MIXTURES OF COSMETIC UV ABSORBERS
    2.
    发明申请

    公开(公告)号:US20170290756A1

    公开(公告)日:2017-10-12

    申请号:US15509668

    申请日:2015-09-04

    Applicant: BASF SE

    CPC classification number: A61K8/496 A61K8/37 A61K8/4966 A61K2800/592 A61Q17/04

    Abstract: Disclosed is a cosmetic or pharmaceutical composition comprising a UV filter combination of (a) at least one benzotriazole derivative corresponding to the formula wherein R1 is hydrogen; C1-C5alkyl; C1-C5alkoxy; or halogen; R2 is hydrogen; C1-C20alkyl; C1-C5alkoxy; C1-C5alkoxycarbonyl; C5-C10cycloalkyl; C5-C10aryl; or C5-C10aralkyl; R3 is C1-C20alkyl; C5-C10cycloalkyl; C1-C20alkoxy; or C5-C10cycloalkoxy; and R4 is hydrogen; or C1-C5alkyl; (b) at least one UV filter selected from (b1) benzylidene malonate UV filters; (b2) micronized 5,6,5′,6′-tetraphenyl-3,3′-(1,4-Phenylene)bis(1,2,4-Triazine) corresponding to the formula (b3) Benzoic acid, 4,4′-[[6-[[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]-1 disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester; and (b4) 2-Propenoic acid, 3-(4-methoxyphenyl)-, 2-methylphenyl ester; and optionally (c) at least one UV filter selected from (c1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (c2) Butyl Methoxydibenzoylmethane; (c3) Diethylhexyl Butamido Triazone; (c4) Ethylhexyl Triazone; (c5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (c6) Ethylhexyl Methoxycinnamate; (c7) Ethylhexyl Salicylate; (c8) Homosalate; (c9) Octocrylene; (c10) Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (c11) Phenylbenzimidazole Sulfonic Acid; (c12) Titanium Dioxide; (c13) Tris-Biphenyl Triazine; (c14) (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (c15) merocyanine derivatives; (c16) Bis(butylbenzoate) diaminotriazine aminopropylsiloxane; and (c17) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine, encapsulated in a polymer matrix.

    MICRO-PARTICULATE ORGANIC UV ABSORBER COMPOSITION

    公开(公告)号:US20190274939A1

    公开(公告)日:2019-09-12

    申请号:US16302466

    申请日:2017-05-19

    Applicant: BASF SE

    Abstract: Disclosed are aqueous dispersions (A), comprising a micronized organic UV filter (a) selected from (a1) the micronized compound of formula (1), wherein R1 and R2 independently from each other are C1-C20alkyl; C2-C20alkenyl; C3-C10ocycloalkyl; C3-C10cycloalkenyl; or R1 and R2 together with the linking nitrogen atom form a 5- or 6-membered heterocyclic ring; A is —N(R3)—; —O—; or the direct bond; B is a bivalent radical selected from alkylene, cycloalkylene alkenylene or phenylene radical which is optionally substituted by a carbonyl- or carboxy group; a radical of formula *—CH2—C≡═C—CH2—; or the divalent radical *-B-* corresponds to the formula (1a), wherein n1 is a number from 1 to 3; A is —N(R3)—; or —O—; and R3 is hydrogen; C1-C5alkyl; or hydroxy-C1-C5alkyl; (a2) the micronized compound of formula (2), wherein T1 is hydrogen; C1-C12alkyl; preferably iso-octyl, or C1-C4alkyl substituted by phenyl; (a3) the micronized compound of formula (3a); wherein R4 and R5 independently from each other are hydrogen; C1-C18alkyl; or C6-C12acryl; R6, R7 and R8 independently from each other, are hydrogen; C1-C18alkyl; or a radical of formula (3b); wherein R9, R10 and R11 independently from each other, are hydrogen; or C1-C18alkyl; (a4) the micronized compound of formula (4); wherein R12 and R13, independently from each other, represent hydrogen; halogen; C1-C12alkyl: C1-C18hydroxy; C1-C18alkoxy; poly(ethoxy)-alkoxy with a C1-C4 alkyl fragment and an ethoxy number ranging from 1 to 4; C1-C4mono- or dialkyl amino, R14 represents halogen; hydroxy; amino; phenyl which is optionally substituted 1 to 3 times by a hydroxy radical situated at least in a para or phenyl position, possibly 1 to 3 times substituted in an ortho, meta or para position by a C1-C12alkoxy or cyano or C1-C7alkyl-amino group; and (b) a vinylpyrrolidone copolymer or homopolymer.

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