摘要:
Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to the stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.According to a further embodiment, the reactive stabilizing compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains.In all cases, stabilized polymers are obtained containing the stabilizing compound in a form which is not removable from the polymer.The processes for preparing the reactive stabilizing compounds and for preparing the stabilizing polymer compositions are also described.
摘要:
Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.According to a further embodiment, the reactive stabilizing compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains.In all cases, stabilized polymers are obtained containing the stabilizing compound in a form which is not removable from the polymer.The processes for preparing the reactive stabilizing compounds and for preparing the stabilized polymer compositions are also described.
摘要:
Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function. In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized. According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized. According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups. According to a further embodiment, the reactive stabilizing compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains. In all cases, stabilized polymers are obtained containing the stabilizing compound in a form which is not removable from the polymer. The processes for preparing the reactive stabilizing compounds and for preparing the stabilized polymer compositions are also described.
摘要:
Reactive antioxidant compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered phenolic group and a hydrolysable silyl function. In stabilizing organic polymers, said reactive antioxidant compounds can be hydrolysed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to be stabilized. According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized. According to a further embodiment, the reactive antioxidant compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups. According to a further embodiment, the reactive antioxidant compound is made to interact with the polymer so that the stabilizing compound becomes chemically bonded to the polymer chains. In all cases, stabilized polymers are obtained containing the antioxidant compound in a form which is not removable from the polymer. The processes for preparing the reactive antioxidant compounds and for preparing the stabilized polymer compositions are also described.
摘要:
A fuel composition with a high energy content, for direct-ignition internal combustion engines contains a gasoline from petroleum and an amount of up to 90% by volume, as referred to the same fuel composition, of hydrocarbon "cubane" or of its alkyl-derivatives, to be defined by means of the formula: ##STR1## wherein R' and R" represent, independently from each other, a hydrogen atom or an alkyl radical containing from 1 to 3 carbon atoms.
摘要:
Polymeric stabilizer compounds with a polyorganosiloxane structure suitable for stabilizing organic polymers against UV radiation and heat, containing sterically hindered piperidino groups in their molecule and easily prepared in well defined, predetermined structures.
摘要:
A high-energy-content fuel composition, for controlled-ignition internal combustion engines, contains quadricyclane (tetracyclo-[2.2.1.0-(2,6).0-3,5]-heptane), for which a new synthesis method is proposed.The use of the quadricyclane-containing fuel composition makes it possible a larger amount of energy to be available per each fuel volume unit, and favorably modifies the combustion kinetics in controlled-ignition internal combustion engines.
摘要:
An integrated clutch-transmission assembly for a road vehicle; the integrated clutch-transmission assembly has a power-assisted clutch having a number of first hydraulic actuators; a power-assisted transmission having a number of second hydraulic actuators; a high-pressure pump for the hydraulic actuators; a number of solenoid valves for controlling the hydraulic actuators; a housing having a first chamber housing the clutch, and a second chamber housing the transmission; and a flat supporting plate, which is housed removably inside the housing to separate the two chambers of the housing, has a first wall fitted with the clutch, and has a second wall parallel to and opposite the first wall and fitted with the high-pressure pump and at least some of the solenoid valves.
摘要:
A four-wheel-drive vehicle transmission (1) having a drive torque input shaft (8) rotated about a first axis of rotation (A); a front output shaft (10); a rear output shaft (12); an auxiliary tubular shaft (14) mounted alongside the input shaft (8) to rotate about a second axis of rotation (D); at least one first group of gears (15, 16) for selectively connecting the auxiliary tubular shaft (14) to the input shaft (8); a first countershaft (17) mounted inside the auxiliary tubular shaft (14); a second countershaft (18) mounted for rotation opposite the first countershaft (17); a planetary gear train (19) for mechanically connecting the auxiliary tubular shaft (14) to the first (17) and second (18) countershafts; and a first (25) and a second (26) cascade gear set for connecting the first and second countershafts (17,18) to the front and rear output shafts (10,12), respectively.
摘要:
Mixtures of additives in granular form comprising: one or more stabilizers for organic polymers; one or more organic or inorganic pigments; and/or one or more dyes; obtained by extrusion at a temperature capable of enabling the partial or total melting of the lowest-melting component. The above mixtures can be used in the stabilization and dyeing of organic polymers.