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1.发明公开METAL OXIDE-STABILIZED ZIRCONIUM OXIDE CERAMIC MATERIALS 审中-公开METALLOXIDSTABILISIERTE ZIRKONOXID-KERAMIKMATERIALIEN
公开(公告)号：EP3137434A1
公开(公告)日：2017-03-08
申请号：EP15720888.5
申请日：2015-04-27
申请人： Clariant Corporation
发明人： SHEN, Wenqin , PETZOLD, Franz , LIBBY, Karen , TURBEVILLE, Wayne , PURCELL, Matthew , BORN, Marc
IPC分类号： C04B35/486 , B01J37/03 , B01J37/08 , B01J21/06 , B01J23/70 , B01J23/72 , B01J23/74 , B01J23/745 , B01J23/75 , B01J23/755 , B01J35/00 , B01J35/02 , B01J35/10 , C01G25/02 , C04B35/488 , C07C29/149 , C12P19/02
CPC分类号： C07C29/132 , B01J21/066 , B01J23/06 , B01J23/40 , B01J23/44 , B01J23/48 , B01J23/72 , B01J23/74 , B01J23/745 , B01J23/75 , B01J23/755 , B01J23/83 , B01J23/8435 , B01J23/892 , B01J35/0006 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J37/0009 , B01J37/0215 , B01J37/0236 , B01J37/031 , B01J37/04 , B01J37/06 , B01J37/08 , B01J37/088 , B01J37/18 , B01J2523/00 , C01G3/02 , C01G25/00 , C01G25/02 , C01G51/04 , C01G53/04 , C01P2002/54 , C01P2002/72 , C01P2006/12 , C01P2006/14 , C01P2006/21 , C04B35/486 , C04B35/488 , C04B2235/3206 , C04B2235/3208 , C04B2235/3225 , C04B2235/3227 , C04B2235/3229 , C04B2235/3232 , C04B2235/3251 , C04B2235/3258 , C04B2235/3262 , C04B2235/327 , C04B2235/3272 , C04B2235/3275 , C04B2235/3277 , C04B2235/3279 , C04B2235/3281 , C04B2235/3284 , C04B2235/3293 , C04B2235/3294 , C04B2235/3409 , C04B2235/6021 , C04B2235/72 , C04B2235/721 , C04B2235/765 , C07C29/00 , C07C29/141 , C07C29/60 , Y02P20/52 , C07C31/205 , C07C31/18 , C07C31/202 , C07C31/225 , B01J2523/3706 , B01J2523/48 , B01J2523/847
摘要： The present disclosure relates generally to ceramic materials suitable for use as catalyst support materials, catalysts using such materials and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is a ceramic material including zirconium oxide and one or more metal oxides selected from nickel oxide, copper oxide, cobalt oxide, iron oxide and zinc oxide, the ceramic material being at least about 50 wt. % zirconium oxide. In certain embodiments, the ceramic material is substantially free of any binder or additional stabilizing agent.
摘要翻译： 本公开一般涉及适合用作催化剂载体材料的陶瓷材料，使用这种材料的催化剂及其使用方法，例如将糖，糖醇，甘油和生物可再生有机酸转化为商业上有价值的化学品的方法，以及 中间体。 本发明的一个方面是包括氧化锆和一种或多种选自氧化镍，氧化铜，氧化钴，氧化铁和氧化锌的金属氧化物的陶瓷材料，所述陶瓷材料为至少约50wt。 ％的氧化锆。 在某些实施方案中，陶瓷材料基本上不含任何粘合剂或另外的稳定剂。
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公开(公告)号：EP3595809A1
公开(公告)日：2020-01-22
申请号：EP18714404.3
申请日：2018-03-09
申请人： Clariant Corporation
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公开(公告)号：EP2403818B1
公开(公告)日：2020-07-15
申请号：EP10749051.8
申请日：2010-03-03
申请人： Clariant Corporation
IPC分类号： C07C29/132 , C07C31/18 , C07C31/20 , C07C31/02 , C07C29/128
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公开(公告)号：EP2877282A1
公开(公告)日：2015-06-03
申请号：EP13745294.2
申请日：2013-07-24
申请人： Clariant Corporation
发明人： SHEN, Wenqin , LUI, Aiguo , TURBEVILLE, Wayne
IPC分类号： B01J35/00 , B01J21/06 , B01J23/28 , B01J23/14 , B01J23/42 , B01J23/44 , B01J23/46 , B01J23/36 , B01J23/72 , B01J23/75 , B01J23/755 , B01J23/847 , B01J23/882 , B01J23/883 , B01J23/888
CPC分类号： B01J35/002 , B01J21/066 , B01J23/14 , B01J23/28 , B01J23/36 , B01J23/42 , B01J23/44 , B01J23/462 , B01J23/464 , B01J23/466 , B01J23/468 , B01J23/63 , B01J23/6482 , B01J23/6484 , B01J23/6486 , B01J23/6525 , B01J23/6527 , B01J23/6562 , B01J23/6567 , B01J23/72 , B01J23/75 , B01J23/755 , B01J23/83 , B01J23/8472 , B01J23/8474 , B01J23/8476 , B01J23/882 , B01J23/883 , B01J23/888 , B01J23/8892 , B01J23/8896 , B01J37/0009 , B01J37/0207 , B01J37/0242 , C10G3/47 , C10G3/48 , C10G3/52 , C10G2300/1011 , C10G2300/1014 , C10G2300/1018 , C10L1/04 , Y02P30/20
摘要： A hydrodeoxygenation catalyst comprises a metal catalyst, an acid promoter, and a support. The metal catalyst is selected from platinum, palladium, ruthenium, rhenium rhodium, osmium, iridium, nickel, cobalt, molybdenum, copper, tin, or mixtures thereof. The support is a promoted-zirconium material including texture promoters and acid promoters. The hydrodeoxygenation catalyst may be used for hydrodeoxygenation (HDO) of sugar or sugar alcohol in an aqueous solution. In one embodiment the HDO catalyst may be used for HDO of fatty acids such as fatty acid methyl esters (FAME), triglycerols (in plant oil and animal fat), pyrolysis oil, or lignin. The hydrodeoxygenation catalyst for fatty acid process does not require the use of an acid promoter, it is optional
摘要翻译： 加氢脱氧催化剂包含金属催化剂，酸促进剂和载体。 金属催化剂选自铂，钯，钌，铼铑，锇，铱，镍，钴，钼，铜，锡或其混合物。 该载体是一种促进剂 - 锆材料，包括质构促进剂和酸促进剂。 加氢脱氧催化剂可用于水溶液中糖或糖醇的加氢脱氧（HDO）。 在一个实施方案中，HDO催化剂可以用于脂肪酸如脂肪酸甲酯（FAME），甘油三酯（在植物油和动物脂肪中），热解油或木质素的HDO。 用于脂肪酸加工的加氢脱氧催化剂不需要使用酸促进剂，它是任选的
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公开(公告)号：EP2790808A1
公开(公告)日：2014-10-22
申请号：EP12799477.0
申请日：2012-12-04
申请人： Clariant Corporation
CPC分类号： B01D53/02 , B01D53/64 , B01D2253/102 , B01D2253/1128 , B01D2257/602 , B01J20/0237 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J20/20 , B01J20/2803 , B01J20/28042 , C10G2300/205 , C10K1/004 , C10K1/32
摘要： A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H
2 S), carbonyl sulfide (COS), salts of sulfide (S
2 -), salts of hydrosulfide (HS
- ), and salts of polysulfide (S
n
2- ). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia.-
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公开(公告)号：EP3024572A1
公开(公告)日：2016-06-01
申请号：EP14739306.0
申请日：2014-06-17
申请人： Clariant Corporation
IPC分类号： B01J21/06 , B01J35/10 , B01J35/00 , B01J37/03 , B01J37/08 , B01J23/34 , B01J23/889 , B01J23/755 , B01J23/843 , B01J23/46 , B01J23/72 , C12P19/02 , C07C29/149
CPC分类号： B01J23/8892 , B01J21/066 , B01J23/34 , B01J23/462 , B01J23/6562 , B01J23/72 , B01J23/755 , B01J23/8435 , B01J35/002 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J37/031 , B01J37/08 , C07C29/00 , C07C29/132 , C07C29/149 , C07C29/172 , C07C29/60 , C12P19/02 , Y02P20/52 , C07C31/202 , C07C31/205 , C07C31/225 , C07C31/26
摘要： The present disclosure relates generally to catalyst support materials, catalysts and methods for using them, such as methods for converting sugars, sugar alcohols, glycerol, and bio-renewable organic acids to commercially-valuable chemicals and intermediates. One aspect of the invention is catalyst support material including ZrO
2 and one or more oxides of manganese (MnO
x ), the catalyst support material being at least about 50 wt% ZrO
2 and MnO
x . In certain embodiments, the weight ratio of ZrO
2 to MnO
x is within the range of about 1:1 to about 30:1; and/or the catalyst support material is substantially free of any binder, extrusion aid or additional stabilizing agent摘要翻译： 本公开一般涉及催化剂载体材料，催化剂和使用它们的方法，例如将糖，糖醇，甘油和生物可再生有机酸转化为商业上有价值的化学品和中间体的方法。 本发明的一个方面是包含ZrO 2和一种或多种锰的氧化物（MnO x）的催化剂载体材料，所述催化剂载体材料为至少约50重量％的ZrO 2和MnO x。 在某些实施方案中，ZrO 2与MnO x的重量比在约1：1至约30：1的范围内; 和/或催化剂载体材料基本上不含任何粘合剂，挤出助剂或另外的稳定剂
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公开(公告)号：EP2961525A1
公开(公告)日：2016-01-06
申请号：EP14709007.0
申请日：2014-02-13
申请人： Clariant Corporation
发明人： MILLER, Aaron , RAGHUNATH, Malati , SOKOLOVSKII, Valery , LUGMAIR, Claus , VOLPE, Anthony , SHEN, Wenqin , TURBEVILLE, Wayne
IPC分类号： B01J21/06 , B01J23/843 , B01J23/89 , B01J23/835 , B01J23/83 , B01J23/889 , B01J21/18 , B01J37/02
CPC分类号： B01J23/8993 , B01J21/066 , B01J21/18 , B01J21/185 , B01J23/755 , B01J23/83 , B01J23/835 , B01J23/8435 , B01J23/8437 , B01J23/866 , B01J23/868 , B01J23/8892 , B01J23/8926 , B01J35/023 , B01J37/0201 , B01J37/18 , B82Y30/00 , C07C29/00 , C07C29/60 , Y02P20/52 , C07C31/202 , C07C31/205
摘要： Ethylene glycol and propylene glycol may be made by hydrogenolysis of a polyol comprising the steps of reacting a polyol with hydrogen in the presence of a hydrogenolysis catalyst. The hydrogenolysis comprises nickel, one or more promoter, and one or more support. The promoter is selected from bismuth, silver, tin, antimony, gold, lead, thallium, cerium, lanthanum, and manganese. The support is selected from zirconia and carbon. A zirconia support comprises a zirconia textual promoter, which is selected from Cr, Mo, W, Nb, Ce, Ca, Mg, La, Pr, Nd, Al, and P. If the support comprises carbon, then the promoter is selected from bismuth and antimony. In another embodiment, if the support comprises carbon, then both the promoter is selected from bismuth and antimony, and the catalyst comprises copper. In another embodiment, the catalyst additionally comprises copper.
摘要翻译： 乙二醇和丙二醇可以通过多元醇的氢解来制备，包括在氢解催化剂存在下使多元醇与氢反应的步骤。 氢解包括镍，一种或多种促进剂和一种或多种载体。 促进剂选自铋，银，锡，锑，金，铅，铊，铈，镧和锰。 载体选自氧化锆和碳。 氧化锆载体包含选自Cr，Mo，W，Nb，Ce，Ca，Mg，La，Pr，Nd，Al和P的氧化锆文本促进剂。如果载体包含碳，则促进剂选自 铋和锑。 在另一个实施方案中，如果载体包含碳，则促进剂均选自铋和锑，并且催化剂包含铜。 在另一个实施方案中，催化剂另外包含铜。
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公开(公告)号：EP2790809A1
公开(公告)日：2014-10-22
申请号：EP12799480.4
申请日：2012-12-04
申请人： Clariant Corporation
CPC分类号： B01D53/02 , B01D53/64 , B01D2253/102 , B01D2253/1128 , B01D2257/602 , B01J20/0237 , B01J20/0285 , B01J20/08 , B01J20/106 , B01J20/20 , B01J20/2803 , B01J20/28042 , C10G2300/205 , C10K1/004 , C10K1/32
摘要： A process for removing mercury from a gas or liquid phase, wherein the gas or liquid phase containing mercury is placed in contact with a composition comprising a precipitated metal sulfide. The precipitated metal sulfide may be made by the process of combining a metal source, sulfide source, and modifier to form the precipitated metal sulfide. The metal source may comprise iron, cobalt, nickel, copper, zinc, zirconium, molybdenum, silver, or gold salts. The metal salt may be selected from metal nitrate, metal sulfate, metal phosphate, metal acetate, metal carbonate, metal hydroxide, metal ammonium carbonate, and metal hydroxycarbonate. The sulfide source is selected from hydrogen sulfide (H2S), carbonyl sulfide (COS), salts of sulfide (S2−), salts of hydrosulfide (HS−), and salts of polysulfide (Sn2−). The modifier may be selected from alumina, silica, aluminosilicate, clay, zeolites, carbon, cement, titania, zirconia.
摘要翻译： 一种从气相或液相中除去汞的方法，其中使含有汞的气相或液相与包含沉淀的金属硫化物的组合物接触。 沉淀的金属硫化物可以通过将金属源，硫化物源和改性剂结合以形成沉淀的金属硫化物的过程来制备。 金属源可以包括铁，钴，镍，铜，锌，锆，钼，银或金盐。 金属盐可以选自金属硝酸盐，金属硫酸盐，金属磷酸盐，金属乙酸盐，金属碳酸盐，金属氢氧化物，金属碳酸铵和金属羟基碳酸盐。 硫化物源选自硫化氢（H 2S），硫化羰（COS），硫化物（S 2-）的盐，硫氢化物（HS - ）的盐和多硫化物（Sn 2-）的盐。 改性剂可以选自氧化铝，二氧化硅，硅铝酸盐，粘土，沸石，碳，水泥，二氧化钛，氧化锆。
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公开(公告)号：EP2758166A1
公开(公告)日：2014-07-30
申请号：EP12756319.5
申请日：2012-08-29
申请人： Clariant Corporation
发明人： TURBEVILLE, Wayne , KORYNTA, Greg
IPC分类号： B01J21/08 , B01J23/20 , B01J27/18 , B01J27/182 , B01J35/00 , B01J37/00 , B01J37/03 , B01J37/08
CPC分类号： B01J21/08 , B01J23/20 , B01J27/18 , B01J27/182 , B01J35/0013 , B01J37/0018 , B01J37/038 , B01J37/08 , B01J2523/00 , B01J2523/41 , B01J2523/51 , B01J2523/56
摘要： The present invention relates to solid phosphoric acid (SPA) catalysts, processes for making the catalysts, and processes for conversion of hydrocarbons using the catalysts, such as oligomerization of propylene. In an exemplary embodiment, the catalyst comprises a calcined extrudate of phosphoric acid, diatomaceous earth, and niobic acid. Methods for converting hydrocarbons to olefins comprise contacting a hydrocarbon feedstock with the catalyst at hydrocarbon conversion conditions.
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