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1.发明授权Process for the production of diaminodiphenylmethane and its higher homologues 有权生产二氨基二苯甲烷及其高级同系物的方法公开(公告)号：US07238840B2
公开(公告)日：2007-07-03
申请号：US10947103
申请日：2004-09-21
IPC分类号： C07C209/78 , C07C263/10
CPC分类号： C07C209/78 , B01J21/16 , B01J29/041 , B01J29/70 , C08G18/7664 , C07C211/50
摘要： Method of preparing diaminodiphenylmethane and higher homologues thereof from aniline and formaldehyde in the presence of heterogeneous solid acid catalysts selected from (a) delaminated zeolites and/or (b) metal silicate catalysts having an ordered mesoporous pore structure and/or (c) delaminated phyllosilicates.
摘要翻译： 选自（a）分层沸石和/或（b）具有有序介孔孔结构的金属硅酸盐催化剂和/或（c）分层页硅酸盐的非均相固体酸催化剂存在下，由苯胺和甲醛制备二氨基二苯基甲烷及其高级同系物的方法 。
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2.发明申请Process for the production of diaminodiphenylmethane and its higher homologues 有权生产二氨基二苯甲烷及其高级同系物的方法公开(公告)号：US20050101801A1
公开(公告)日：2005-05-12
申请号：US10947103
申请日：2004-09-21
IPC分类号： C07C29/60 , C07C263/10
CPC分类号： C07C209/78 , B01J21/16 , B01J29/041 , B01J29/70 , C08G18/7664 , C07C211/50
摘要： Method of preparing diaminodiphenylmethane and higher homologues thereof from aniline and formaldehyde in the presence of heterogeneous solid acid catalysts selected from (a) delaminated zeolites and/or (b) metal silicate catalysts having an ordered mesoporous pore structure and/or (c) delaminated phyllosilicates.
摘要翻译： 选自（a）分层沸石和/或（b）具有有序介孔孔结构的金属硅酸盐催化剂和/或（c）分层页硅酸盐的非均相固体酸催化剂存在下，由苯胺和甲醛制备二氨基二苯基甲烷及其高级同系物的方法 。
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公开(公告)号：US20110282099A1
公开(公告)日：2011-11-17
申请号：US13133410
申请日：2009-11-26
IPC分类号： C07C211/51
CPC分类号： C07C209/60 , C07C209/78 , C07C211/50
摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps ofa) condensing aniline and formaldehyde, providing a condensate, the molar ratio of aniline to formaldehyde being chosen in the range of 2 to 3.5;b) reacting, in a first catalytic reaction step, at a reaction temperature within the range of about 30° C. to about 100° C., said condensate over a solid catalyst being chosen from the group consisting of clays, silicates, silica-aluminas and ion exchange resins, whereby an intermediate mixture is provided, the intermediate mixture comprising amino benzyl amines;c) converting, in a subsequent catalytic reaction step, at a temperature within the range of about 70° C. to about 250° C., the reaction temperature in said subsequent catalytic reaction step is higher than the reaction temperature in said first catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst being chosen from the group consisting of zeolites, delaminated zeolites and ordered mesoporous materials, thereby providing said methylene-bridged polyphenyl polyamines.
摘要翻译： 根据本发明的由苯胺和甲醛提供亚甲基桥接的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合，提供缩合物，苯胺与甲醛的摩尔比选择在2至3.5的范围内; b）在第一催化反应步骤中，在约30℃至约100℃范围内的反应温度下使所述缩合物在固体催化剂上选自粘土，硅酸盐，二氧化硅 - 氧化铝和离子交换树脂，由此提供中间体混合物，所述中间体混合物包含氨基苄基胺; c）在随后的催化反应步骤中，在约70℃至约250℃的温度范围内转化，所述后续催化反应步骤中的反应温度高于所述第一催化反应中的反应温度 在随后的固体催化剂存在下将所述中间体混合物形成亚甲基桥连的聚苯胺，所述固体催化剂选自沸石，分层沸石和有序介孔材料，从而提供所述亚甲基桥连的聚苯基多胺。
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公开(公告)号：US20050085678A1
公开(公告)日：2005-04-21
申请号：US10909276
申请日：2004-07-30
IPC分类号： B01J23/00 , B01J23/20 , B01J23/28 , B01J23/31 , B01J23/887 , B01J23/888 , B01J27/057 , B01J35/00 , B01J37/10 , C07C5/48 , C07C51/215 , C07C51/25 , C07C253/24 , C07C255/03 , C07C5/327
CPC分类号： C07C51/215 , B01J23/002 , B01J23/20 , B01J23/28 , B01J23/31 , B01J23/8877 , B01J23/8885 , B01J27/0576 , B01J35/002 , B01J37/10 , B01J2523/00 , C07C5/48 , C07C51/25 , C07C253/24 , C07C2521/04 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/04 , C07C2523/10 , C07C2523/14 , C07C2523/18 , C07C2523/20 , C07C2523/22 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/31 , C07C2523/32 , C07C2523/72 , C07C2523/745 , C07C2523/75 , C07C2523/755 , C07C2523/885 , C07C2523/887 , C07C2527/057 , Y02P20/52 , C07C11/04 , C07C53/08 , B01J2523/17 , B01J2523/55 , B01J2523/56 , B01J2523/64 , B01J2523/68 , C07C255/03
摘要： The invention relates to a method for the oxidative dehydrogenation of ethane. The inventive method is characterized in that it consists of bringing the ethane into contact with the catalyst containing Mo, Te, V, Nb and at least a fifth element A which is selected from Cu, Ta, Sn, Se, W, Ti, Fe, Co, Ni, Cr, Zr, Sb, Bi, an alkali metal, an alkaline-earth metal and a rare earth, in which at least Mo, Te, V and Nb are present in the form of at least one oxide, said catalyst presenting, in calcined form, an X-ray diffractogram with more than ten intense diffraction lines, typically, the most intense lines corresponding to diffraction angles 2Θ of 7.7°±0.4, 8.9°±0.4, 22.1°+0.4, 26.6°±0.4, 26.9°±0.4, 27.1°±0.4, 28.1°±0.4, 31.2°±0.4, 35.0°±0.4 and 45.06°±0.
摘要翻译： 本发明涉及乙烷的氧化脱氢方法。 本发明的方法的特征在于使乙烷与含有Mo，Te，V，Nb的催化剂和至少一种选自Cu，Ta，Sn，Se，W，Ti，Fe ，Co，Ni，Cr，Zr，Sb，Bi，碱金属，碱土金属和稀土，其中至少Mo，Te，V和Nb以至少一种氧化物的形式存在，所述 催化剂以煅烧形式呈现具有超过十条强衍射线的X射线衍射图，典型地，对应于衍射角2θ的最强烈线，其中7.7°±0.4°，8.9°±0.4°，22.1°±0.4°，26.6°± 0.4,26.9°±0.4,27.1°±0.4,28.1°±0.4,31.2°±0.4,35.0°±0.4和45.06°±0。
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公开(公告)号：US08871979B2
公开(公告)日：2014-10-28
申请号：US13133410
申请日：2009-11-26
IPC分类号： C07C211/00 , C07C209/60 , C07C209/78
CPC分类号： C07C209/60 , C07C209/78 , C07C211/50
摘要： A process for providing methylene-bridged polyphenyl polyamines from aniline and formaldehyde according to the invention comprises the subsequent steps of a) condensing aniline and formaldehyde; b) reacting, in a first catalytic reaction step, said condensate over a solid catalyst, whereby an intermediate mixture is provided; c) converting, in a subsequent catalytic reaction step, said intermediate mixture into methylene-bridged polyphenyl polyamines in presence of a subsequent solid catalyst, thereby providing said methylene-bridged polyphenyl polyamines.
摘要翻译： 根据本发明的由苯胺和甲醛提供亚甲基桥连的聚苯胺的方法包括以下步骤：a）使苯胺和甲醛缩合; b）在第一催化反应步骤中使所述缩合物在固体催化剂上反应，由此提供中间体混合物; c）在随后的催化反应步骤中，将所述中间体混合物在随后的固体催化剂的存在下转化为亚甲基桥连的聚苯胺，从而提供所述亚甲基桥接的聚苯胺。
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