PROCESS FOR THE PRODUCTION OF LIVING RADICAL POLYMERS AND POLYMERS
    2.
    发明公开
    PROCESS FOR THE PRODUCTION OF LIVING RADICAL POLYMERS AND POLYMERS 有权
    VERFAHREN ZUR HERSTELLUNG VON LEBENDEN RADIKALISCHEN POLYMEREN UND POLYMERE

    公开(公告)号:EP1595894A4

    公开(公告)日:2007-05-30

    申请号:EP04711754

    申请日:2004-02-17

    CPC分类号: C07C395/00 C08F4/04 C08F4/42

    摘要: A process for the production of living radical polymers, characterized by polymerizing a vinyl monomer by the use of an organotellurium compound represented by the general formula (1) and an azo polymerization initiator; and living radical polymers produced by the process: (1) wherein R1 is C1-8 alkyl, aryl, substituted aryl, or an aromatic heterocyclic group; R2 and R3 are each hydrogen or C1-8 alkyl; and R4 is aryl, substituted aryl, an aromatic heterocyclic group, acyl, oxycarbonyl, or cyano.

    摘要翻译: 一种生产活性自由基聚合物的方法,其特征在于使用由通式(1)表示的有机碲化合物和偶氮聚合引发剂使乙烯基单体聚合; (1)其中R1为C1-8烷基,芳基,取代的芳基或芳族杂环基; R2和R3各自为氢或C1-8烷基; 并且R 4是芳基,取代的芳基,芳族杂环基,酰基,氧羰基或氰基。

    PROCESS FOR THE PRODUCTION OF LIVING RADICAL POLYMERS AND POLYMERS
    4.
    发明公开
    PROCESS FOR THE PRODUCTION OF LIVING RADICAL POLYMERS AND POLYMERS 有权
    VERFAHREN ZUR HERSTELLUNG VON LEBENDEN RADIKALISCHEN POLYMEREN

    公开(公告)号:EP1595894A1

    公开(公告)日:2005-11-16

    申请号:EP04711754.4

    申请日:2004-02-17

    IPC分类号: C08F4/00

    CPC分类号: C07C395/00 C08F4/04 C08F4/42

    摘要: A process for producing a living radical polymer characterized in that a vinyl monomer is polymerized with use of an organotellurium compound represented by the formula (1) and an azo type polymerization initiator, and the living radical polymer obtainable by the process
    wherein R 1 is C 1 -C 8 alkyl, aryl, substituted aryl or an aromatic heterocyclic group, R 2 and R 3 are each a hydrogen atom or C 1 -C 8 alkyl, and R 4 is aryl, substituted aryl, an aromatic heterocyclic group, acyl, oxycarbonyl or cyano.

    摘要翻译: 一种活性自由基聚合物的制造方法,其特征在于,使用由式(1)表示的有机碲化合物和偶氮型聚合引发剂来聚合乙烯基单体,和通过方法