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    Method for producing vinyl acetate monomer from ethane or ethylene oxidation
    2.
    发明授权
    Method for producing vinyl acetate monomer from ethane or ethylene oxidation 有权
    从乙烷或乙烯氧化制备乙酸乙烯酯单体的方法

    公开(公告)号：US06605739B1

    公开(公告)日：2003-08-12

    申请号：US10031808

    申请日：2001-11-13

    申请人： Khalid Karim ,  Alaa E. M. Adris

    发明人： Khalid Karim ,  Alaa E. M. Adris

    IPC分类号： C07C6915

    CPC分类号： C07C67/05 ,  C07C67/055 ,  Y02P20/582 ,  C07C69/01 ,  C07C69/15

    摘要： Methods for the catalytic production of vinyl acetate monomer from ethane, ethylene or an ethanelethylene mixture using a first catalyst containing MoVNbPd, MoVLaPdbX (where X is Al, Ga, Ge or Si) or MoVNbX (where X is P, B, Hf, Te, As or mixtures thereof) in the first step of oxidation and using a conventional VAM catalyst for the second step. The method produces high yields to acetic acid and vinyl acetate without the coproduction of carbon monoxide. Furthermore, the ethylene and acetic acid produced in the first step may be utilized in the second step for VAM production.

    摘要翻译： 使用含有MoVNbPd，MoVLaPdbX（其中X为Al，Ga，Ge或Si）或MoVNbX（其中X为P，B，Hf，Te）的第一催化剂从乙烷，乙烯或乙烷乙烯混合物催化制备乙酸乙烯酯单体的方法 ，As或其混合物），并且使用用于第二步骤的常规VAM催化剂。 该方法对乙酸和乙酸乙烯酯产生高产率而不产生一氧化碳。 此外，第一步中生产的乙烯和乙酸可用于VAM生产的第二步。

    Method for producing vinyl acetate monomer from ethane or ethylene oxidation
    5.
    发明授权
    Method for producing vinyl acetate monomer from ethane or ethylene oxidation 有权
    从乙烷或乙烯氧化制备乙酸乙烯酯单体的方法

    公开(公告)号：US6143921A

    公开(公告)日：2000-11-07

    申请号：US312683

    申请日：1999-05-14

    申请人： Khalid Karim ,  Alaa E. M. Adris

    发明人： Khalid Karim ,  Alaa E. M. Adris

    IPC分类号： B01J23/68 ,  B01J37/04 ,  C07B61/00 ,  C07C67/05 ,  C07C67/055 ,  C07C69/15 ,  C07C51/16

    CPC分类号： C07C67/05 ,  C07C67/055 ,  Y02P20/582

    摘要： Methods for the catalytic production of vinyl acetate monomer from ethane, ethylene or an ethane/ethylene mixture using a first catalyst containing MoVNbPd, MoVLaPdNbX (where X is Al, Ga, Ge or Si) or MoVNbX (where X is P, B, Hf, Te, As or mixtures thereof) in the first step of oxidation and using a conventional VAM catalyst for the second step. The method produces high yields to acetic acid and vinyl acetate without the coproduction of carbon monoxide. Further-more, the ethylene and acetic acid produced in the first step may be utilized in the second step for VAM production

    摘要翻译： 使用含有MoVNbPd，MoVLaPdNbX（其中X为Al，Ga，Ge或Si）或MoVNbX（其中X为P，B，Hf）的第一催化剂从乙烷，乙烯或乙烷/乙烯混合物催化制备乙酸乙烯酯单体的方法 ，Te，As或其混合物），并且使用用于第二步骤的常规VAM催化剂。 该方法对乙酸和乙酸乙烯酯产生高产率而不产生一氧化碳。 此外，在第一步中生产的乙烯和乙酸可以用于第二步中用于VAM生产

    Gallium zeolites
    9.
    发明授权
    Gallium zeolites 失效
    GALLIUM ZEOLITES

    公开(公告)号：US5238675A

    公开(公告)日：1993-08-24

    申请号：US682731

    申请日：1991-04-09

    申请人： David J. Rawlence ,  Khalid Karim ,  John Dwyer

    发明人： David J. Rawlence ,  Khalid Karim ,  John Dwyer

    IPC分类号： B01J29/87 ,  C01B39/06 ,  C10G11/05

    CPC分类号： C01B39/065 ,  B01J29/87 ,  C10G11/05 ,  Y10S423/21

    摘要： Zeolites containing gallium in their crystalline framework structure are prepared by treating a zeolite material with a reagent capable of replacing a part of the aluminum of the framework structure of the zeolite material with the gallium. The method is especially applicable for the preparation of faujasitic materials of the formulaM.sub.(x+y/n) [ALO.sub.2 ].sub.x [GaO.sub.2 ].sub.y [SiO.sub.2 ].sub.zwherein:M is a charge balancing ion and n is the oxidation state thereof,x, y and z are the respective numbers of tetrahedra represented respectively by AlO.sub.2, GaO.sub.2 and SiO.sub.2,x+y+z=192, for a said faujasitic structure with no missing tetrahedra,x+y is from 0.1 to 71 inclusive, andy is from 0.01 to 60 inclusive.

    CATALYST USEFUL IN FISHER-TROPSCH SYNTHESIS
    10.
    发明申请
    CATALYST USEFUL IN FISHER-TROPSCH SYNTHESIS 有权
    催化剂有利于鱼类合成

    公开(公告)号：US20130274355A1

    公开(公告)日：2013-10-17

    申请号：US13995646

    申请日：2011-12-15

    申请人： Khalid Karim ,  Saleh A. Al-Sayari

    发明人： Khalid Karim ,  Saleh A. Al-Sayari

    IPC分类号： C07C1/04 ,  B01J27/187

    CPC分类号： C07C1/0435 ,  B01J23/8892 ,  B01J27/187 ,  B01J37/031 ,  B01J37/16 ,  C10G2/33 ,  C10G2400/30

    摘要： The present invention relates to a catalyst composition comprising cobalt manganese oxide which is modified with lanthanum and/or phosphorus and optionally one or more basic elements selected from the group consisting of alkali metal, alkaline earth metal and transition metal. Furthermore, a method for preparing said catalyst composition and a process for producing aliphatic and aromatic hydrocarbons by Fischer-Tropsch synthesis using said catalyst composition is provided.

    摘要翻译： 本发明涉及一种催化剂组合物，其包含用镧和/或磷改性的钴锰氧化物和任选的一种或多种选自碱金属，碱土金属和过渡金属的碱性元素。 此外，提供了制备所述催化剂组合物的方法和通过使用所述催化剂组合物通过费 - 托合成制备脂族和芳族烃的方法。