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公开(公告)号：US06344158B1
公开(公告)日：2002-02-05
申请号：US09496023
申请日：2000-01-29
申请人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
发明人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
IPC分类号： C09K2100
CPC分类号： C08K5/5313 , C08K5/34928
摘要： The invention relates to a flame retardant combination for thermoplastic polymers comprising, as component A, a salt of 1-hydroxydihydrophosphole oxides of formula (Ia) or formula (Ib) and/or 1-hydroxyphospholane oxides of formula (II), and, as component B, a synthetic inorganic compound and/or a mineral product.
摘要翻译： 本发明涉及用于热塑性聚合物的阻燃剂组合物，其包含作为组分A的式（Ia）或式（Ib）的1-羟基二氢氧化物的盐和/或式（II）的1-羟基乙氧基氧化物的盐，以及作为 组分B，合成无机化合物和/或矿物产物。
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公开(公告)号：US20130210968A1
公开(公告)日：2013-08-15
申请号：US13878167
申请日：2011-10-25
申请人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser , Bernd Nass
发明人： Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser , Bernd Nass
IPC分类号： C08K5/5399 , C08K5/3492
CPC分类号： C08K5/5399 , C08K5/3492 , C08K5/34922 , C08K5/53
摘要： The invention relates to flame-retardant polyester compounds comprising as component A 40% to 89.9% by weight of thermoplastic polyesters, as component B 5% to 25% by weight of phosphinic salt of the formula (V) and/or diphosphinic salt of the formula (VI) and/or polymers thereof, in which R1 and R2 are H or C1-C6-alkyl and/or aryl; R3 is C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; and x is 1 to 4, and as component C 5% to 25% by weight of a phosphazene, as component D 0% to 15% by weight of reaction products of melamine with phosphoric acid and/or condensed phosphoric acids, as component E 0% to 45% by weight of reinforcing agents, and as component F 0.1% to 3% by weight of further additives, the sum of the components by weight being 100% by weight.
摘要翻译： 本发明涉及阻燃聚酯化合物，其包含作为组分A 40％至89.9％重量的热塑性聚酯，作为组分B 5％至25％重量的式（V）的次膦酸盐和/或二 式（VI）和/或其聚合物，其中R 1和R 2是H或C 1 -C 6 - 烷基和/或芳基; R3是C1-C10-亚烷基，C6-C10-亚芳基， - - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分C 5〜25重量％的磷腈，作为成分D的组分D为0〜15重量％的三聚氰胺与磷酸和/或缩合磷酸的反应产物，作为组分E 0〜45重量％的增强剂，作为成分F为0.1〜3重量％的其他添加剂，其重量份数为100重量％。
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公开(公告)号：US20050173684A1
公开(公告)日：2005-08-11
申请号：US10625281
申请日：2003-07-23
申请人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
发明人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
IPC分类号： C08K5/3492 , C08K5/5313 , C08L85/02 , C08L101/00 , C09K21/12 , C09K21/14 , C08K5/53 , C08J3/00 , C08L1/00 , C09K21/04
CPC分类号： C08K5/34928 , C08K5/5313 , C09K21/12
摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.
摘要翻译： 本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或这些的聚合物，其中R 1和 R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐， 黑夜和/或混战。
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公开(公告)号：US06547992B1
公开(公告)日：2003-04-15
申请号：US09496025
申请日：2000-01-29
申请人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
发明人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
IPC分类号： C09K2100
CPC分类号： C08K5/34928 , C08K5/5313
摘要： The invention relates to a flame retardant combination for thermoplastic polymers comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M are calcium ions, aluminum ions and/or zinc ions; m is 2 or 3; n is 1 or 3; x is 1 or 2, and, as component B, a synthetic inorganic compound and/or a mineral product.
摘要翻译： 本发明涉及热塑性聚合物的阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其它R 1和R 2的聚合物相同或不同，并且是 C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是钙离子，铝离子和/或锌 离子; m为2或3; n为1或3; x为1或2，作为组分B的合成无机化合物和/或矿物产物。
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公开(公告)号：US06255371B1
公开(公告)日：2001-07-03
申请号：US09617473
申请日：2000-07-17
申请人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
发明人： Elke Schlosser , Bernd Nass , Wolfgang Wanzke
IPC分类号： C08K534
CPC分类号： C09K21/12 , C08K5/34928 , C08K5/5313 , C09K21/14
摘要： The invention relates to a novel flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, preferably aluminium or zinc; m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising, as component B, condensation products of melamine and/or reaction products of melamine with phosphoric acid and/or reaction products of condensation products of melamine with phosphoric acid and/or comprising a mixture of these. The invention also relates to the use of the abovementioned flame retardant combination, especially in thermoplastic polymers.
摘要翻译： 本发明涉及包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其它R 1和R 2的聚合物相同或不同的C1- 直链或支链的烷基，和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，优选铝或锌; m为2或3; n为1或3; x为1或2; 并且作为组分B包含三聚氰胺和/或三聚氰胺的反应产物与磷酸和/或三聚氰胺与磷酸的缩合产物和/或包含它们的混合物的反应产物的缩合产物。 本发明还涉及上述阻燃剂组合物的用途，特别是在热塑性聚合物中。
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公开(公告)号：US20130190432A1
公开(公告)日：2013-07-25
申请号：US13878145
申请日：2011-09-30
申请人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K5/5313 , C08K5/3492 , C08K5/10 , C08K3/22 , C08K5/5317 , C08K5/56 , C08K5/52 , C08K3/38
CPC分类号： C08K5/5313 , C08K3/22 , C08K3/38 , C08K5/0008 , C08K5/10 , C08K5/34922 , C08K5/34924 , C08K5/52 , C08K5/5317 , C08K5/56
摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
摘要翻译： 一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物 其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％ 含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物 氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。
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公开(公告)号：US06964746B2
公开(公告)日：2005-11-15
申请号：US10459976
申请日：2003-06-12
IPC分类号： C08J3/22 , C07F9/48 , C08K3/02 , C08K5/00 , C08K5/098 , C08K5/10 , C08K5/20 , C08K5/34 , C08K5/5393 , C08L67/02 , C08L77/00 , C08L101/00 , C09K21/10 , C08K5/49 , C08K5/51 , C09K15/32 , C09K21/12
摘要： The invention relates to mixtures of phosphonite (component A) and/or an ester and/or salt of a long-chain fatty acid (component B), and/or a carboxylic ester, and/or carboxylic amide (component C), and also to their use in polyamides or in polyesters.
摘要翻译： 本发明涉及亚磷酸酯（组分A）和/或长链脂肪酸（组分B）和/或羧酸酯和/或羧酰胺（组分C）的酯和/或盐的混合物，和 也用于聚酰胺或聚酯。
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公开(公告)号：US20050014874A1
公开(公告)日：2005-01-20
申请号：US10890366
申请日：2004-07-13
CPC分类号： C08K5/0066 , C08K5/5313 , C08L77/00 , C08L77/02 , C08L77/06 , C08L77/10 , C08L2666/84
摘要： The invention relates to flame-retardant aromatic or semiaromatic copolyamides comprising, as flame retardant, at least one phosphinic salt of the formula (I), and/or one diphosphinic salt of the formula (II), and/or polymers of these, where R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na; K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4.
摘要翻译： 本发明涉及阻燃芳族或半芳族共聚酰胺，其包含作为阻燃剂的至少一种式（I）的次膦酸盐和/或一种式（II）的二膦酸盐，和/或这些的聚合物，其中 R 1，R 2相同或不同，为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na; K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4。
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公开(公告)号：US09534109B2
公开(公告)日：2017-01-03
申请号：US13809716
申请日：2011-07-06
IPC分类号： C08K13/02 , C08K5/00 , C08K5/16 , C08K5/3492 , C08K5/524 , C08K5/5313
CPC分类号： C08K13/02 , C08K5/0066 , C08K5/16 , C08K5/34922 , C08K5/524 , C08K5/5313
摘要： A flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof, as component B a nitrogen-containing synergist or a phosphorus/nitrogen flame retardant, and as component C a metal oxide coated with a metal salt and/or metal hydroxide coated with a metal salt.
摘要翻译： 作为组分A的作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物作为组分B的含氮增效剂的阻燃稳定剂组合物 或磷/氮阻燃剂，作为组分C，涂覆有被金属盐涂覆的金属盐和/或金属氢氧化物的金属氧化物。
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公开(公告)号：US20130109792A1
公开(公告)日：2013-05-02
申请号：US13809716
申请日：2011-07-06
IPC分类号： C08K13/02
CPC分类号： C08K13/02 , C08K5/0066 , C08K5/16 , C08K5/34922 , C08K5/524 , C08K5/5313
摘要： Flame retardant-stabilizer combination for thermoplastic polymersThe invention relates to a flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 30 to 79.9% by weight of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each H, C1-C18-alkyl, C6-C18-aryl, C7-C18-arylalkyl and/or C7-C18-alkylaryl; R3 is linear or branched C1-C10-alkylene, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 20 to 50% by weight of a nitrogen-containing synergist or of a phosphorus/nitrogen flame retardant and as component C 0.1 to 20% by weight of a metal oxide and/or metal hydroxide coated with a metal salt, component C comprising 50 to 95% by weight of metal oxide and/or metal hydroxide and 5 to 50% by weight of metal salt and the sum of components A to C always being 100% by weight.
摘要翻译： 用于热塑性聚合物的阻燃稳定剂组合物本发明涉及一种用于热塑性聚合物的阻燃剂 - 稳定剂组合物，其包含作为组分A 30至79.9重量％的式（I）的次膦酸盐和/或二 其中R 1，R 2相同或不同并且各自为H，C 1 -C 18 - 烷基，C 6 -C 18 - 芳基，C 7 -C 18 - 芳烷基和/或C 7 -C 18烷基芳基的式（II）和/或其聚合物 ; R3是直链或支链C1-C10-亚烷基，C6-C10-亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，作为组分B 20至50重量％的含氮增效剂或磷/氮阻燃剂和作为组分C的0.1至20重量％的涂覆有金属氧化物和/或金属氢氧化物的组分 金属盐，包含50-95重量％的金属氧化物和/或金属氢氧化物和5-50重量％的金属盐的组分C，组分A至C的总和总是100重量％。
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