公开(公告)号：US20060024221A1

公开(公告)日：2006-02-02

申请号：US11194523

申请日：2005-08-02

Applicant: Etienne Lebas ,  Stephane Bertholin ,  Luc Nougier ,  Beatrice Fischer

Inventor： Etienne Lebas ,  Stephane Bertholin ,  Luc Nougier ,  Beatrice Fischer

IPC: B01J10/00

CPC classification number: F23C99/00 ,  F23C2900/99008 ,  Y02E20/346

Abstract: The invention relates to a device for producing a hot gas by oxidation of an active material exhibiting an oxidized form and a reduced form by means of a simulated-rotation reactor.

Abstract translation: 本发明涉及通过模拟旋转反应器氧化形成氧化形式和还原形式的活性材料来生产热气的装置。

公开(公告)号：US20070092436A1

公开(公告)日：2007-04-26

申请号：US11523805

申请日：2006-09-20

Applicant: Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

Inventor： Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

IPC: C01B3/26

CPC classification number: C01B3/384 ,  B01J8/067 ,  B01J2208/00221 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/1294 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  Y02P20/128

Abstract: The invention concerns a process for producing synthesis gas, SG, from hydrocarbons and/or recycled compounds, in which: a stream comprising a first feed F1 supplemented with steam undergoes steam reforming in a multi-tube reactor-exchanger R with reaction tubes (38) containing a steam reforming catalyst, and with a shell; the reaction tubes are heated by convection by circulating in the shell, in overall counter-current mode, a heating fluid HF external to said tubes, which fluid comprises a first combustion gas stream of a second feed F2, then said fluid HF is mixed in a complementary combustion zone (32, 34) internal to the shell with a third feed F3 and a gas comprising oxygen, to increase the temperature of the HF, then the stream of mixture obtained circulates in R to heat the reaction tubes in a complementary manner; SG is produced from the steam reforming effluent from F1 and optionally part or all of the HF.

Abstract translation: 本发明涉及从烃和/或再循环化合物生产合成气SG的方法，其中：包含补充有蒸汽的第一进料F 1的流在具有反应管的多管反应器 - 交换器R中进行蒸汽重整 38），其含有蒸汽重整催化剂和壳; 反应管通过在外壳中以总体逆流模式循环加热，在所述管外部的加热流体HF，该流体包括第二进料F 2的第一燃烧气体流，然后将所述流体HF混合 在具有第三进料F 3和包含氧的气​​体的壳体内部的互补燃烧区域（32,34）中，为了增加HF的温度，则获得的混合物流在R中循环以在反应管中加热 互补的方式 SG由来自F 1的蒸汽重整流出物和可选的部分或全部HF产生。

公开(公告)号：US08858221B2

公开(公告)日：2014-10-14

申请号：US12745185

申请日：2008-10-24

Applicant: Stephane Bertholin ,  Fabrice Giroudiere

Inventor： Stephane Bertholin ,  Fabrice Giroudiere

IPC: F23L1/00 ,  F23M5/00 ,  B01J3/04 ,  B01J19/02

CPC classification number: B01J3/048 ,  B01J19/02 ,  B01J2219/00076 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/0263 ,  B01J2219/0286 ,  F23M5/00

Abstract: The present invention describes a novel reactor adapted for carrying out chemical reactions at temperatures of up to 1600° C., and at pressures of up to 100 bars. The reactor of the invention has two vessels surrounding the reaction zone, an inner vessel constituted by a refractory material and an outer vessel surrounding the inner vessel and constituted by an insulating material.

Abstract translation: 本发明描述了一种适用于在高达1600℃的温度和高达100巴的压力下进行化学反应的新型反应器。 本发明的反应器具有围绕反应区的两个容器，由耐火材料构成的内容器和围绕内容器并由绝缘材料构成的外容器。

公开(公告)号：US20080307707A1

公开(公告)日：2008-12-18

申请号：US12125411

申请日：2008-05-22

Applicant: Luc NOUGIER ,  Stephane Bertholin ,  Willy Nastoll

Inventor： Luc NOUGIER ,  Stephane Bertholin ,  Willy Nastoll

IPC: C10J1/20

CPC classification number: B01J8/0221 ,  B01J8/0285 ,  B01J19/006 ,  B01J19/244 ,  B01J2208/00495 ,  B01J2208/0053 ,  B01J2208/00557 ,  B01J2219/00085 ,  B01J2219/00094 ,  B01J2219/00155 ,  B01J2219/00768 ,  B01J2219/182 ,  B01J2219/185 ,  B01J2219/187 ,  C01B3/36 ,  C01B2203/0255 ,  C01B2203/0883 ,  C01B2203/1241 ,  C01B2203/1247 ,  C01B2203/1282 ,  Y02P20/129

Abstract: A reactor intended to carry out partial oxidation reactions starting from liquid feedstocks that can go from GPL to gas oil for the purpose of producing synthesis gas is characterized by finely controlled hydrodynamics and a high degree of thermal integration, and comprises an elongated jacket along an axis of any orientation, means (12) for supplying a preheated gas that contains oxygen and optionally water vapor, means (9) for supplying a hydrocarbon feedstock, means (11) for evacuation of a hydrogen-rich effluent, a first internal chamber (5) inside of which is carried out an essentially isothermal partial oxidation reaction that is connected to means (9) for supplying the hydrocarbon feedstock and to means (12) for supplying preheated gas, gas turbulizing means that are suitable for creating a perfect mixing flow, means (8) for linking first chamber (5) to a second chamber (7) with a suitable volume for carrying out a piston flow, linking means (8) that comprise at least one orifice, and second chamber (7) exchanging heat in an indirect manner over at least a portion of its length with means (12) for supplying said thus preheated gas, whereby the second chamber is connected to said means (11) for evacuating the hydrogen-rich effluent, and in which gas supply means (12) comprise an annular chamber that is essentially coaxial with the reactor jacket, and second chamber (7) is essentially coaxial with said jacket.

Abstract translation: 旨在进行部分氧化反应的反应器，其特征在于精细控制的流体动力学和高度的热积分，其特征在于可以从GPL到瓦斯油从液态原料开始的部分氧化反应，并且包括沿轴线的细长夹套 任何方向的装置（12），用于提供含氧气和任选的水蒸气的预热气体，用于供应烃原料的装置（9），用于抽空富氢流出物的装置（11），第一内室（5 ），其中进行基本上等温的部分氧化反应，其连接到用于供应烃原料的装置（9）和用于供应预热气体的装置（12），适于产生完美混合流的气体湍流装置， 用于将第一室（5）与第二室（7）连接的装置（8），其具有用于进行活塞流的合适体积，连接装置（8），其包括至少一个 e和第二室（7）以间接方式在其长度的至少一部分上与用于供应所述如此预热的气体的装置（12）进行热交换，由此第二室连接到所述装置（11）以抽空氢 其中气体供应装置（12）包括基本上与反应器夹套同轴的环形室，而第二室（7）基本上与所述夹套同轴。

公开(公告)号：US20110020758A1

公开(公告)日：2011-01-27

申请号：US12745185

申请日：2008-10-24

Applicant: Stephane Bertholin ,  Fabrice Giroudiere

Inventor： Stephane Bertholin ,  Fabrice Giroudiere

IPC: F23L1/00 ,  F28D21/00

CPC classification number: B01J3/048 ,  B01J19/02 ,  B01J2219/00076 ,  B01J2219/00155 ,  B01J2219/00159 ,  B01J2219/0263 ,  B01J2219/0286 ,  F23M5/00

Abstract: The present invention describes a novel reactor adapted for carrying out chemical reactions at temperatures of up to 1600° C., and at pressures of up to 100 bars. The reactor of the invention has two vessels surrounding the reaction zone, an inner vessel constituted by a refractory material and an outer vessel surrounding the inner vessel and constituted by an insulating material.

Abstract translation: 本发明描述了一种适用于在高达1600℃的温度和高达100巴的压力下进行化学反应的新型反应器。 本发明的反应器具有围绕反应区的两个容器，由耐火材料构成的内容器和围绕内容器并由绝缘材料构成的外容器。

公开(公告)号：US07687050B2

公开(公告)日：2010-03-30

申请号：US11523741

申请日：2006-09-20

Applicant: Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

Inventor： Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

IPC: C01B3/24 ,  C01B3/00 ,  B01J8/06

CPC classification number: C01B3/382 ,  B01J8/0496 ,  B01J8/067 ,  B01J2208/00221 ,  B01J2208/00309 ,  B01J2208/00539 ,  C01B3/384 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/1294 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  Y02E60/324

Abstract: For producing synthesis gas, SG, from a hydrocarbon feed and optionally from recycled compounds, F, a first feed F1 supplemented with steam undergoes steam reforming in a multi-tube reactor-exchanger R comprising a plurality of reaction tubes (38) containing a steam reforming catalyst and a shell containing said tubes, to produce a first synthesis gas SG1; reaction tubes (38) are heated principally by convection by circulating a fluid HF in the shell external to said tubes, in which HF is a staged partial oxidation stream with oxygen of a second feed F2 at a pressure in the range 0.5 to 12 MPa, to produce a second synthesis gas SG2; and the synthesis gas SG is produced by mixing SG1 and SG2.

Abstract translation: 为了从烃进料和任选地来自再循环的化合物F生产合成气，SG，补充有蒸汽的第一进料F1在多管反应器 - 交换器R中经历蒸汽重整，其包括多个反应管（38），其包含蒸汽 重整催化剂和含有所述管的壳，以产生第一合成气SG1; 反应管（38）主要通过对流来加热所述管外部的壳体中的流体HF，其中HF是第二进料F2的氧在0.5至12MPa的压力下的分段部分氧化流， 以产生第二合成气SG2; 并且通过混合SG1和SG2产生合成气SG。

公开(公告)号：US20090274593A1

公开(公告)日：2009-11-05

申请号：US12293126

申请日：2007-03-16

Applicant: Beatrice Fischer ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Jerome Colin

Inventor： Beatrice Fischer ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Jerome Colin

IPC: B01J19/00

CPC classification number: C01B3/384 ,  B01J8/02 ,  B01J8/025 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/067 ,  B01J19/26 ,  B01J2208/00123 ,  B01J2208/00132 ,  B01J2208/00221 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/00513 ,  B01J2208/00522 ,  B01J2208/0053 ,  B01J2208/00849 ,  B01J2208/00884 ,  B01J2208/025 ,  B01J2219/00119 ,  C01B2203/0233 ,  C01B2203/025 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/141 ,  C01B2203/82

Abstract: The invention concerns an exchanger-reactor (1) comprising: a vessel (2); means for distributing a feed through a fixed bed catalytic zone (10); means (6) for collecting effluent from the catalytic zone (10); means for heating the catalytic zone (10); in which said collection means (6) comprise conduits passing right through the catalytic zone (10), said conduits being distributed in the catalytic zone and interposed between the heating means, and in which the heating means of the catalytic zone are contained in sheaths (8) which are partially immersed in the catalytic zone (10), the sheaths (8) being open at one of their ends and closed at the other, the open end being fixed to an upper tube plate (21) defining the collection chamber (19) which is located above the catalytic zone (10), said heating means comprising at least one combustion zone (13) located close to the catalytic zone, means for supplying said combustion zone (13) with an oxidizing gas mixture (15) and with a gaseous fuel (17), and means for evacuating the gaseous effluent deriving from the combustion (14).

Abstract translation: 本发明涉及一种交换器 - 反应器（1），包括：容器（2）; 用于通过固定床催化区（10）分配进料的装置; 用于收集来自催化区（10）的流出物的装置（6）; 用于加热催化区（10）的装置; 其中所述收集装置（6）包括通过催化剂区域（10）的导管，所述管道分布在催化区域中，并且介于加热装置之间，并且其中催化区域的加热装置包含在护套中 8）部分地浸没在催化区域（10）中，护套（8）在其一端开口并在另一端开口，开口端固定到限定收集室的上管板（21） 19），其位于催化区（10）上方，所述加热装置包括靠近催化区的至少一个燃烧区（13），用于向燃烧区（13）供应氧化气体混合物（15）的装置和 与气体燃料（17）和用于排出源自燃烧（14）的气态流出物的装置。

公开(公告)号：US08273314B2

公开(公告)日：2012-09-25

申请号：US12293126

申请日：2007-03-16

Applicant: Beatrice Fischer ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Jerome Colin

Inventor： Beatrice Fischer ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Jerome Colin

IPC: B01J8/00

CPC classification number: C01B3/384 ,  B01J8/02 ,  B01J8/025 ,  B01J8/0278 ,  B01J8/0285 ,  B01J8/0453 ,  B01J8/0492 ,  B01J8/067 ,  B01J19/26 ,  B01J2208/00123 ,  B01J2208/00132 ,  B01J2208/00221 ,  B01J2208/00309 ,  B01J2208/00504 ,  B01J2208/00513 ,  B01J2208/00522 ,  B01J2208/0053 ,  B01J2208/00849 ,  B01J2208/00884 ,  B01J2208/025 ,  B01J2219/00119 ,  C01B2203/0233 ,  C01B2203/025 ,  C01B2203/0811 ,  C01B2203/0844 ,  C01B2203/141 ,  C01B2203/82

Abstract: The invention concerns an exchanger-reactor (1) comprising: a vessel (2); means for distributing a feed through a fixed bed catalytic zone (10); means (6) for collecting effluent from the catalytic zone (10); means for heating the catalytic zone (10); in which said collection means (6) comprise conduits passing right through the catalytic zone (10), said conduits being distributed in the catalytic zone and interposed between the heating means, and in which the heating means of the catalytic zone are contained in sheaths (8) which are partially immersed in the catalytic zone (10), the sheaths (8) being open at one of their ends and closed at the other, the open end being fixed to an upper tube plate (21) defining the collection chamber (19) which is located above the catalytic zone (10), said heating means comprising at least one combustion zone (13) located close to the catalytic zone, means for supplying said combustion zone (13) with an oxidizing gas mixture (15) and with a gaseous fuel (17), and means for evacuating the gaseous effluent deriving from the combustion (14).

Abstract translation: 本发明涉及一种交换器 - 反应器（1），包括：容器（2）; 用于通过固定床催化区（10）分配进料的装置; 用于收集来自催化区（10）的流出物的装置（6）; 用于加热催化区（10）的装置; 其中所述收集装置（6）包括通过催化剂区域（10）的导管，所述管道分布在催化区域中，并且介于加热装置之间，并且其中催化区域的加热装置包含在护套中 8）部分地浸没在催化区域（10）中，护套（8）在其一端开口并在另一端开口，开口端固定到限定收集室的上管板（21） 19），其位于催化区（10）上方，所述加热装置包括靠近催化区的至少一个燃烧区（13），用于向燃烧区（13）供应氧化气体混合物（15）的装置和 与气体燃料（17）和用于排出源自燃烧（14）的气态流出物的装置。

公开(公告)号：US08025862B2

公开(公告)日：2011-09-27

申请号：US11523805

申请日：2006-09-20

Applicant: Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

Inventor： Alexandre Rojey ,  Stephane Bertholin ,  Fabrice Giroudiere ,  Eric Lenglet

IPC: C01B3/26

CPC classification number: C01B3/384 ,  B01J8/067 ,  B01J2208/00221 ,  C01B3/382 ,  C01B3/386 ,  C01B2203/0233 ,  C01B2203/0255 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/043 ,  C01B2203/0805 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0844 ,  C01B2203/1241 ,  C01B2203/1294 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/143 ,  Y02P20/128

Abstract: The invention concerns a process for producing synthesis gas, SG, from hydrocarbons and/or recycled compounds. In the process: a stream comprising a first feed F1 supplemented with steam undergoes steam reforming in a multi-tube reactor-exchanger R having a shell and reaction tubes containing a steam reforming catalyst within the shell; the reaction tubes are heated by convection by circulating in the shell, in overall counter-current mode, a heating fluid HF external to the tubes, which fluid comprises a first combustion gas stream of a second feed F2, then fluid HF is mixed, in 1 to 4 complementary combustion zones internal to the shell, with a third feed F3 and a gas comprising oxygen, to increase the temperature of the HF, and then the mixture obtained circulates in R to heat the reaction tubes in a complementary manner; and SG is produced from the steam reforming effluent from F1 and optionally part or all of the HF.

Abstract translation: 本发明涉及从烃和/或再循环化合物生产合成气SG的方法。 在该过程中：包含补充有蒸汽的第一进料F1的料流在具有外壳的多管反应器 - 交换器R中进行蒸汽重整，并且在壳内含有蒸汽重整催化剂的反应管; 反应管通过在外壳中以总体逆流模式循环加热，在管的外部加热流体HF，该流体包括第二进料F2的第一燃烧气流，然后将流体HF混合在 1至4个壳体内部的互补燃烧区域，具有第三进料F3和包含氧气的气体，以增加HF的温度，然后获得的混合物在R中循环以互补的方式加热反应管; 并且SG由来自F1和任选的部分或全部HF的蒸汽重整流出物产生。

公开(公告)号：US20090241419A1

公开(公告)日：2009-10-01

申请号：US12057897

申请日：2008-03-28

Applicant: Christophe Boyer ,  Fabrice Giroudiere ,  Stephane Bertholin ,  Aziz Sattar

Inventor： Christophe Boyer ,  Fabrice Giroudiere ,  Stephane Bertholin ,  Aziz Sattar

IPC: C01B3/02

CPC classification number: C01B3/38 ,  C01B3/323 ,  C01B3/382 ,  C01B3/48 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/042 ,  C01B2203/044 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0888 ,  C01B2203/0894 ,  C01B2203/1229 ,  C01B2203/1294 ,  C01B2203/1604 ,  Y02P20/128 ,  Y02P20/129

Abstract: The invention relates to a start-up process for a unit for producing highly thermally-integrated hydrogen by reforming a hydrocarbon feedstock that comprises a stage a wherein a burner whose purpose is to ensure start-up is supplied with a mixture of hydrocarbon feedstock and air, a stage b wherein a water stream is evaporated by indirect heat exchange with at least one of the hot streams of the process, a stage c wherein the hydrocarbon feedstock to be reformed is evaporated and heated and then introduced in gaseous form in a reforming reactor, and a stage d wherein the start-up burner is shut down, and a burner that is in permanent operation is lit.

Abstract translation: 本发明涉及一种用于通过重整烃原料来生产高度热一体化氢的单元的启动方法，所述烃原料包括阶段a，其中其目的是确保启动的燃烧器被供应烃原料和空气的混合物 ，阶段b，其中通过与该方法的至少一个热流间接热交换来蒸发水流，其中待重组的烃原料被蒸发并加热，然后以气态形式引入重整反应器 ，以及阶段d，其中启动燃烧器关闭，并且永久操作的燃烧器点亮。