摘要:
The invention relates to a catalytically active composition containing Pd and Bi as active constituents, and at least one element selected from the group (a) consisting of Rh, Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Na, Cs and Ba; or Pd, Rh and Bi, and optionally an element selected from the group (a') consisting of Au, Sb, V, Cr, W, Mn, Fe, Co, Ni, Pt, Cu, Ag, Na, Cs, Mg, Ca and Ba. The invention also relates to a method for dehydrating hydrocarbons, preferably oxofunctionalised hydrocarbons such as cyclopentanone, cyclohexanone and isovaleraldehyde, by means of the catalytically active composition.
摘要:
The present invention provides a method for preparing dimer of a monohydroxy aromatic compound. In the method of the present invention, oxidative coupling reaction of a monohydroxy aromatic compound represented by formula [I]:
Ar-OH [I]
wherein Ar represents an optionally substituted aromatic group is carried out in a nitrogen containing polar solvent in the presence of a copper salt. By the method of the instant invention, dimer of the monohydroxy aromatic compound can be obtained in high yield.
摘要:
A process for formaldehyde production is disclosed comprising the steps of reacting methanol with formaldehyde to form methylal and then oxidizing the resulting methylal to obtain formaldehyde. Formaldehyde derivatives may also be produced. A dilute formaldehyde solution resulting from recovery of the product is recycled and used as feed material for the initial reaction step.
摘要:
A catalyst used for producing, by catalytic gas phase oxidation of a C 3 -C 5 olefin or tertiary alcohol, the corresponding unsaturated aldehyde and unsaturated carboxylic acid, said catalyst characterized by comprising molybdenum, iron and bismuth and having a specific surface area in the range from 1 to 20m 2 /gr, a pore volume in the range from 0.1 to 1.0 cc/gr and a pore diameter distribution in which the pore diameters are collectively distributed in the range of each of from 1 to 10 microns and from 0.1 to 1 (exclusive) micron; and a process for preparing said catalyst by charging an unfired material powder into a centrifugal flow coating device to form particles having the average particle diameter of 2 to 10mm and then firing the particles.
摘要:
Hexafluoropropylene may be conventionally oxidized to form an impure mixture comprising hexafluoroacetone and residual hexafluoropropylene, which materials are separable only with difficulty. The impure mixture may be subjected to reducing conditions to hydrogenate the hexafluoroacetone to a hexafluoroisopropanol product, which product is easily separable from the hexafluoropropylene impurity, which impurity may be recycled for further oxygenation and production of the acetone. Alternatively, hexafluoroisopropanol may be conventionally made from hexachloroacetone to form an impure mixture of hexafluoroacetone and HF. When this impure mixture is hydrogenated, the resulting hexafluoroisopropanol, mixed with hydrogen fluoride, is formed. Either of these alcohol products may be reacted with hydrogen fluoride and a formaldehyde to obtain a fluoromethyl-1,1,1,-3,3,3-hexafluoroisopropyl ether, which is a useful anesthetic.