Copper complex
    5.
    发明专利
    Copper complex 有权
    铜复合材料

    公开(公告)号:JP2012232977A

    公开(公告)日:2012-11-29

    申请号:JP2012095728

    申请日:2012-04-19

    Abstract: PROBLEM TO BE SOLVED: To provide a copper complex more excellent in durability of luminous intensity than that of the conventional copper complex.SOLUTION: The copper complex represented by a compositional formula (1): (Cu)(L)(L)(L)(X)is provided. In the formula (1), Lis a molecule which has three or four atoms selected from phosphorus atom and nitrogen atom in a nitrogen atom-containing 5-membered ring which may have a substituent as neutral atoms capable of being coordinated with the same Cu+, at least two atoms of the neutral atoms capable of being coordinated with the same Cuin Lare phosphorus atoms and at least one selected from a group consisting of the phosphorus atoms does not have spcarbon atoms bonded thereto, Land Lindependently represent a molecule which has an atom or an ion capable of being coordinated with Cu, selected from phosphorus atom, nitrogen atom, oxygen atom, sulfur atom, arsenic atom, oxygen anion and sulfur anion, Xrepresents an anion, (a) represents a number greater than 0.5, and (b), (c) and (d) independently represent a number of 0 or more.

    Abstract translation: 要解决的问题:提供比常规铜络合物更加优异的发光强度的铜络合物。 < P>解决方案:由组成式(1)表示的铜络合物:(Cu + )(L 1 ) SB POS =“POST”> a (L 2 b (L 3 c (X 1 d 提供。 在式(1)中,L 1 是在含氮原子的5元环中具有选自磷原子和氮原子的三个或四个原子的分子,其可以具有 作为能够与相同Cu +配位的中性原子的取代基,能够与L + 配位的中性原子的至少两个原子, POST“> 1 是磷原子,并且从磷原子组成的组中选择的至少一个不具有键合到其上的sp 3 个碳原子,L 2 和L 3 独立地表示具有能与Cu配位的原子或离子的分子。 +选自磷原子,氮原子,氧原子,硫原子,砷原子,氧阴离子和硫阴离子,X 1 表示阴离子,(a) 表示大于0.5的数,并且(b),(c)和(d)独立地表示0或数 更多。 版权所有(C)2013,JPO&INPIT

    Film containing silver complex
    10.
    发明专利
    Film containing silver complex 有权
    镀膜复合物

    公开(公告)号:JP2012012584A

    公开(公告)日:2012-01-19

    申请号:JP2011120141

    申请日:2011-05-30

    Abstract: PROBLEM TO BE SOLVED: To provide a film using a complex which is cheaper than complexes of platinum group metals, and is excellent in durability in the presence of oxygen as a light emission material.SOLUTION: The film contains a silver complex represented by the composition formula (1): (Ag)(L)(L)(L)(X)(wherein Lis a molecule having ≥3 and ≤6 of the total number of one or more phosphorus atoms, and one or more selected from a nitrogen atom, an oxygen atom, a sulfur atom, an arsenic atom, an oxygen anion and a sulfur anion; Lis a molecule having two of the total number of atoms and ions selected from the atoms and ions described above; Lis a molecule having one atom or ion described above; Xis an anion; and a is a number larger than 0.5, and b, c and d are each independently a number equal to or larger than 0). A light emission device uses the film.

    Abstract translation: 要解决的问题:提供使用比铂族金属络合物便宜的复合物的膜,并且在作为发光材料的氧的存在下的耐久性优异。

    解决方案:该膜含有由组成式(1)表示的银络合物:(Ag + )(L 1 a (L 2 b (L 3 c (X 1 d < SB>(其中L 1 是一个或多个磷原子总数≥3且≤6的分子,并且选自氮原子,氧 原子,硫原子,砷原子,氧阴离子和硫阴离子; L 2 是一个分子,其具有从原子中选出的总原子数和离子数的两个, 离子; L 3 是具有上述一个原子或离子的分子; X 1 是阴离子; a是 大于0.5的数,b,c和d各自独立地为等于或大于0的数)。 发光装置使用该膜。 版权所有(C)2012,JPO&INPIT

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