-
公开(公告)号:US20240368418A1
公开(公告)日:2024-11-07
申请号:US18654201
申请日:2024-05-03
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: C09D11/38 , B29C64/112 , B29C64/124 , B29K33/00 , B29K105/00 , B33Y10/00 , B33Y70/00 , C09D11/037 , C09D11/101 , C09D11/107 , C09D11/328
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength λ of less than or equal to 2×Dp.
-
公开(公告)号:US20220289994A1
公开(公告)日:2022-09-15
申请号:US17832129
申请日:2022-06-03
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: C09D11/38 , C09D11/328 , C09D11/101 , C09D11/107 , B29C64/124 , B33Y10/00 , B33Y70/00 , C09D11/037 , B29C64/112
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, an ink described herein comprises up to 80 wt. % oligomeric curable material; up to 80 wt. % monomeric curable material; up to 10 wt. % photoinitiator; up to 1 wt. % non-curable absorber material; and up to 10 wt. % one or more additional components, based on the total weight of the ink, and wherein the total amount of the foregoing components is equal to 100 wt. %. Additionally, the photoinitiator is operable to initiate curing of the oligomeric curable material and/or the monomeric curable material when the photoinitiator is exposed to incident curing radiation having a peak wavelength λ. Moreover, the ink has a penetration depth (Dp), a critical energy (Ec), and a print through depth (DPT) at the wavelength λ of less than or equal to 2×Dp.
-
公开(公告)号:US20240191089A1
公开(公告)日:2024-06-13
申请号:US18532480
申请日:2023-12-07
Applicant: 3D Systems, Inc.
Inventor: Mehrgan KHAVARI , Khalil MOUSSA
Abstract: In one aspect, inks for use with a three-dimensional (3D) printing system are described herein. In some embodiments, a composite ink described herein comprises a carrier ink comprising a curable material and a solid powder filler dispersed in the carrier ink. In some cases, the composite ink, in an uncured state, has a highly accelerated life testing (HALT) score of at least 2 when tested at 65° C. for at least 14 days. Additionally, in some embodiments, the composite ink, in an uncured state, has an average loss factor tan δ of less than or equal to 3 or less than or equal to 2 over an angular frequency range of 0.5 to 5 rad/s.
-
公开(公告)号:US20240131780A1
公开(公告)日:2024-04-25
申请号:US18390827
申请日:2023-12-20
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: B29C64/129 , C08F2/48 , C08F220/36 , C08F222/10 , C08F224/00 , C09D11/101 , C09D11/107
CPC classification number: B29C64/129 , C08F2/48 , C08F220/36 , C08F222/1065 , C08F224/00 , C09D11/101 , C09D11/107 , B33Y10/00
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.
-
公开(公告)号:US20250059378A1
公开(公告)日:2025-02-20
申请号:US18936488
申请日:2024-11-04
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: C09D4/00 , B29C64/124 , B29K105/00 , B33Y10/00 , B33Y70/00 , C08F220/22 , C08F220/58 , C08F222/10 , C08K5/521 , C09D7/63 , C09D133/16 , C09D133/24 , C09D135/02
Abstract: Polymerizable liquids for 3D printing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed from the liquids. The polymerizable liquids may also impart desirable mechanical properties to the articles. In some embodiments, a polymerizable liquid comprises a curable isocyanurate component in an amount of at least 5 wt. %, based on total weight of the polymerizable liquid, and a brominated acrylate ester component. Additionally, methods of printing three-dimensional articles using said polymerizable liquids are described herein.
-
公开(公告)号:US20240158610A1
公开(公告)日:2024-05-16
申请号:US18416540
申请日:2024-01-18
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: C08K5/01 , B29C64/106 , B33Y10/00 , B33Y70/10 , C08F20/10
CPC classification number: C08K5/01 , B29C64/106 , B33Y10/00 , B33Y70/10 , C08F20/10 , B29K2033/04
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart flame retardant properties and/or structural enhancements to articles printed from the build materials. In some embodiments, such an additive comprises a compound of Formula I herein, wherein L and Z are ring substituents comprising at least one polymerizable point of unsaturation, and wherein R1 and R2 are independently selected from the group consisting of alkylene and alkenylene, and R3-R6 each represent one to four optional ring substituents, each one of the one to four ring substituents independently selected from the group consisting of alkyl, heteroalkyl, haloalkyl, halo, hydroxyl, alkoxy, amine, amide, and ether, and wherein n is an integer from 1 to 7.
-
公开(公告)号:US20230249396A1
公开(公告)日:2023-08-10
申请号:US18180316
申请日:2023-03-08
Applicant: 3D Systems, Inc.
Inventor: Khalil MOUSSA
IPC: B29C64/124 , B33Y70/00 , C08L75/14 , B33Y10/00
CPC classification number: B29C64/124 , B33Y70/00 , C08L75/14 , B33Y10/00 , B29K2075/00
Abstract: Additives for three-dimensional build materials or inks are described herein which, in some embodiments, can impart one or more structural enhancements to articles printed from the build materials. In one aspect, a polymerizable liquid comprises at least one additive including a plurality of cyclopolymerizable functionalities separated by an aliphatic linker or alkylene oxide linker.
-
公开(公告)号:US20220363867A1
公开(公告)日:2022-11-17
申请号:US17826878
申请日:2022-05-27
Applicant: 3D Systems, Inc.
Inventor: Mehrgan KHAVARI , Khalil MOUSSA , Scott BROCE
IPC: C08K5/08 , C08F220/50 , C08F226/06
Abstract: Build materials for 3D printing applications are described herein which, in some embodiments, comprise a dye component operable to alter spectral characteristics of the printed part over the course of the build cycle. In some embodiments, for example, the dye component can provide desirable light penetration depth during article printing and sufficient optical clarity during final light curing processes.
-
9.
公开(公告)号:US20240052181A1
公开(公告)日:2024-02-15
申请号:US18448551
申请日:2023-08-11
Applicant: 3D Systems, Inc.
Inventor: Meisam Shir MOHAMMADI , Khalil MOUSSA , Zezette PFLAUM
CPC classification number: C09D5/185 , C09K21/02 , C09D5/033 , C09D5/031 , C09D7/61 , C09D7/69 , C09D177/02 , B33Y70/00 , C08K7/24
Abstract: Compositions for additive manufacturing applications are described herein which, in some embodiments, impart flame resistant and/or flame retardant properties to articles printed or formed from the compositions. The compositions may also impart desirable mechanical properties to the articles. In some embodiments, a composition comprises a sinterable powder or a thermoplastic polymer in an amount of 10-99 wt. %, based on the total weight of the composition, and an expandable graphite component in an amount of up to 20 wt. %, based on the total weight of the composition. In some instances, the expandable graphite component is in its free form or encapsulated in material.
-
公开(公告)号:US20240026183A1
公开(公告)日:2024-01-25
申请号:US18351875
申请日:2023-07-13
Applicant: 3D SYSTEMS, INC.
Inventor: Monica KEILSOHN , Michael BRADY , Khalil MOUSSA
IPC: C09D151/08 , B33Y70/00 , C09D4/00 , C09D7/41 , C08F290/06 , A61L27/52 , A61L27/16
CPC classification number: C09D151/08 , B33Y70/00 , C09D4/00 , C09D7/41 , C08F290/062 , A61L27/52 , A61L27/16 , B29C64/124
Abstract: In one aspect, build materials for use with a three-dimensional (3D) printing system are described herein. In some embodiments, a build material described herein comprises an acrylate component, a photoinitiator component, a non-curable absorber component, and water. The photoinitiator component of the build material is operable to initiate curing of the acrylate component and/or other curable materials that may optionally be present when the photoinitiator is exposed to incident curing radiation having a Gaussian distribution of wavelengths and a peak wavelength λ. The build material has a penetration depth (Dp) and a critical energy (Ec) at the wavelength λ. In some embodiments, the Dp is greater than 200 μm and less than 300 μm, and the Ec is 3-12 mJ/cm2. In other embodiments, the Dp is greater than 10 μm and less than 50 μm, and the Ec is 5-40 mJ/cm2.
-
-
-
-
-
-
-
-
-