Dinuclear complexes and polymerization catalysts therefrom
    3.
    发明授权
    Dinuclear complexes and polymerization catalysts therefrom 有权
    双核络合物和聚合催化剂

    公开(公告)号:US06235917B1

    公开(公告)日:2001-05-22

    申请号:US09234192

    申请日:1999-01-20

    IPC分类号: C07F1700

    摘要: Group 3-6 or Lanthanide metal complexes possessing two metal centers joined by means of a divalent bridging group joining trivalent moieties comprising boron or a member of Group 14 of the Periodic Table of the Elements, and optionally also comprising nitrogen, phosphorus, sulfur or oxygen, in the complexes, catalysts derived therefrom by combining the same with strong Lewis acids, Bronsted acid salts, salts containing a cationic oxidizing agent or subjected to bulk electrolysis in the presence of compatible, inert non-coordinating anions and the use of such catalysts for polymerizing olefins, diolefins and/or acetylenically unsaturated monomers are disclosed.

    摘要翻译: 具有两个金属中心的第3-6族或镧系元素金属络合物通过连接包含硼或元素周期表第14族成员的三价基团的二价桥连基团连接,并且任选还包含氮,磷,硫或氧 在络合物中,通过将其与强路易斯酸,布朗斯台德酸盐,含有阳离子氧化剂的盐或在相容的惰性非配位阴离子存在下进行本体电解,并将其用于 公开了烯烃,二烯烃和/或炔属不饱和单体的聚合。