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1.发明申请PROCESSES FOR THE PREPARATION OF 4-AMINO-3-HALO-6- (SUBSTITUTED)PICOLINATES AND 4-AMINO-5-FLUORO-3-HALO-6- (SUBSTITUTED)PICOLINATES 审中-公开制备4-氨基-3-羟基-6-（取代的）吡啶甲酸酯和4-氨基-5-氟-3-羟基-6-（取代的）吡啶甲酸酯的方法
公开(公告)号：WO2014093591A1
公开(公告)日：2014-06-19
申请号：PCT/US2013/074604
申请日：2013-12-12
申请人： DOW AGROSCIENCES LLC , JOHNSON, Peter Lee , RENGA, James M. , GIAMPIETRO, Natalie C. , WHITEKER, Gregory T. , GALLIFORD, Christopher
发明人： JOHNSON, Peter Lee , RENGA, James M. , GIAMPIETRO, Natalie C. , WHITEKER, Gregory T. , GALLIFORD, Christopher
IPC分类号： A01N43/40
CPC分类号： C07D213/74 , C07C251/12 , C07D213/73 , C07D251/12 , Y02P20/55
摘要： 4-Amino-3-chloro-6-(substituted)picolinates are prepared from difluoroacetic acid or trifluoroacetic acid, tritylamine or t-butylamine as a protecting group, a 3,3-dialkoxyprop-1-yne and a substituted methylene amine by a series of steps. Provided herein are processes for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates and 4-amino-3-halo-6-(substituted)picolinates. More particularly, provided herein are processes for the preparation of 4-amino-5-fluoro-3-halo-6-(substituted)picolinates and 4-amino-3-halo-6- (substituted)picolinates from a non-pyridine source. These picolinates are useful as herbicides.
摘要翻译： 4-氨基-3-氯-6-（取代的）吡啶甲酸盐由二氟乙酸或三氟乙酸，三苯甲基胺或叔丁胺作为保护基团制备，3,3-二烷氧基丙-1-炔和取代的亚甲基胺 一系列步骤。 本文提供了制备4-氨基-5-氟-3-卤代-6-（取代的）吡啶甲酸盐和4-氨基-3-卤代-6-（取代的）吡啶甲酸盐的方法。 更具体地，本文提供的是从非吡啶源制备4-氨基-5-氟-3-卤代-6-（取代的）吡啶甲酸盐和4-氨基-3-卤代-6-（取代的）吡啶甲酸盐的方法 。 这些吡啶甲酸盐作为除草剂是有用的。
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公开(公告)号：WO2006116344A3
公开(公告)日：2006-11-02
申请号：PCT/US2006/015532
申请日：2006-04-21
IPC分类号： C07B53/00
摘要： The present invention comprises synthetically useful processes in which an olefin undergoes an asymmetric reaction selected from the group consisting of hydroformylation, hydrocyanation, hydrocarboxylation and hydroesterification, in the presence of, as catalyst, a transition metal complex of an enantiomerically enriched chiral bis(phospholane) ligand.
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公开(公告)号：WO2005077884A3
公开(公告)日：2005-11-24
申请号：PCT/US2005001624
申请日：2005-01-21
发明人： BRIGGS JOHN R , WHITEKER GREGORY T , KLOSIN JERZY
IPC分类号： C07C29/60 , C07C33/30 , C07C69/732 , C07C209/26 , C07C209/60 , C07C211/03 , C07C211/17 , C07C231/12 , C07C237/08 , C07C311/08 , C07D211/22 , C07D215/22 , C07D215/227 , C07D295/023
CPC分类号： C07C209/60 , C07C33/30 , C07C69/732 , C07C231/12 , C07C311/08 , C07D211/22 , C07D215/227 , C07D295/023 , C07C211/17 , C07C237/08
摘要： The present invention relates to a method comprising the step of contacting under hydroaminomethylation conditions, an olefin, an amine, a rhodium-phosphorous ligand, and synthesis gas (syngas). In particular, it has been discovered that, under some circumstances, a neutral rhodium-monodentate phosphite ligand is prescribed. The invention provides a simple way of making, in high yields and regiospecificity, a variety of products, including pharmacologically active products such as ibutilide, terfenadine, and fexofenadine, and derivatives thereof.
摘要翻译： 本发明涉及包括在氢氨基甲基化条件下接触烯烃，胺，铑 - 磷配体和合成气（合成气）的步骤的方法。 特别地，已经发现，在某些情况下，规定了中性铑 - 单齿亚磷酸酯配体。 本发明提供了以高产率和区域特异性制备各种产品，包括药理活性产物如伊布利特，特非那定和非索非那定及其衍生物的简单方法。
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4.发明申请MANUFACTURE OF HIGH PURITY STEARIN FROM HIGH OLEIC ACID AND LOW PALMITIC ACID SUNFLOWER OIL 审中-公开高油酸和低酸度酸性油的高纯度硬脂酸的制备
公开(公告)号：WO2014070199A1
公开(公告)日：2014-05-08
申请号：PCT/US2012/063386
申请日：2012-11-02
申请人： DOW AGROSCIENCES LLC , SYED, Asim , DEAMICIS, Carl Vincent , WHITEKER, Gregory Todd , PATTERSON, Thomas G. , FLOOK, Josh , GERDES, James Todd Gerdes , KAHL, Charles James , ERICKSON, Angela Lee , BENSON, Robert Martin
发明人： SYED, Asim , DEAMICIS, Carl Vincent , WHITEKER, Gregory Todd , PATTERSON, Thomas G. , FLOOK, Josh , GERDES, James Todd Gerdes , KAHL, Charles James , ERICKSON, Angela Lee , BENSON, Robert Martin
IPC分类号： C11C3/12
摘要： This disclosure concerns methods for producing a high purity stearin comprising, for example, providing a sunflower oil comprising no more than about 4% total saturated fat and hydrogenating the sunflower oil. By way of further example, a method for producing a high purity tristearin may comprise providing sunflower oil comprising at least about 88% oleic acid and hydrogenating the sunflower oil. High purity stearin produced by methods, such as the foregoing, are also disclosed.
摘要翻译： 本公开涉及用于生产高纯度硬脂精的方法，其包括例如提供包含不超过约4％的总饱和脂肪并使葵花籽油加氢的向日葵油。 作为进一步的实例，用于生产高纯度三硬脂酸甘油酯的方法可以包括提供包含至少约88％油酸的向日葵油，并使向日葵油加氢。 还公开了通过诸如前述方法生产的高纯度硬脂精。
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5.发明申请PROCESS FOR THE PREPARATION OF 4-AMINO-5-FLUORO-3-HALO-6-(SUBSTITUTED)PICOLINATES 审中-公开制备4-氨基-5-氟-3-羟基-6-（取代的）吡啶甲酸酯的方法
公开(公告)号：WO2012103047A1
公开(公告)日：2012-08-02
申请号：PCT/US2012/022291
申请日：2012-01-24
申请人： DOW AGROSCIENCES LLC , WHITEKER, Gregory, T. , ARNDT, Kim, E. , RENGA, James, M. , ZHU, Yuanming , LOWE, Christian, T. , SIDDALL, Thomas, L. , PODHOREZ, David, E. , ROTH, Gary, Alan , WEST, Scott, P.
发明人： WHITEKER, Gregory, T. , ARNDT, Kim, E. , RENGA, James, M. , ZHU, Yuanming , LOWE, Christian, T. , SIDDALL, Thomas, L. , PODHOREZ, David, E. , ROTH, Gary, Alan , WEST, Scott, P.
IPC分类号： A01N43/40 , C07D213/04
CPC分类号： C07D213/803 , C07D213/79
摘要： 4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinates by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation and transition metal assisted coupling.
摘要翻译： 通过涉及氟交换，胺化，卤素交换，卤化和过渡金属辅助偶联的一系列步骤，方便地由4,5,6-三氯吡啶酸盐制备4-氨基-5-氟-3-卤代-6-（取代的）吡啶甲酸盐。
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公开(公告)号：WO2010144380A1
公开(公告)日：2010-12-16
申请号：PCT/US2010/037670
申请日：2010-06-08
发明人： RENGA, James , WHITEKER, Gregory , ARNDT, Kim , LOWE, Christian
IPC分类号： C07D213/79 , C07D211/90
CPC分类号： C07D213/79 , C07D211/90
摘要： 3-Halo-6-(aryl)-4-iminotetrahydropicolinic acid esters are heated with polar solvents to prepare 6-(aryl)-4-aminopicolinates.
摘要翻译： 将3-卤代-6-（芳基）-4-亚氨基四氢吡啶甲酸酯用极性溶剂加热以制备6-（芳基）-4-氨基吡啶甲酸酯。
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7.发明申请PROCESS FOR THE PREPARATION OF 4-AMINO-5-FLUORO-3-HALO-6-(SUBSTITUTED)PICOLINATES 审中-公开制备4-氨基-5-氟-3-羟基-6-（取代的）吡啶甲酸酯的方法
公开(公告)号：WO2012103045A1
公开(公告)日：2012-08-02
申请号：PCT/US2012/022289
申请日：2012-01-24
申请人： DOW AGROSCIENCES LLC , ZHU, Yuanming , WHITEKER, Gregory, T. , RENGA, James, M. , ARNDT, Kim, E. , ROTH, Gary, Alan , PODHOREZ, David, E. , WEST, Scott, P.
发明人： ZHU, Yuanming , WHITEKER, Gregory, T. , RENGA, James, M. , ARNDT, Kim, E. , ROTH, Gary, Alan , PODHOREZ, David, E. , WEST, Scott, P.
IPC分类号： A01N43/40 , C07D213/04
CPC分类号： C07D213/81 , C07D213/78 , C07D213/79 , C07D213/803
摘要： 4-Amino-5-fluoro-3-halo-6-(substituted)picolinates are conveniently prepared from 4,5,6-trichloropicolinonitrile by a series of steps involving fluorine exchange, amination, halogen exchange, halogenation, nitrile hydrolysis, esterification, and transition metal assisted coupling.
摘要翻译： 通过一系列涉及氟交换，胺化，卤素交换，卤化，腈水解，酯化等步骤的方法，可以方便地从4,5,6-三氯吡啶腈制备4-氨基-5-氟-3-卤代-6-（取代的） 和过渡金属辅助耦合。
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8.发明申请CATALYSTS, PROCESSES FOR MAKING CATALYSTS, PROCESSES FOR MAKING POLYOLEFIN COMPOSITIONS AND POLYOLEFIN COMPOSITIONS 审中-公开催化剂，制备催化剂的方法，制备聚烯烃组合物的方法和聚烯烃组合物
公开(公告)号：WO2010102163A3
公开(公告)日：2011-01-13
申请号：PCT/US2010026296
申请日：2010-03-05
发明人： KUHLMAN ROGER , WHITEKER GREGORY
CPC分类号： C07F7/00 , C07D521/00 , C08F10/00 , C08F210/16 , C08F210/14 , C08F4/64144 , C08F4/62144
摘要： The present invention relates to compositions and processes of making catalysts and polyolefins. More particularly, the invention relates to snap shut catalysts, processes for making the catalysts, processes for making polyolefins using the catalysts and the polyolefins resulting therefrom.
摘要翻译： 本发明涉及制备催化剂和聚烯烃的组合物和方法。 更具体地，本发明涉及快速关闭催化剂，制备催化剂的方法，使用催化剂制备聚烯烃的方法和由其产生的聚烯烃。
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公开(公告)号：WO2005077884A2
公开(公告)日：2005-08-25
申请号：PCT/US2005/001624
申请日：2005-01-21
申请人： UNION CARBIDE CHEMICALS & PLASTICS TECHNOLOGY CORPORATION , BRIGGS, John, R. , WHITEKER, Gregory, T. , KLOSIN, Jerzy
IPC分类号： C07C209/26
CPC分类号： C07C209/60 , C07C33/30 , C07C69/732 , C07C231/12 , C07C311/08 , C07D211/22 , C07D215/227 , C07D295/023 , C07C211/17 , C07C237/08
摘要： The present invention relates to a method comprising the step of contacting under hydroaminomethylation conditions, an olefin, an amine, a rhodium-phosphorous ligand, and synthesis gas (syngas). In particular, it has been discovered that, under some circumstances, a neutral rhodium-monodentate phosphite ligand is prescribed. The invention provides a simple way of making, in high yields and regiospecificity, a variety of products, including pharmacologically active products such as ibutilide, terfenadine, and fexofenadine, and derivatives thereof.
摘要翻译： 本发明涉及包括在氢氨甲基化条件下接触烯烃，胺，铑 - 磷配体和合成气（合成气）的步骤的方法。 具体而言，已经发现，在某些情况下，规定了中性铑 - 单齿亚磷酸酯配体。 本发明提供了以高产率和区域特异性制备各种产品的简单方法，包括药理学活性产品如伊布利特，特非那定和非索非那定及其衍生物。
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10.发明申请ASYMMETRIC CATALYSTS PREPARED FROM OPTICALLY ACTIVE BISPHOSPHITES BRIDGED BY ACHIRAL DIOLS 审中-公开由乙酰胆碱交联的光学活性双磷酸盐制备的不对称催化剂
公开(公告)号：WO2004094442A2
公开(公告)日：2004-11-04
申请号：PCT/US2004/006291
申请日：2004-03-02
IPC分类号： C07F9/6574
CPC分类号： B01J31/1855 , B01J31/1845 , B01J31/185 , B01J2231/321 , B01J2531/0266 , B01J2531/74 , B01J2531/80 , B01J2531/82 , B01J2531/821 , B01J2531/822 , B01J2531/824 , B01J2531/825 , B01J2531/827 , B01J2531/828 , B01J2531/847 , C07B2200/07 , C07C45/505 , C07C67/293 , C07C255/17 , C07F9/657154 , C07F9/65746 , Y02P20/582 , C07C69/003 , C07C69/14
摘要： This invention relates to asymmetric hydroformylation (hf) processes in which a prochiral or chiral compound is contacted in the presence of an optically active metal-ligand complex catalyst to produce an optically active aldehyde or product derived from an optically active aldehyde. The invention encompasses novel ligands and catalysts for use in such processes.
摘要翻译： 本发明涉及不对称加氢甲酰化（hf）方法，其中前旋手性或手性化合物在光学活性金属 - 配体配合物催化剂存在下接触以产生光学活性醛或衍生自光学活性醛的产物。 本发明包括用于这些方法的新型配体和催化剂。
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