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    Reactive stabilizing compounds containing a sterically hindered amino group and a hydrolyzable silyl function
    2.
    发明授权
    Reactive stabilizing compounds containing a sterically hindered amino group and a hydrolyzable silyl function 失效
    含有空间位阻氨基和可水解甲硅烷基官能团的反应性稳定化合物

    公开(公告)号：US4684726A

    公开(公告)日：1987-08-04

    申请号：US733526

    申请日：1985-05-13

    申请人： Alberto Greco ,  Carlo Busetto ,  Luigi Cassar ,  Carlo Neri

    发明人： Alberto Greco ,  Carlo Busetto ,  Luigi Cassar ,  Carlo Neri

    IPC分类号： C07D207/08 ,  C07D211/46 ,  C07D211/58 ,  C07D265/32 ,  C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C07F11/00 ,  C08F8/12 ,  C08F8/42 ,  C08K5/00 ,  C08K5/54 ,  C08K5/5419 ,  C08K5/544 ,  C08K5/548 ,  C08K9/12 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L101/00 ,  C07F7/10

    CPC分类号： C07D207/08 ,  C07D211/46 ,  C07D211/58 ,  C07D265/32 ,  C07F7/0854 ,  C07F7/0896 ,  C07F7/12 ,  C07F7/182 ,  C08F8/42 ,  C08K5/5442 ,  C08K9/12

    摘要： Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.According to a further embodiment, the reactive stabilizing compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains.In all cases, stabilized polymers are obtained containing the stabilizing compound in a form which is not removable from the polymer.The processes for preparing the reactive stabilizing compounds and for preparing the stabilized polymer compositions are also described.

    摘要翻译： 能够稳定有机聚合物的反应性稳定化合物在其分子中含有空间位阻氨基和可水解的甲硅烷基官能团。 在稳定有机聚合物中，所述反应性稳定化合物可以在甲硅烷基官能团下水解，形成硅烷醇基团，使其相互作用以形成复杂的树脂稳定结构。 这些后者以稳定的量加入要稳定的聚合物中。 根据一个具体实施方案，甲硅烷基官能团中的水解和树脂结构的形成在待稳定的聚合物内自发发生。 根据另一个实施方案，将反应性稳定化合物通过与具有表面羟基的无机固体反应稳定地负载在固体载体上之后加入到聚合物中。 根据另一个实施方案，使反应性稳定化合物与聚合物相互作用，使得稳定化合物变得化学键合到聚合物链上。 在所有情况下，获得的稳定化聚合物含有不能从聚合物中除去的形式的稳定化合物。 还描述了制备反应性稳定化合物和制备稳定化聚合物组合物的方法。

    Stabilizer compounds and process for their preparation
    4.
    发明授权
    Stabilizer compounds and process for their preparation 失效
    稳定剂化合物及其制备方法

    公开(公告)号：US4778838A

    公开(公告)日：1988-10-18

    申请号：US45066

    申请日：1987-05-01

    申请人： Alberto Greco ,  Carlo Busetto

    发明人： Alberto Greco ,  Carlo Busetto

    IPC分类号： C09K15/32 ,  C07F9/59 ,  C07F9/6574 ,  C08K5/54 ,  C08K5/544 ,  C08L101/00 ,  C08K5/34 ,  C07D211/46 ,  C07F7/02

    CPC分类号： C07F9/65746 ,  C07F9/592 ,  C07F9/65744 ,  C08K5/5406

    摘要： Siliconic compounds, stabilizer for organic polymers, containing in their molecule the aromatic phosphite or phosphonite function and the sterically hindered aminic function, are obtained by making a 2,2,6,6-tetramethyl-piperidinyl-4-oxyalkylene-.gamma.-alkyl-di(alkyloxy)silane, an aliphatic glycol, an aromatic phosphite, phosphonite or diphosphite and possibly an aliphatic mono-hydroxy alcohol interact with each other.

    摘要翻译： 通过制备2,2,6,6-四甲基 - 哌啶基-4-氧亚烷基-γ-烷基 - 亚烷基 - 取代基来获得在其分子中含有芳族亚磷酸酯或亚膦酸酯官能团和空间位阻胺官能团的有机聚合物的稳定剂， 二（烷氧基）硅烷，脂族二醇，芳族亚磷酸酯，亚膦酸酯或二亚磷酸酯和可能的脂族单羟基醇相互作用。

    Photochromatic composition endowed with light fatigue resistance and photochromatic articles which contain it
    5.
    发明授权
    Photochromatic composition endowed with light fatigue resistance and photochromatic articles which contain it 失效
    具有轻度耐疲劳性和含有它的光致变色制品的光色漆

    公开(公告)号：US5225113A

    公开(公告)日：1993-07-06

    申请号：US853910

    申请日：1992-03-19

    申请人： Carlo Busetto ,  Luciana Crisci

    发明人： Carlo Busetto ,  Luciana Crisci

    IPC分类号： C07F7/08 ,  C08K5/544 ,  G03C1/685

    CPC分类号： C07F7/0858 ,  C08K5/5442 ,  G03C1/685

    摘要： A photochromatic composition, endowed with a high light fatigue resistance contains a photochromatic compound belonging to the class of spirooxazines and an U.V.-stabilizer consisting of a sterically hindered amine to be defined by means of formula (I): ##STR1## wherein: R is either hydrogen or a methyl group,x is either oxygen or nitrogen,m is a number comprised within the range of from 2 to 10, andn is a number coprised within the range of from 1 to 100.A photochromatic article made from a thermoplastic material, endowed with a high light fatigue resistance, contains a thermoplastic material and the hereinabove disclosed photochromatic composition.

    摘要翻译： 具有高耐光疲劳性的光色调组合物包含属于螺恶嗪类的光色化合物和由通式（I）定义的空间位阻胺组成的UV稳定剂：其中：R为 氢或甲基，x为氧或氮，m为2至10范围内的数，n为1至100范围内的数。由热塑性塑料制成的彩色制品 具有高耐光疲劳性的材料含有热塑性材料和上述公开的光致变色组合物。

    Stabilizing compositions for organic polymers
    6.
    发明授权
    Stabilizing compositions for organic polymers 失效
    有机聚合物的稳定组合物

    公开(公告)号：US5229442A

    公开(公告)日：1993-07-20

    申请号：US846936

    申请日：1992-03-06

    申请人： Fabio Broussard ,  Carlo Busetto

    发明人： Fabio Broussard ,  Carlo Busetto

    IPC分类号： C08K5/13 ,  C07C211/51 ,  C07C211/55 ,  C07D219/02 ,  C08K5/134 ,  C08K5/17 ,  C08K5/18 ,  C08K5/3412 ,  C08K5/3437 ,  C08L101/00 ,  C09K15/04

    CPC分类号： C09K15/04 ,  C07C211/51 ,  C07C211/55 ,  C07D219/02 ,  C08K5/1345 ,  C08K5/18 ,  C08K5/3437

    摘要： Stabilizing compositions for organic polymers, composed of mixtures of at least one liquid phenolic antioxidant and at least one aminic antioxidant, subjected to thermal treatment, are characterized by their stabilizing capacity which is considerably higher than that of either single components or of corresponding untreated mixtures.These stabilizing compositions can be used in all field where the single components of the mixtures are generally used and, preferably, in the stabilization of organic polymers normally subject to deterioration due to oxidation processes.

    摘要翻译： 由经受热处理的至少一种液体酚类抗氧化剂和至少一种氨基抗氧化剂的混合物组成的有机聚合物的稳定组合物的特征在于其稳定能力比单一组分或相应的未处理混合物的稳定组分高得多。 这些稳定化组合物可用于通常使用混合物的单一组分的所有领域，优选在通常由于氧化过程而劣化的有机聚合物的稳定化中使用。

    Solid polymeric stabilizer compounds and process for their manufacture
    9.
    发明授权
    Solid polymeric stabilizer compounds and process for their manufacture 失效
    固体聚合物稳定剂化合物及其制备方法

    公开(公告)号：US4797451A

    公开(公告)日：1989-01-10

    申请号：US910885

    申请日：1986-09-24

    申请人： Arnaldo Roggero ,  Guglielmo Bertolini ,  Carlo Busetto

    发明人： Arnaldo Roggero ,  Guglielmo Bertolini ,  Carlo Busetto

    IPC分类号： C08K5/34 ,  C08C19/22 ,  C08F8/30 ,  C08L101/00 ,  C08F8/42

    CPC分类号： C08F8/30 ,  C08C19/22

    摘要： Solid polymeric stabilizer compounds are disclosed comprising an organic polymeric matrix, to which are linked groups containing a sterically hindered aminic function, the organic polymeric matrix being a polymeric matrix of a vinyl-aromatic, aromatic with heteroatoms, dienic or olefinic polymer, containing hydrogen atoms replaceable by metal atoms, the groups containing the sterically hindered aminic function replacing, at least partially, said replaceable-by-metal hydrogen atoms of the matrix.Also disclosed are processes for the preparation of said solid polymeric stabilizers and stabilized polymeric compositions comprising an organic polymer and a stabilizing amount of said solid polymeric stabilizers.

    摘要翻译： 公开了包含有机聚合物基质的固体聚合物稳定剂化合物，其中是含有空间位阻胺官能团的连接基团，有机聚合物基质是具有杂原子的芳香族芳族化合物，含有氢原子的二烯或烯烃聚合物的聚合物基体 由金属原子替代，含有空间位阻氨基官能团的基团至少部分替代了基质的所述可替换的金属氢原子。 还公开了制备所述固体聚合物稳定剂和包含有机聚合物和稳定量的所述固体聚合物稳定剂的稳定化聚合物组合物的方法。