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    RETRO-ALDOL REACTION PRODUCTS AND METHODS OF MAKING AND USING SAME
    52.
    发明公开
    RETRO-ALDOL REACTION PRODUCTS AND METHODS OF MAKING AND USING SAME 审中-公开
    RETRO ALDOL反应产物及其生产和使用方法

    公开(公告)号：EP2964601A4

    公开(公告)日：2016-11-02

    申请号：EP14759581

    申请日：2014-03-07

    申请人： UNIV CENTRAL FLORIDA RES FOUND

    发明人： BLAIR RICHARD GEORGE

    IPC分类号： C07C45/60 ,  B01J23/10 ,  C07C47/19 ,  C07C49/17

    CPC分类号： C07C65/21 ,  B01J23/10 ,  C07C45/60 ,  C07C47/58 ,  C07C51/16 ,  C07C47/19 ,  C07C49/17

    摘要： The presently disclosed and/or claimed inventive concept(s) relates generally to retro-aldol reaction products and methods of making and using same. More particularly, but without limitation, the methods disclosed herein for producing the retro-aldol reaction products are performed in a non-aqueous/solvent-free based process. The reaction products obtained from the process include, for example, dihydroxyacetone, glyceraldehyde, glycolaldehyde, and combinations thereof. In one particular embodiment, the process of making such retro-aldol reaction products includes, without limitation, the step of mechanocatalytically reacting a heterogeneous catalyst with one or more sugar reactants.

    METAL-MATRIX INTEGRATED MEMBRANE CATALYST FOR FISCHER-TROPSCH SYNTHESIS, AND PREPARATION METHOD THEREOF
    54.
    发明公开
    METAL-MATRIX INTEGRATED MEMBRANE CATALYST FOR FISCHER-TROPSCH SYNTHESIS, AND PREPARATION METHOD THEREOF 审中-公开
    在METALLMATRIX INTEGRIERTER膜分离器中FÜRFISCHER-TROPSCH-SYNTHESE UND HERSTELLUNGSVERFAHRENDAFÜR

    公开(公告)号：EP3085442A1

    公开(公告)日：2016-10-26

    申请号：EP14872435.4

    申请日：2014-11-18

    申请人： Wuhan Kaidi Engineering Technology Research Institute Co., Ltd.

    发明人： LI, Changyuan ,  LIU, Qianqian ,  SONG, Dechen ,  YANG, Weiguang ,  ZHAN, Xiaodong ,  JIN, Jiaqi ,  ZHANG, Yanfeng

    IPC分类号： B01J29/03 ,  B01J35/10 ,  B01J23/75 ,  B01J23/02 ,  B01J23/10 ,  B01J23/42 ,  C10G2/00

    CPC分类号： B01J23/894 ,  B01J29/0333 ,  B01J29/70 ,  B01J35/023 ,  B01J35/04 ,  B01J37/0217 ,  B01J37/0225 ,  B01J37/0242 ,  B01J37/0246 ,  B01J37/06 ,  B01J37/343 ,  B01J2229/66 ,  B01J2523/00 ,  C10G2/332 ,  C10G2/333 ,  C10G2/334 ,  B01J2523/3712 ,  B01J2523/828 ,  B01J2523/845

    摘要： Provided are a metal-matrix integrated membrane catalyst for Fischer-Tropsch (F-T) synthesis, and preparation method thereof. The catalyst consists of a metallic integrated matrix, a molecular sieve membrane carrier, an active component Co and other adjuvants. The method comprises: pre-treating the metallic integrated matrix, and conducting in-situ growth of an SBA-16 molecular sieve membrane carrier, the thickness of the molecular sieve membrane carrier being 26-67 µm; and then loading the active component Co and other adjuvants on the molecular sieve membrane carrier via an impregnation method. The method of preparing the metal-matrix integrated membrane catalyst for the F-T synthesis comprises the following steps: pre-treating the metal-matrix; 2) pre-establishing well-chosen seed; 3) placing the pre-treated metallic integrated matrix in the SBA-16 molecular sieve synthesized solution, and conducting in-situ growth of the molecular sieve membrane carrier on the metallic integrated matrix; 4) impregnating, aging and calcinating the active component and adjuvant element; impregnating the metallic integrated matrix having the in-situ grown SBA-16 molecular sieve into the saline solution of the active component Co and other adjuvants, drying, aging, calcinating, and cooling to room temperature. The formed molecular sieve membrane has mechanical pressure resistance, and better firmness.

    摘要翻译： 提供了一种用于费 - 托（F-T）合成的金属基体一体化膜催化剂及其制备方法。 催化剂由金属一体化基质，分子筛膜载体，活性组分Co和其它佐剂组成。 该方法包括：对金属一体化基体进行预处理，并进行SBA-16分子筛膜载体的原位生长，分子筛膜载体的厚度为26-67μm; 然后通过浸渍方法将活性组分Co和其它佐剂装载到分子筛膜载体上。 制备F-T合成金属基体一体膜催化剂的方法包括以下步骤：预处理金属基体; 2）预先选好种子; 3）将预处理的金属一体化基体放入SBA-16分子筛合成溶液中，并在金属一体化基体上进行分子筛膜载体的原位生长; 4）浸渍，老化和煅烧活性成分和佐剂元素; 将具有原位生长的SBA-16分子筛的金属一体化基体浸渍到活性组分Co和其它助剂的盐溶液中，干燥，老化，煅烧并冷却至室温。 形成的分子筛膜具有机械耐压性，更坚固。