefrom, and method for producing hydrocarbons from synthesis gas using said catalyst. The stabilized support is made by a method comprising treating a crystalline hydrous alumina precursor in contact with at least one structural stabilizer or compound thereof. The crystalline hydrous alumina precursor preferably includes an average crystallite size selected from an optimum range delimited by desired hydrothermal resistance and desired porosity. The crystalline hydrous alumina precursor preferably includes an alumina hydroxide, such as crystalline boehmite, crystalline bayerite, or a plurality thereof differing in average crystallite sizes by at least about 1 nm. The crystalline hydrous alumina precursor may be shaped before or after contact with the structural stabilizer or compound thereof. The treating includes calcining at 450oC or more. Preferred structural stabilizers can include cobalt, magnesium, manganese, manganese, zirconium, boron, aluminum, barium, silicon, lanthanum, oxides thereof, or combinations thereof.

摘要翻译： 具有改善的水热稳定性的稳定的催化剂载体，由其制备的催化剂，以及使用所述催化剂由合成气生产烃的方法。 稳定的载体通过包括处理与至少一种结构稳定剂或其化合物接触的结晶含水氧化铝前体的方法制备。 结晶含水氧化铝前体优选包括平均微晶尺寸，其选自由期望的耐热热性和所需孔隙率限定的最佳范围。 结晶水合氧化铝前体优选包括平均微晶尺寸不同至少约1nm的氧化铝氢氧化物，例如结晶勃姆石，结晶三羟铝石或其多个。 结晶含水氧化铝前体可以在与结构稳定剂或其化合物接触之前或之后成型。 处理包括在450℃以上的煅烧。 优选的结构稳定剂可包括钴，镁，锰，锰，锆，硼，铝，钡，硅，镧，氧化物或其组合。