公开(公告)号：WO2016005935A1

公开(公告)日：2016-01-14

申请号：PCT/IB2015/055196

申请日：2015-07-09

Applicant: RELIANCE INDUSTRIES LIMITED

Inventor： UPPARA, Parasuveera ,  RAJE, Vivek ,  ADURI, Pavankumar ,  DUKHANDE, Vibhuti ,  SALVI, Prathmesh Pradeep

IPC: B01J31/02 ,  C07C2/22

CPC classification number: B01J31/0298 ,  B01J31/0202 ,  B01J31/0222 ,  B01J31/0237 ,  B01J31/0287 ,  B01J37/009 ,  B01J37/04 ,  B01J2231/20 ,  B01J2231/326 ,  B01J2231/4205 ,  B01J2231/44 ,  B01J2531/004 ,  C07C2/22 ,  C07C2/66 ,  C07C2/68 ,  C07C2/861 ,  C07C37/11 ,  C07C45/46 ,  C07C45/68 ,  C07C67/293 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2527/138 ,  C07C2531/02 ,  C07F5/06 ,  C07C11/02 ,  C07C15/16 ,  C07C15/107 ,  C07C15/02 ,  C07C49/786 ,  C07C49/78 ,  C07C69/157

Abstract: The present disclosure relates to preparation of liquid salt including but not limiting to ionic liquid and applications thereof. More particularly, the present disclosure provides a process for preparing ionic liquid which comprises reacting at least one electron-pair acceptor and at least one electron-pair donor to form an adduct, and reacting the adduct with at least one electron-pair acceptor to prepare said salt. The present disclosure also provides for applications of the ionic liquid prepared in the present disclosure.

Abstract translation: 本公开涉及液体盐的制备，包括但不限于离子液体及其应用。 更具体地说，本公开提供了一种制备离子液体的方法，其包括使至少一个电子对受体和至少一个电子对供体反应形成加合物，并使加合物与至少一个电子对受体反应以制备 说盐 本公开还提供了在本公开中制备的离子液体的应用。

公开(公告)号：WO2011098375A2

公开(公告)日：2011-08-18

申请号：PCT/EP2011051390

申请日：2011-02-01

Applicant: SALTIGO GMBH ,  GOTTA MATTHIAS ,  LEHNEMANN BERND WILHELM ,  CZAPLIK WALDEMAR MAXIMILIAN ,  MAYER MATTHIAS ,  JACOBI VON WANGELIN AXEL

Inventor： GOTTA MATTHIAS ,  LEHNEMANN BERND WILHELM ,  CZAPLIK WALDEMAR MAXIMILIAN ,  MAYER MATTHIAS ,  JACOBI VON WANGELIN AXEL

IPC: C07B49/00

CPC classification number: C07C253/04 ,  C07B37/04 ,  C07B49/00 ,  C07C1/30 ,  C07C1/326 ,  C07C17/26 ,  C07C17/2632 ,  C07C41/24 ,  C07C41/30 ,  C07C67/343 ,  C07C209/68 ,  C07C209/74 ,  C07C253/30 ,  C07C2527/128 ,  C07C2531/22 ,  C07C2603/26 ,  C07C11/02 ,  C07C15/44 ,  C07C43/2055 ,  C07C43/205 ,  C07C69/612 ,  C07C25/24 ,  C07C211/48 ,  C07C255/50

Abstract: The invention relates to a method for producing organic compounds of the general formula (I) R-R' (I), by reacting a corresponding compound of the general formula (II) R-X (H), where X stands for fluorine, chlorine, bromine, or iodine, forming a magnesium organic compound of the general formula (III) [M+]n [RmMgXkY1] (III), compounds of the formula (III) being reacted with a compound of the general formula (IV), characterized in that the reaction of (III) with (IV) is performed in the presence of a) catalytic quantities of an iron compound, relative to the compound of the general formula (II), and optionally in the presence b) of an additive comprising nitrogen, oxygen, and/or phosphorous in a catalytic or stoichiometric quantity relative to the compound of the general formula (II).

Abstract translation: 描述制备通式（I）R-R”的有机化合物的方法（I）中，由通式的相应化合物反应（II）RX（H），其中X是氟，氯，溴或碘，以一个 有机镁通式化合物（III）[M +] n的[RmMgXkY1]（III），其中，所述式（III）与通式（IV）的化合物的化合物反应，其特征在于，随着反应（III） （IV），催化在的）量的铁化合物的存在下，根据通式（II）化合物，以及任选地在存在b）一种氮，氧和/或基于所述化合物在催化量或化学计算量的添加剂的含磷 通式（II）的化合物。

公开(公告)号：WO2007064105A1

公开(公告)日：2007-06-07

申请号：PCT/KR2006/004970

申请日：2006-11-24

Applicant: Seoul National University Industry Foundation ,  KIM, Young Gyu ,  KIM, Byung Hyun ,  LEE, Jong Gil ,  YIM, Taeeun

Inventor： KIM, Young Gyu ,  KIM, Byung Hyun ,  LEE, Jong Gil ,  YIM, Taeeun

IPC: C07C4/24

CPC classification number: C07C15/24 ,  C07C49/213 ,  C07C2527/08 ,  C07C2527/128 ,  C07C2527/135 ,  C07C2531/08 ,  C07C2531/10 ,  Y02P20/55

Abstract: The present invention relates to a novel method for preparing 2,6-dialkylnaphthalene with high selectivity and high yield using entirely novel starting materials through alkylation and cyclodehydration without necessitating separation or purification of isomers, which has been a problem of the conventional method, and particularly to a method comprising the steps of (a) preparing an intermediate by alkylating an aromatic compound with an alkene compound in an equivalent ratio in the presence of a catalyst and (b) preparing 2,6-dialkylnaphthalene through cyclodehydration of the intermediate.

Abstract translation: 本发明涉及一种使用全新的原料通过烷基化和环化脱水制备2,6-二烷基萘的新方法，而不需要分离或纯化异构体，这是常规方法的问题，特别是 涉及一种方法，包括以下步骤：（a）通过在催化剂存在下以相当比例的烯烃化合物烷基化芳族化合物来制备中间体，和（b）通过中间体的环化脱水制备2,6-二烷基萘。

公开(公告)号：WO2005019143A1

公开(公告)日：2005-03-03

申请号：PCT/US2003/036933

申请日：2003-11-19

Applicant: GRT, INC. ,  THE REGENTS OF THE UNIVERSITY OF CALIFORNIA

Inventor： SHERMAN, Jeffrey, H. ,  MCFARLAND, Eric, W. ,  WEISS, Michael, J. ,  LORKOVIC, Ivan, Marc ,  LAVERMAN, Leroy, E. ,  SUN, Shouli ,  SCHAEFER, Dieter, J. ,  STUCKY, Galen ,  FORD, Peter

IPC: C07C27/00

CPC classification number: C07C45/27 ,  C07C1/30 ,  C07C17/10 ,  C07C29/124 ,  C07C29/58 ,  C07C41/16 ,  C07C2521/02 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2523/04 ,  C07C2523/06 ,  C07C2523/42 ,  C07C2523/745 ,  C07C2523/75 ,  C07C2523/80 ,  C07C2527/128 ,  C07C2527/133 ,  C07D301/26 ,  Y02P20/582 ,  C07C19/043 ,  C07C19/07 ,  C07C19/075 ,  C07C47/06 ,  C07C31/08 ,  C07C31/125 ,  C07C43/04 ,  C07C43/06

Abstract: A reactant selected from the group consisting of alkanes, alkenes, alkynes, dienes, and aromatics is reacted with a halide selected from the group including chlorine, bromine, and iodine to form a first reaction product. The first reaction product is reacted with a solid oxidizer to form a product selected from the group including olefins, alcohols, ethers, and aldehydes, and spent oxidizer. The spent oxidizer is oxidized to form the original solid oxidizer and the second reactant which are recycled.

Abstract translation: 选自烷烃，烯烃，炔烃，二烯烃和芳族化合物的反应物与选自氯，溴和碘的卤化物反应形成第一反应产物。 将第一反应产物与固体氧化剂反应以形成选自包括烯烃，醇，醚和醛的产物和废氧化剂。 废氧化剂被氧化以形成原始的固体氧化剂和再循环的第二反应物。

公开(公告)号：WO1993000164A1

公开(公告)日：1993-01-07

申请号：PCT/US1992005157

申请日：1992-06-18

Applicant: CATALYTICA, INC. ,  KING, David, L. ,  RAO, Pradip ,  COOPER, Michael, D. ,  SAY, Jerome, E.

Inventor： CATALYTICA, INC.

IPC: B01J20/34

CPC classification number: B01J21/04 ,  B01J27/08 ,  B01J27/128 ,  B01J27/135 ,  B01J27/32 ,  B01J38/12 ,  C07C2/60 ,  C07C2521/04 ,  C07C2527/08 ,  C07C2527/10 ,  C07C2527/1213 ,  C07C2527/125 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2527/133 ,  C07C2527/135 ,  C07C2527/14 ,  Y02P20/584 ,  Y10S585/906

Abstract: This invention is a process for the regeneration of a catalyst system component comprising certain transition aluminas promoted with a Lewis acid (preferably BF3) which have been used in the alkylation of isoparaffin with olefins. The process involves the calcination of the catalyst system component to volatilize and to oxidize the reaction product residue adhering to the solid catalyst. The process may include recovery and recycle of the involved Lewis acid.

Abstract translation: 本发明是一种催化剂体系成分的再生方法，该催化剂体系成分包含用路易斯酸（优选BF 3）促进异构烷烃与烯烃的烷基化反应促进的某些过渡氧化铝。 该方法包括煅烧催化剂体系组分挥发并氧化附着在固体催化剂上的反应产物残余物。 该方法可以包括所涉及的路易斯酸的回收和再循环。

公开(公告)号：WO2013040514A1

公开(公告)日：2013-03-21

申请号：PCT/US2012/055651

申请日：2012-09-14

Applicant: MICROMIDAS INC. ,  MICHIGAN MOLECULAR INSTITUTE ,  MASUNO, Makoto, N. ,  CANNON, Douglas ,  BISSELL, John ,  SMITH, Ryan, L. ,  FOSTER, Marc ,  WOOD, Alex, Benjamin ,  SMITH, Patrick, B. ,  HUCUL, Dennis A.

Inventor： MASUNO, Makoto, N. ,  CANNON, Douglas ,  BISSELL, John ,  SMITH, Ryan, L. ,  FOSTER, Marc ,  WOOD, Alex, Benjamin ,  SMITH, Patrick, B. ,  HUCUL, Dennis A.

IPC: C07C15/08 ,  C07C2/52

CPC classification number: C07C51/16 ,  C07C2/52 ,  C07C2/862 ,  C07C2/865 ,  C07C15/08 ,  C07C2521/18 ,  C07C2527/02 ,  C07C2527/053 ,  C07C2527/08 ,  C07C2527/10 ,  C07C2527/122 ,  C07C2527/126 ,  C07C2527/128 ,  C07C2527/132 ,  C07C2527/133 ,  C07C2527/135 ,  C07C2527/138 ,  C07C2527/14 ,  C07C2527/16 ,  C07C2529/08 ,  C07C2529/14 ,  C07C2529/24 ,  C07C2531/02 ,  C07C2531/04 ,  C07C2531/12 ,  C07C15/06

Abstract: The present disclosure provides methods to produce para -xylene, toluene, and other compounds from renewable sources ( e.g ., cellulose, hemicellulose) and ethylene in the presence of an acid, such as a Lewis acid. For example, cellulose and/or hemicellulose may be converted into 2,5-dimethylfuran (DMF) and 2-methylfuran, which may be converted into para -xylene and toluene, respectively. In particular, para -xylene can then be oxidized to form terephthalic acid.

Abstract translation: 本公开提供了在酸例如路易斯酸存在下从可再生来源（例如纤维素，半纤维素）和乙烯生产对二甲苯，甲苯和其它化合物的方法。 例如，纤维素和/或半纤维素可以转化成2,5-二甲基呋喃（DMF）和2-甲基呋喃，其可以分别转化成对二甲苯和甲苯。 特别地，可以将对二甲苯氧化形成对苯二甲酸。

公开(公告)号：WO2011006848A1

公开(公告)日：2011-01-20

申请号：PCT/EP2010/059915

申请日：2010-07-09

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  CHINA UNIVERSITY OF PETROLEUM ,  LIU, Zhichang ,  XU, Chunming ,  ZHANG, Rui ,  MENG, Xianghai ,  PATRONI, Ana Cecilia ,  KLUSENER, Peter Anton August ,  VAN DEN BOSCH, Albertus Vincentius Petrus

Inventor： LIU, Zhichang ,  XU, Chunming ,  ZHANG, Rui ,  MENG, Xianghai ,  PATRONI, Ana Cecilia ,  KLUSENER, Peter Anton August ,  VAN DEN BOSCH, Albertus Vincentius Petrus

IPC: C10G29/20 ,  C07C2/58

CPC classification number: C10G29/205 ,  C07C2/60 ,  C07C2527/053 ,  C07C2527/055 ,  C07C2527/06 ,  C07C2527/122 ,  C07C2527/128 ,  C07C2527/135 ,  C07C2527/138 ,  C07C2527/25 ,  C07C2531/02 ,  C10G2300/1081 ,  C10G2300/1092 ,  C10G2300/70 ,  Y02P20/584 ,  Y10T29/49716

Abstract: The present invention provides a method for revamping an HF or sulphuric acid alkylation unit to an ionic liquid alkylation unit, wherein the HF or sulphuric acid alkylation unit comprise at least: -a reactor unit for contacting catalyst and hydrocarbon reactants; -a separator unit for separating a reactor effluent into a catalyst phase and an alkylate-comprising hydrocarbon phase; -a fractionator unit for fractionating the alkylate- comprising hydrocarbon phase into at least one stream comprising alkylate; -a catalyst phase recycle means to recycle at least part of the catalyst phase from the separator unit to the reactor unit; which method includes: -adapting the catalyst phase recycle means by providing a means for acid injection and/or a means for halohydrocarbon injection into the catalyst recycle means. The invention further provides a method for the production of alkylate.

Abstract translation: 本发明提供了将HF或硫酸烷基化单元改性为离子液体烷基化单元的方法，其中HF或硫酸烷基化单元至少包括： - 用于使催化剂和烃反应物接触的反应器单元; - 用于将反应器流出物分离成催化剂相的分离器单元和包含烷基化物的烃相; 一个用于将包含烷基化物的烃相分级成至少一种包含烷基化物的流的分馏器单元; - 催化剂相再循环装置，用于将至少部分催化剂相从分离器单元再循环到反应器单元; 该方法包括： - 通过提供酸注入的方法和/或将卤代烃注入到催化剂再循环装置中的手段，来适应催化剂相循环装置。 本发明还提供了一种生产烷基化物的方法。

公开(公告)号：WO2006005762A1

公开(公告)日：2006-01-19

申请号：PCT/EP2005/053352

申请日：2005-07-13

Applicant: SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. ,  DE BOER, Eric Johannes Maria ,  VAN DER HEIJDEN, Harry ,  OOSTERVELD, Inge ,  VAN ZON, Arie

Inventor： DE BOER, Eric Johannes Maria ,  VAN DER HEIJDEN, Harry ,  OOSTERVELD, Inge ,  VAN ZON, Arie

IPC: C07C2/22

CPC classification number: C07C2/08 ,  C07C1/327 ,  C07C5/2575 ,  C07C2523/755 ,  C07C2527/128 ,  C07C2531/14 ,  C07C11/02

Abstract: A process for the preparation of linear alpha olefins having 2n carbon atoms from linear alpha olefins having n carbon atoms comprising the steps of: (a) dimerizing a linear alpha olefin having n carbon atoms in the presence of a dimerization catalyst to produce a linear internal olefin having 2n carbon atoms; (b)(i)reacting the linear internal olefin having 2n carbon atoms produced in step (a) with a trialkylaluminium compound in the presence of a catalytic amount of an isomerization/displacement catalyst in order to cause isomerization of the linear internal olefin and to displace alkyl group(s) from said trialkylaluminium compound to form an alkyl aluminium compound wherein at least one of the alkyl groups bound to aluminium is a linear alkyl which has been derived from the isomerization of said linear internal olefin, and (b)(ii) reacting said alkyl aluminium compound with an alpha olefin optionally in the presence of a displacement catalyst so as to displace said linear alkyl from said alkyl aluminium compound to form a linear alpha olefin having 2n carbon atoms.

Abstract translation: 制备具有n个碳原子的直链α-烯烃具有2n个碳原子的直链α-烯烃的方法，包括以下步骤：（a）在二聚催化剂存在下将具有n个碳原子的直链α-烯烃二聚化以产生线性内部 具有2n个碳原子的烯烃; （b）（i）使催化量的异构化/置换催化剂存在下使步骤（a）中产生的具有2n个碳原子的直链内烯烃与三烷基铝化合物反应，以使线性内烯烃异构化， 从所述三烷基铝化合物取代烷基以形成烷基铝化合物，其中至少一个与铝结合的烷基是源自所述线性内烯烃的异构化的直链烷基，和（b）（ii ）使所述烷基铝化合物与α-烯烃反应，任选地在置换催化剂存在下使所述烷基铝化合物的所述直链烷基取代形成具有2n个碳原子的直链α-烯烃。

公开(公告)号：WO2003074455A1

公开(公告)日：2003-09-12

申请号：PCT/JP2003/002665

申请日：2003-03-06

Applicant: 科学技術振興事業団 ,  櫻井 英樹 ,  三治 敬信

Inventor： 櫻井 英樹 ,  三治 敬信

IPC: C07C15/04

CPC classification number: C07C1/26 ,  C07C1/30 ,  C07C2523/06 ,  C07C2527/128 ,  C07C2527/13 ,  C07C2527/138 ,  C07C2531/22 ,  C07C2531/24 ,  C07C15/04 ,  C07C15/14 ,  C07C15/00

Abstract: A process for hydrodehalogenation of aromatic polyhalides, characterized by conducting hydrodehalogenation of an aromatic polyhalide in a reaction system comprising an organic solvent, an aromatic polyhalide, an aqueous solution of an inorganic base as the scavenger for the hydrogen halide to be formed by hydro- dehalogenation of the aromatic polyhalide, isopropyl alcohol as the hydrogen source for the hydrodechlorination, and a catalyst system composed of both an organonickel complex catalyzing the hydrodehalogenation of the aromatic polyhalide and PPh3.

Abstract translation: 芳族多卤化物的加氢脱卤的方法，其特征在于在包括有机溶剂，芳族多卤化物，无机碱的水溶液作为通过氢化脱卤形成的卤化氢的清除剂的反应体系中进行芳族多卤化物的加氢脱卤 的芳族多卤化物，异丙醇作为加氢脱氯的氢源，以及由催化芳族多卤化物和PPh 3的加氢脱卤的有机镍配合物组成的催化剂体系。

公开(公告)号：WO01072672A1

公开(公告)日：2001-10-04

申请号：PCT/FR2001/000932

申请日：2001-03-27

IPC: C07C2/88 ,  C07B61/00 ,  C07C2/86 ,  C07C13/48 ,  C09K5/08 ,  C09K5/10

CPC classification number: C09K5/10 ,  C07C2/861 ,  C07C13/48 ,  C07C2527/128

Abstract: The invention concerns compositions comprising a mixture of mono- and polybenzyl-1,2,3,4-tetrahydronaphthalenes. The invention also concerns said compositions or a mixture of monobenzyl-1,2,3,4-tetrahydronaphthalene isomers as heat transfer fluid. Said compositions or the mixture of monobenzyl-1,2,3,4-tetrahydronaphthalene isomers are obtained by the action of benzyl chloride on 1,2,3,4-tetrahydronaphthalene in the presence of FeCl3.

Abstract translation: 本发明涉及包含单苄氧基-1,2,3,4-四氢萘混合物的组合物。 本发明还涉及所述组合物或单苄基-1,2,3,4-四氢萘异构体作为传热流体的混合物。 所述组合物或单苄基-1,2,3,4-四氢萘异构体的混合物是通过在FeCl 3存在下苄基氯作用于1,2,3,4-四氢化萘的作用获得的。