STRUCTURAL ADHESIVE AND BONDING APPLICATION THEREOF
    2.
    发明申请
    STRUCTURAL ADHESIVE AND BONDING APPLICATION THEREOF 审中-公开
    结构粘合和粘结应用

    公开(公告)号:WO2013070415A1

    公开(公告)日:2013-05-16

    申请号:PCT/US2012/060975

    申请日:2012-10-19

    摘要: A structural adhesive composition that is suitable for high-strength bonding of metals and aerospace structural materials. In one embodiment, the structural adhesive composition based on a two-part system, which is curable at or below 200°F (93 °C). The two-part system is composed of a resinous part (A) and a catalyst part (B), which may be stored separately at room temperature until they are ready to be used. The resinous part (A) includes at least two different multifunctional epoxy resins with different functionality selected from difunctional, trifunctional, and tetrafunctional epoxy resins, certain toughening components, and inorganic filler particles as a rheology/thixotrophy modifying component. The toughening components include core-shell rubber particles with different particle sizes and at least one of an elastomeric polymer and a polyethersulfone polymer. The catalyst part (B) includes an aliphatic or cyclic amine compound as a curing agent and inorganic filler as a rheology/thixotropy modifying component. The weight ratio of part (A) to part (B) is within the range of 3:2 to 10:2. In another embodiment, the structural adhesive composition is based on a one-part system which includes the components of the resinous part (A) in the two-part system mixed with a latent amine curing agent. The one-part system may further include an imidazole and/or an aliphatic amine. The one-part system is curable within the temperature range of 140-300°F (60-150°C). The paste adhesive disclosed herein has film-like properties and is particularly useful in rapid-assembly aerospace structure bonding applications.

    摘要翻译: 适用于金属和航空航天结构材料的高强度粘合的结构粘合剂组合物。 在一个实施方案中,基于两部分系统的结构粘合剂组合物,其可在或低于200°F(93℃)下固化。 两部分系统由树脂部分(A)和催化剂部分(B)组成,可以在室温下分开储存,直到准备使用。 树脂部分(A)包括至少两种具有不同官能度的功能性多官能环氧树脂,其中二官能,三官能和四官能环氧树脂,某些增韧组分和无机填料颗粒作为流变学/触变性改良组分。 增韧组分包括具有不同粒度的核 - 壳橡胶颗粒和弹性体聚合物和聚醚砜聚合物中的至少一种。 催化剂部分(B)包括作为固化剂的脂族或环状胺化合物和作为流变/触变性改性成分的无机填料。 部分(A)与部分(B)的重量比在3:2至10:2的范围内。 在另一个实施方案中,结构粘合剂组合物基于一部分系统,其包括与潜伏胺固化剂混合的两部分体系中的树脂部分(A)的组分。 单组分体系可以进一步包括咪唑和/或脂族胺。 单组分系统可在140-300°F(60-150°C)的温度范围内固化。 本文公开的糊状粘合剂具有膜状特性,并且在快速组装航空航天结构粘合应用中特别有用。

    FIBER REINFORCED PUTTY, DEVICE AND METHOD FOR ITS MANUFACTURE, DEVICE AND METHOD TO MAKE LAMINATES AND OTHER FINISHED PARTS FROM THE PUTTY, AND A LAMINATE MADE FROM THE PUTTY
    3.
    发明申请
    FIBER REINFORCED PUTTY, DEVICE AND METHOD FOR ITS MANUFACTURE, DEVICE AND METHOD TO MAKE LAMINATES AND OTHER FINISHED PARTS FROM THE PUTTY, AND A LAMINATE MADE FROM THE PUTTY 审中-公开
    纤维增强腻子,其制造方法及其制造方法,设备和方法,用于制造层压材料和其他成品部件,以及从馅料制成的层压材料

    公开(公告)号:WO2011116923A3

    公开(公告)日:2013-03-14

    申请号:PCT/EP2011001395

    申请日:2011-03-21

    申请人: FUSCO LUCIANO

    发明人: FUSCO LUCIANO

    IPC分类号: B29C70/08 B32B27/04 C08J5/04

    摘要: The invention relates to a filamentized fiber reinforced putty compound, to parts made from said putty, and to devices and methods for manufacturing both the putty and the parts. The compound of the invention is formed by a chopped fibers composition including monofilaments that have been broken down from chopped strands and a UV and/or chemical curable resin composition and is a ready-to-mold plastic putty used in molding, mainly by continuous lamination/pultrusion/extrusion and injection. The putty fiber reinforcement, whose weight makes up between 10 and 50% of the total weight of the putty, more particularly in the range of 20 to 40%, is formed by one of the group consisting of at least one type of chopped strands that has been entirely broken down into filaments, and at least one type of chopped strands that has been entirely broken down into filaments in combination with at least one type of chopped strands that has been left intact; each one of the types of fibers involved in the same composition is chopped in one or more lengths of between 3 and 50 mm, with the bulk preferably being between 12 and 30 mm; the percentage of the fiber filaments in the putty being the amount necessary and sufficient to capillarity reinforce the resin thoroughly and everywhere in the putty.

    摘要翻译: 本发明涉及一种丝状纤维增强油灰化合物,由所述油灰制成的部件以及用于制造油灰和部件的装置和方法。 本发明的化合物是由短切纤维组合物形成的,该组合物包括从短切原料中分解的单丝和UV和/或化学固化树脂组合物,并且是主要通过连续层压成型的成型模塑胶浆 /拉挤/挤出和注射。 腻子纤维增强物的重量占腻子总重量的10-50%之间,特别是在20至40%的范围内,由至少一种类型的切碎的丝线之一组成, 已经完全分解成细丝,并且至少一种类型的短切丝已经完全分解成长丝,并与至少一种已经保持完整的切断的丝束组合; 涉及相同组合物的纤维类型中的每一种以3至50mm的一个或多个长度切碎,体积优选在12至30mm之间; 腻子中纤维长丝的百分比是所需量和足以使毛细作用量增加的树脂,彻底地增强了腻子中的各处。

    REINFORCED HOLLOW PROFILES
    6.
    发明申请
    REINFORCED HOLLOW PROFILES 审中-公开
    加强中空轮廓

    公开(公告)号:WO2011163357A2

    公开(公告)日:2011-12-29

    申请号:PCT/US2011/041445

    申请日:2011-06-22

    IPC分类号: B29C70/08

    摘要: A hollow lineal profile formed from a continuous fiber reinforced ribbon ("CFRT") that contains a plurality of continuous fibers embedded within a first thermoplastic polymer matrix. To enhance the tensile strength of the profile, the continuous fibers are aligned within the ribbon in a substantially longitudinal direction (e.g., the direction of pultrusion). In addition to continuous fibers, the hollow profile of the present invention also contains a plurality of long fibers that may be optionally embedded within a second thermoplastic matrix to form a long fiber reinforced thermoplastic ("LFRT"). The long fibers may be incorporated into the continuous fiber ribbon or formed as a separate layer of the profile. Regardless, at least a portion of the long fibers are oriented at an angle (e.g., 90°) to the longitudinal direction to provide increased transverse strength to the profile.

    摘要翻译: 由连续纤维增强带(“CFRT”)形成的空心线状轮廓,其包含嵌入在第一热塑性聚合物基质内的多个连续纤维。 为了提高轮廓的拉伸强度,连续纤维在丝带内沿基本上纵向的方向(例如拉挤方向)对准。 除了连续纤维之外,本发明的中空型材还包含多根长纤维,其可任选地嵌入第二热塑性基质中以形成长纤维增强热塑性塑料(“LFRT”)。 长纤维可以结合到连续纤维带中或形成为轮廓的单独层。 无论如何,长纤维的至少一部分以与纵向方向成一定角度(例如90°)取向,以提供对轮廓的增强的横向强度。

    FRP CONTINUOUS LAMINATE, LAMINATION METHOD AND LAMINATION DEVICE, BY INVERTED EXTRUSION TECHNIQUE
    7.
    发明申请
    FRP CONTINUOUS LAMINATE, LAMINATION METHOD AND LAMINATION DEVICE, BY INVERTED EXTRUSION TECHNIQUE 审中-公开
    FRP连续层压板,层压法和层压装置,采用倒角挤压技术

    公开(公告)号:WO2011116784A1

    公开(公告)日:2011-09-29

    申请号:PCT/EP2010/001791

    申请日:2010-03-22

    申请人: FUSCO, Luciano

    发明人: FUSCO, Luciano

    IPC分类号: B29C70/08 B32B27/04 C08J5/04

    摘要: The invention relates to a device for continuous lamination, a corresponding method and a FRP continuous laminate, comprising: a fiber reinforced plastic (FRP) structural core (15) comprising a composite filamentary premix of glassfiber (5) and unsaturated polyester resin composition (2) said core having a lower face and an upper face, a central area and two longitudinal edges, wherein said glassfiber (5) is formed of monofilaments, having a diameter of between 0.1 and 35 microns, that have been isolated and/or separated from standard glassfiber chopped strands and homogeneously and isotropically dispersed within said resin composition (2), said resin composition (2) contains curing agents that are been selected from a group including chemical curing agents and UV curing agents, and said longitudinal edges are straight, smooth, molded, uncut edges.

    摘要翻译: 本发明涉及一种用于连续层压的装置,相应的方法和FRP连续层压板,其包括:包含玻璃纤维(5)和不饱和聚酯树脂组合物(2)的复合长丝预混物的纤维增强塑料(FRP)结构芯 )所述芯具有下表面和上表面,中心区域和两个纵向边缘,其中所述玻璃纤维(5)由直径为0.1至35微米的单丝形成,所述单丝已经被隔离和/或从 所述树脂组合物(2)含有固化剂,所述固化剂选自包括化学固化剂和UV固化剂的组,并且所述纵向边缘是直的,平滑的 ,模制,未切割边缘。