公开(公告)号：EP1339073B1

公开(公告)日：2011-09-21

申请号：EP01970208.3

申请日：2001-09-26

申请人： HARIMA CHEMICALS, INC. ,  ULVAC, INC.

发明人： MATSUBA, Yorishige, Tsukuba Research Laboratory ,  MISAWA, Yoshihisa, Tsukuba Research Laboratory ,  GOTO, Hideyuki, Tsukuba Research Laboratory ,  UEDA, Masayuki, Tsukuba Research Laboratory ,  OOSAKO, Katsuhisa, Tsukuba Research Laboratory ,  ODA, Masaaki ,  SAITO, Norimichi ,  SUZUKI, Toshihiro ,  ABE, Noriyuki

IPC分类号： H01B1/22 ,  H01B1/00 ,  H01B13/00 ,  C09J9/02 ,  C09J201/00 ,  B22F1/02

CPC分类号： B22F1/0062 ,  B22F2998/00 ,  C09J9/02 ,  H01B1/22 ,  H05K1/092 ,  Y10T428/29 ,  B22F1/0018

摘要： [purpose] The provision of an electroconductive metal paste of low temperature sintering type for use in printing a high density circuit, which exhibits good adhesion and a smooth surface when applied on a substrate and burned, and thus can be used for forming a fine circuit exhibiting a low resistance. [constitution] An electroconductive metal paste which comprises a resin composition comprising a thermosetting resin component, an organic acid anhydride or a derivative thereof or an organic acid, and one or more organic solvents and, dispersed homogeneously therein, as an electroconductive medium, ultra-fine metal particles having an average particle diameter of 100 nm or less and being surface-coated with one or more compounds having a group capable of forming a coordinate-type bonding with a metal element contained in said ultra-fine metal particle through a lone electron pair of N, O or S, optionally in combination with a metal filler having an average particle diameter of 0.5 to 20 νm. The electroconductive metal paste can undergo low temperature sintering between ultra-fine metal particles contained therein when the paste is subjected to a low temperature heat treatment.

公开(公告)号：EP1339073A1

公开(公告)日：2003-08-27

申请号：EP01970208.3

申请日：2001-09-26

申请人： Harima Chemicals, Inc. ,  Ulvac, Inc.

发明人： MATSUBA, Yorishige, Tsukuba Research Laboratory ,  MISAWA, Yoshihisa, Tsukuba Research Laboratory ,  GOTO, Hideyuki, Tsukuba Research Laboratory ,  UEDA, Masayuki, Tsukuba Research Laboratory ,  OOSAKO, Katsuhisa, Tsukuba Research Laboratory ,  ODA, Masaaki ,  SAITO, Norimichi ,  SUZUKI, Toshihiro ,  ABE, Noriyuki

IPC分类号： H01B1/22 ,  H01B1/00 ,  H01B13/00 ,  C09J9/02 ,  C09J201/00 ,  B22F1/02

CPC分类号： B22F1/0062 ,  B22F2998/00 ,  C09J9/02 ,  H01B1/22 ,  H05K1/092 ,  Y10T428/29 ,  B22F1/0018

摘要： An electroconductive metal paste which comprises a resin composition comprising a thermosetting resin component, an organic acid anhydride or a derivative thereof or an organic acid and one or more organic solvents and, dispersed homogeneously therein, as an electroconductive medium, ultra-fine metal particles having an average particle diameter of 100 nm or less and being surface-coated with one or more compounds having a group capable of forming a coordinate-type bonding with a metal element contained in said ultra-fine metal particle through a lone electron pair of N, O or S, optionally combined with a metal filler having an average particle diameter of 0.5 to 20 µ. The electroconductive metal paste is of a low temperature sintering type, exhibits good adhesion and a smooth surface when applied on a substrate and burned, and thus can be used for forming a fine circuit having a low resistance and for printing a high density circuit.

摘要翻译： 一种导电金属膏，其包含含有热固性树脂组分，有机酸酐或其衍生物或有机酸和一种或多种有机溶剂并且均匀分散在其中作为导电介质的树脂组合物，其具有超细金属颗粒， 平均粒径为100nm以下，表面被一个或多个具有能够通过N电子对形成与所述超细金属颗粒中所含的金属元素形成坐标型键合的化合物进行表面被覆， O或S，任选地与平均粒径为0.5至20μm的金属填料组合。 导电金属膏是低温烧结型的，当涂敷在基材上时表现出良好的粘附性和光滑的表面，并被烧制，因此可用于形成具有低电阻的精细电路和印刷高密度电路。

公开(公告)号：EP1329488B1

公开(公告)日：2006-12-20

申请号：EP01974834.2

申请日：2001-10-12

申请人： ULVAC, INC.

发明人： ABE, Noriyuki ,  ODA, Masaaki

IPC分类号： C09D11/02 ,  H01B1/22 ,  H05K1/09 ,  B41J2/01 ,  B41M5/00 ,  C09D11/00

CPC分类号： C09D11/30 ,  C09D11/322 ,  H01B1/22 ,  H05K1/097 ,  H05K3/102 ,  H05K3/125 ,  H05K2203/013 ,  H05K2203/0783 ,  Y10S977/777 ,  Y10S977/81 ,  Y10T428/2982 ,  Y10T428/2991

摘要： An ink-jet ink with excellent ink properties which comprises a metal dispersion in which ultrafine metal particles having a particle diameter of 100 nm or smaller are evenly dispersed independently. This ink is for use in printing or conductive-circuit formation with an ink-jet printer. The process comprises: a first step in which a metal vapor is contacted with the vapor of a first solvent by the gas vaporization method to obtain a dispersion of ultrafine metal particles; a second step in which a second solvent which is a low-molecular polar solvent is added to the dispersion to sediment the ultrafine metal particles and the first solvent is removed by extraction; and a third step in which a third solvent is added to the sediment to conduct solvent replacement and thereby obtain an ultrafine-metal-particle dispersion. In the first and/or third step, a dispersant is added.

公开(公告)号：EP1696443A1

公开(公告)日：2006-08-30

申请号：EP04807305.0

申请日：2004-12-17

申请人： ULVAC, INC.

发明人： UKISHIMA, Sadayuki c/o ULVAC, Inc. ,  TAKEI, Hideo c/o ULVAC, Inc. ,  ISHIBASHI, Satoru c/o ULVAC, Inc. ,  ATSUKI, Tsutomu ,  ODA, Masaaki ,  YAMAGUCHI, Hiroshi

IPC分类号： H01B13/00 ,  B05D3/02 ,  B05D5/12

CPC分类号： C23C26/00 ,  G02F1/13439 ,  H05K1/092

摘要： To the surface of a base material, there is applied, a dispersion containing fine particles of at least one metal selected from the group consisting of indium, tin, antimony, aluminum and zinc, fine particles of at least one alloy consisting of at least two metals specified above or a mixture of these fine particles, the coated layer is then fired in a vacuum atmosphere, an inert gas atmosphere, a reducing atmosphere; and subsequently the layer is fired in an oxidizing atmosphere. After this firing step in an oxidizing atmosphere, the coated layer may further be fired in a reducing atmosphere. The inert gas atmosphere is one comprising at least one inert gas selected from the group consisting of rare gases, carbon dioxide and nitrogen and the reducing atmosphere is one comprising at least one reducing gas selected from the group consisting of hydrogen, carbon monoxide and lower alcohols. A transparent electrode is composed of a transparent conductive film prepared according to the foregoing method. The present invention thus permits the formation of a transparent conductive film having a low resistance and a high transmittance while making use of a low temperature firing step.

摘要翻译： 到基材的表面上，被施加的分散体包含选自下组的铟，锡，锑，铝和锌的至少一种的合金的细颗粒由至少两个中选择的至少一种金属的微粒子 以上或微粒论文的混合物指定金属，涂布的层在真空气氛中，以惰性气体气氛，还原性气氛中进行烧成; 并且随后层在氧化性气氛中烧制。 到氧化气氛该烧成工序后，涂布层可以进一步在还原性气氛中进行烧成。 的惰性气体气氛是包含选自稀有气体，二氧化碳和氮气中的至少一种惰性气体和还原性气氛是包含选自氢气，一氧化碳和低级醇中的至少一种还原性气体 ， 透明电极由透明导电膜制备的雅定于上述方法的。 因此，本发明允许的透明导电膜具有 - 低电阻的形成，并同时利用低温烧成工序的高透射率。

公开(公告)号：EP1329488A1

公开(公告)日：2003-07-23

申请号：EP01974834.2

申请日：2001-10-12

申请人： ULVAC, INC.

发明人： ABE, Noriyuki ,  ODA, Masaaki

IPC分类号： C09D11/02 ,  H01B1/22 ,  H05K1/09 ,  B41J2/01 ,  B41M5/00

CPC分类号： C09D11/30 ,  C09D11/322 ,  H01B1/22 ,  H05K1/097 ,  H05K3/102 ,  H05K3/125 ,  H05K2203/013 ,  H05K2203/0783 ,  Y10S977/777 ,  Y10S977/81 ,  Y10T428/2982 ,  Y10T428/2991

摘要： The present invention relates to ink jet printing ink consisting of an independently dispersed metal ultrafine particles-containing liquid dispersion in which the metal ultrafine particles having a particle size of not more than 100 nm are independently and uniformly dispersed and which is excellent in characteristic properties required for ink. The ink is used in the printing or the formation of conductive circuits using an ink jet printer. The ink can be prepared by steps comprising the first step in which metal vapor is brought into contact with vapor of the first solvent according to the evaporation-in-gas technique to thus form a metal ultrafine particles-containing liquid dispersion; the second step in which a low molecular weight polar solvent as the second solvent is added to the liquid dispersion to thus precipitate the metal ultrafine particles and to extract and remove the first solvent; and the third step in which the third solvent is added to the resulting precipitates to carry out solvent-substitution and to thus give a liquid dispersion containing metal ultrafine particles independently and uniformly dispersed therein, a dispersant being added in the first step and/or the third step.

公开(公告)号：EP1696443B1

公开(公告)日：2013-07-03

申请号：EP04807305.0

申请日：2004-12-17

申请人： ULVAC, INC.

发明人： UKISHIMA, Sadayuki c/o ULVAC, Inc. ,  TAKEI, Hideo c/o ULVAC, Inc. ,  ISHIBASHI, Satoru c/o ULVAC, Inc. ,  ATSUKI, Tsutomu ,  ODA, Masaaki ,  YAMAGUCHI, Hiroshi

IPC分类号： H01B13/00 ,  B05D3/02 ,  B05D5/12 ,  C09D5/24

CPC分类号： C23C26/00 ,  G02F1/13439 ,  H05K1/092

公开(公告)号：EP1840244B1

公开(公告)日：2012-09-26

申请号：EP05816844.4

申请日：2005-12-15

申请人： ULVAC, INC. ,  Jemco Inc.

发明人： ATSUKI, Tsutomu ,  TEI, Kyuukou ,  ODA, Masaaki

IPC分类号： C23C24/08 ,  B22F9/12 ,  B22F9/24 ,  H01B5/14 ,  H01B13/00 ,  C23C26/00

CPC分类号： H05K1/097 ,  B22F2998/00 ,  C23C24/08 ,  C23C26/00 ,  H05K3/1291 ,  H05K2203/1126 ,  H05K2203/122 ,  B22F1/0022 ,  B22F1/0062

公开(公告)号：EP1340568B1

公开(公告)日：2009-09-16

申请号：EP01974833.4

申请日：2001-10-12

申请人： ULVAC, INC.

发明人： SUZUKI, Toshihiro ,  ODA, Masaaki

IPC分类号： B22F9/00 ,  B22F9/12 ,  B22F9/30 ,  B22F1/02 ,  B01F17/16 ,  B01F17/22 ,  B01F17/28

CPC分类号： B22F9/30 ,  B22F1/0018 ,  B22F9/12 ,  B22F9/24 ,  B22F2998/00 ,  B82Y30/00 ,  C09D17/006 ,  B22F1/0022

摘要： A dispersion of ultrafine metal particles which, even in a high concentration, retains flowability and is free from particle aggregation and which can be concentrated. The dispersion is usable for forming a multilayered wiring in IC boards, etc. and an internal wiring in semiconductors. The dispersion contains a dispersant which comprises: an alkylamine in which the main chain has 4 or 20 carbon atoms and which is a primary amine; and at least one compound selected among carboxamides and aminocarboxylic acid salts. Due to the dispersant, the ultrafine metal particles having a particle diameter of 100 nm or smaller are dispersed independently. This dispersion, in which the ultrafine metal particles having a given particle diameter are dispersed independently, is obtained by contacting a metal vapor with a vapor of an organic solvent, collecting the vapors through cooling, adding the dispersant to the liquid obtained, and then optionally conducting solvent replacement. Alternatively, the dispersion is obtained by contacting a metal vapor with a mixture of a vapor of an organic solvent and a vapor of the dispersant, collecting the vapors through cooling, and then optionally conducting solvent replacement.

公开(公告)号：EP1840244A1

公开(公告)日：2007-10-03

申请号：EP05816844.4

申请日：2005-12-15

申请人： ULVAC, INC. ,  Jemco Inc.

发明人： ATSUKI, Tsutomu ,  TEI, Kyuukou ,  ODA, Masaaki

IPC分类号： C23C24/08 ,  B22F9/12 ,  B22F9/24 ,  H01B5/14 ,  H01B13/00

CPC分类号： H05K1/097 ,  B22F2998/00 ,  C23C24/08 ,  C23C26/00 ,  H05K3/1291 ,  H05K2203/1126 ,  H05K2203/122 ,  B22F1/0022 ,  B22F1/0062

摘要： A metal thin film-forming method which comprises the step of firing metal nanoparticles each comprising a particle consisting of at least one metal selected from Ag, Au, Ni, Pd, Rh, Ru, and Pt or an alloy comprising at least two of these metals and an organic substance adhered to the periphery thereof as a dispersant, under a gas atmosphere containing water and/or an organic acid to thus form a metal thin film. This metal thin film possesses a low resistance value.

摘要翻译： 一种金属薄膜形成方法，其包括烧制金属纳米颗粒的步骤，每个金属纳米颗粒包含由至少一种选自Ag，Au，Ni，Pd，Rh，Ru和Pt的金属组成的颗粒或包含这些中的至少两种的合金 金属和作为分散剂附着在其周围的有机物质，在含有水和/或有机酸的气体气氛下，从而形成金属薄膜。 该金属薄膜具有低电阻值。

公开(公告)号：EP1340568A1

公开(公告)日：2003-09-03

申请号：EP01974833.4

申请日：2001-10-12

申请人： ULVAC, INC.

发明人： SUZUKI, Toshihiro ,  ODA, Masaaki

IPC分类号： B22F9/00 ,  B22F9/12 ,  B22F9/30 ,  B22F1/02 ,  B01F17/16 ,  B01F17/22 ,  B01F17/28

CPC分类号： B22F9/30 ,  B22F1/0018 ,  B22F9/12 ,  B22F9/24 ,  B22F2998/00 ,  B82Y30/00 ,  C09D17/006 ,  B22F1/0022

摘要： The present invention relates to a liquid dispersion of metal ultrafine particles, which can maintain a desired flow ability even at a high concentration, which is free of any aggregation between fine particles and which can be concentrated. This liquid dispersion is used in, for instance, multilayer distributing wires of, for instance, IC substrates and internal distributing wires of semiconductor devices. If using, as a dispersant, at least one member selected from the group consisting of alkylamines, which are primary amines and whose main chain contains 4 to 20 carbon atoms, carboxylic acid amides and amino-carboxylic acid salts, metal ultrafine particles having a particle size of not more than 100 nm are individually or separately dispersed in the resulting liquid dispersion. The liquid dispersion of metal ultrafine particles in which the metal ultrafine particles having a desired particle size are individually or separately dispersed can be prepared by bringing metal vapor into contact with organic solvent vapor, adding a dispersant to a liquid collected after cooling the vapor mixture, subsequently optionally subjecting the liquid to a solvent-substitution step; or by bringing metal vapor into contact with mixed vapor of an organic solvent and a dispersant, cooling the vapor mixture to collect a liquid product and then, if desired, subjecting the liquid to a solvent-substitution step.