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公开(公告)号：US20080086946A1
公开(公告)日：2008-04-17
申请号：US11847097
申请日：2007-08-29
申请人： Alan Weimer , Christopher Perkins , Dragan Mejic , Paul Lichty
发明人： Alan Weimer , Christopher Perkins , Dragan Mejic , Paul Lichty
CPC分类号： C10B19/00 , B01J19/127 , C01B3/10 , C01B3/12 , C01B3/586 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C10B53/02 , C10J3/485 , C10J3/506 , C10J2300/0916 , C10J2300/092 , C10J2300/0973 , C10J2300/0983 , C10J2300/1284 , C10J2300/1292 , C22B5/10 , C22B5/12 , C22B7/001 , F24S90/00 , Y02E10/40 , Y02E50/14 , Y02E50/32 , Y02E60/36 , Y02P10/122 , Y02P10/214 , Y02P20/134 , Y02P20/145
摘要： Methods for carrying out high temperature reactions such as biomass pyrolysis or gasification using solar energy. The biomass particles are rapidly heated in a solar thermal entrainment reactor. The residence time of the particles in the reactor can be 5 seconds or less. The biomass particles may be directly or indirectly heated depending on the reactor design. Metal oxide particles can be fed into the reactor concurrently with the biomass particles, allowing carbothermic reduction of the metal oxide particles by biomass pyrolysis products. The reduced metal oxide particles can be reacted with steam to produce hydrogen in a subsequent process step.
摘要翻译： 使用太阳能进行生物质热解或气化的高温反应的方法。 生物质颗粒在太阳能热夹带反应器中快速加热。 颗粒在反应器中的停留时间可以为5秒或更短。 生物质颗粒可以根据反应器设计直接或间接加热。 金属氧化物颗粒可以与生物质颗粒同时进料到反应器中，通过生物质热解产物使金属氧化物颗粒发生碳热还原。 还原的金属氧化物颗粒可以与蒸汽反应以在随后的工艺步骤中产生氢。
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公开(公告)号：US08287610B2
公开(公告)日：2012-10-16
申请号：US11847097
申请日：2007-08-29
申请人： Alan W. Weimer , Christopher Perkins , Dragan Mejic , Paul Lichty
发明人： Alan W. Weimer , Christopher Perkins , Dragan Mejic , Paul Lichty
CPC分类号： C10B19/00 , B01J19/127 , C01B3/10 , C01B3/12 , C01B3/586 , C01B2203/0283 , C01B2203/0445 , C01B2203/047 , C10B53/02 , C10J3/485 , C10J3/506 , C10J2300/0916 , C10J2300/092 , C10J2300/0973 , C10J2300/0983 , C10J2300/1284 , C10J2300/1292 , C22B5/10 , C22B5/12 , C22B7/001 , F24S90/00 , Y02E10/40 , Y02E50/14 , Y02E50/32 , Y02E60/36 , Y02P10/122 , Y02P10/214 , Y02P20/134 , Y02P20/145
摘要： Methods for carrying out high temperature reactions such as biomass pyrolysis or gasification using solar energy. The biomass particles are rapidly heated in a solar thermal entrainment reactor. The residence time of the particles in the reactor can be 5 seconds or less. The biomass particles may be directly or indirectly heated depending on the reactor design. Metal oxide particles can be fed into the reactor concurrently with the biomass particles, allowing carbothermic reduction of the metal oxide particles by biomass pyrolysis products. The reduced metal oxide particles can be reacted with steam to produce hydrogen in a subsequent process step.
摘要翻译： 使用太阳能进行生物质热解或气化的高温反应的方法。 生物质颗粒在太阳能热夹带反应器中快速加热。 颗粒在反应器中的停留时间可以为5秒或更短。 生物质颗粒可以根据反应器设计直接或间接加热。 金属氧化物颗粒可以与生物质颗粒同时进料到反应器中，通过生物质热解产物使金属氧化物颗粒发生碳热还原。 还原的金属氧化物颗粒可以与蒸汽反应以在随后的工艺步骤中产生氢。
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3.发明授权Metal ferrite spinel energy storage devices and methods for making and using same 有权金属铁素体尖晶石储能装置及其制造和使用方法公开(公告)号：US08397508B2
公开(公告)日：2013-03-19
申请号：US12741492
申请日：2008-11-05
CPC分类号： F28D20/003 , C01B3/042 , C01B3/06 , C01B13/0203 , C09K5/16 , C23C16/406 , C23C16/45525 , C23C16/45531 , Y02E60/142 , Y02E60/364 , Y02E70/30 , Y02P20/134 , Y10T428/24033 , Y10T428/257
摘要： 1-100 nm metal ferrite spinel coatings are provided on substrates, preferably by using an atomic layer deposition process. The coatings are able to store energy such as solar energy, and to release that stored energy, via a redox reaction. The coating is first thermally or chemically reduced. The reduced coating is then oxidized in a second step to release energy and/or hydrogen, carbon monoxide or other reduced species.
摘要翻译： 优选通过使用原子层沉积工艺在衬底上提供1-100nm的金属铁素体尖晶石涂层。 涂层能够储存诸如太阳能的能量，并通过氧化还原反应释放储存的能量。 涂层首先被热或化学还原。 然后在第二步骤中将还原的涂层氧化以释放能量和/或氢，一氧化碳或其它还原物质。
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4.发明申请METAL FERRITE SPINEL ENERGY STORAGE DEVICES AND METHODS FOR MAKING AND USING SAME 有权金属铁素体能量储存装置及其制造和使用方法公开(公告)号：US20100218491A1
公开(公告)日：2010-09-02
申请号：US12741492
申请日：2008-11-05
CPC分类号： F28D20/003 , C01B3/042 , C01B3/06 , C01B13/0203 , C09K5/16 , C23C16/406 , C23C16/45525 , C23C16/45531 , Y02E60/142 , Y02E60/364 , Y02E70/30 , Y02P20/134 , Y10T428/24033 , Y10T428/257
摘要： 1-100 nm metal ferrite spinel coatings are provided on substrates, preferably by using an atomic layer deposition process. The coatings are able to store energy such as solar energy, and to release that stored energy, via a redox reaction. The coating is first thermally or chemically reduced. The reduced coating is then oxidized in a second step to release energy and/or hydrogen, carbon monoxide or other reduced species.
摘要翻译： 优选通过使用原子层沉积工艺在衬底上提供1-100nm的金属铁素体尖晶石涂层。 涂层能够储存诸如太阳能的能量，并通过氧化还原反应释放储存的能量。 涂层首先被热或化学还原。 然后在第二步骤中将还原的涂层氧化以释放能量和/或氢，一氧化碳或其它还原物质。
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公开(公告)号：US20100215897A1
公开(公告)日：2010-08-26
申请号：US12774286
申请日：2010-05-05
IPC分类号： C23C16/44
CPC分类号： F28D20/003 , C01B3/042 , C01B3/06 , C01B13/0203 , C09K5/16 , C23C16/406 , C23C16/45525 , C23C16/45531 , Y02E60/142 , Y02E60/364 , Y02E70/30 , Y02P20/134 , Y10T428/24033 , Y10T428/257
摘要： 1-100 nm metal ferrite spinel coatings are provided on substrates, preferably by using an atomic layer deposition process. The coatings are able to store energy such as solar energy, and to release that stored energy, via a redox reaction. The coating is first thermally or chemically reduced. The reduced coating is then oxidized in a second step to release energy and/or hydrogen, carbon monoxide or other reduced species.
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6.发明授权Metal ferrite spinel energy storage devices and methods for making and using same 有权金属铁素体尖晶石储能装置及其制造和使用方法公开(公告)号：US08187731B2
公开(公告)日：2012-05-29
申请号：US12774286
申请日：2010-05-05
IPC分类号： C23C16/44
CPC分类号： F28D20/003 , C01B3/042 , C01B3/06 , C01B13/0203 , C09K5/16 , C23C16/406 , C23C16/45525 , C23C16/45531 , Y02E60/142 , Y02E60/364 , Y02E70/30 , Y02P20/134 , Y10T428/24033 , Y10T428/257
摘要： 1-100 nm metal ferrite spinel coatings are provided on substrates, preferably by using an atomic layer deposition process. The coatings are able to store energy such as solar energy, and to release that stored energy, via a redox reaction. The coating is first thermally or chemically reduced. The reduced coating is then oxidized in a second step to release energy and/or hydrogen, carbon monoxide or other reduced species.
摘要翻译： 优选通过使用原子层沉积工艺在衬底上提供1-100nm的金属铁素体尖晶石涂层。 涂层能够储存诸如太阳能的能量，并通过氧化还原反应释放储存的能量。 涂层首先被热或化学还原。 然后在第二步骤中将还原的涂层氧化以释放能量和/或氢，一氧化碳或其它还原物质。
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7.发明授权Semi-continuous vapor deposition process for the manufacture of coated particles 有权用于制造涂层颗粒的半连续气相沉积工艺公开(公告)号：US09284643B2
公开(公告)日：2016-03-15
申请号：US13069452
申请日：2011-03-23
申请人： David M. King , Alan W. Weimer , Paul Lichty
发明人： David M. King , Alan W. Weimer , Paul Lichty
IPC分类号： C23C16/00 , C23C16/44 , C04B41/00 , C04B41/45 , C04B41/81 , C23C16/40 , C23C16/455 , C23C16/442
CPC分类号： C23C16/402 , C04B41/009 , C04B41/4584 , C04B41/5031 , C04B41/5035 , C04B41/5041 , C04B41/5049 , C04B41/81 , C04B41/87 , C23C16/403 , C23C16/405 , C23C16/407 , C23C16/4417 , C23C16/442 , C23C16/45525 , C23C16/45555 , C04B35/46 , C04B35/48 , C04B41/4531
摘要： A reactor for conducting vapor phase deposition process is disclosed. The reactor includes a reactive precursor reservoir beneath a powder reservoir and separated from it by valve means. A reactive precursor is charged into the reactive precursor reservoir and a powder is charged into the powder reservoir. The pressures are adjusted so that the pressure in the reactive precursor reservoir is higher than that of the powder reservoir. The valve means is opened, and the vapor phase reactant fluidized the powder and coats its surface. The powder falls into the reactive precursor reservoir. The apparatus permits vapor phase deposition processes to be performed semi-continuously.
摘要翻译： 公开了一种用于进行气相沉积工艺的反应器。 反应器包括位于粉末储存器下方的反应性前体储存器，并通过阀装置与其分离。 将反应性前体装入反应性前体储存器中，并将粉末装入粉末储存器中。 调整压力使得反应性前体储存器中的压力高于粉末储存器的压力。 打开阀门装置，汽相反应物流化粉末并涂覆其表面。 粉末落入反应性前体储存器中。 该装置允许气相沉积工艺半连续地进行。
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8.发明申请Semi-Continuous Vapor Deposition Process for the Manufacture of Coated Particles 有权用于制造涂层颗粒的半连续气相沉积工艺公开(公告)号：US20110236575A1
公开(公告)日：2011-09-29
申请号：US13069452
申请日：2011-03-23
申请人： David M. King , Alan W. Weimer , Paul Lichty
发明人： David M. King , Alan W. Weimer , Paul Lichty
IPC分类号： C23C16/44 , C23C16/455 , C23C16/46
CPC分类号： C23C16/402 , C04B41/009 , C04B41/4584 , C04B41/5031 , C04B41/5035 , C04B41/5041 , C04B41/5049 , C04B41/81 , C04B41/87 , C23C16/403 , C23C16/405 , C23C16/407 , C23C16/4417 , C23C16/442 , C23C16/45525 , C23C16/45555 , C04B35/46 , C04B35/48 , C04B41/4531
摘要： A reactor for conducting vapor phase deposition process is disclosed. The reactor includes a reactive precursor reservoir beneath a powder reservoir and separated from it by valve means. A reactive precursor is charged into the reactive precursor reservoir and a powder is charged into the powder reservoir. The pressures are adjusted so that the pressure in the reactive precursor reservoir is higher than that of the powder reservoir. The valve means is opened, and the vapor phase reactant fluidized the powder and coats its surface. The powder falls into the reactive precursor reservoir. The apparatus permits vapor phase deposition processes to be performed semi-continuously.
摘要翻译： 公开了一种用于进行气相沉积工艺的反应器。 反应器包括位于粉末储存器下方的反应性前体储存器，并通过阀装置与其分离。 将反应性前体装入反应性前体储存器中，并将粉末装入粉末储存器中。 调整压力使得反应性前体储存器中的压力高于粉末储存器的压力。 打开阀门装置，汽相反应物流化粉末并涂覆其表面。 粉末落入反应性前体储存器中。 该装置允许气相沉积工艺半连续地进行。
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