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公开(公告)号：US6031015A
公开(公告)日：2000-02-29
申请号：US682327
申请日：1996-07-17
IPC分类号： A61C13/23 , A61K6/083 , C07C69/54 , C07C69/92 , C07J9/00 , C08F2/50 , C08F20/26 , C08F20/30 , C08G63/181 , C08G63/19 , C09J4/00 , C09J4/02 , C09K19/20 , C09K19/36 , C08K9/06 , C08L67/07
CPC分类号： A61K6/083 , C07C69/92 , C09K19/2007 , C09K19/36 , C09K2019/0448 , Y10S522/908
摘要： A dental material based on polymerizable monomers is described which contains at least one polymerizable monomer which has liquid crystalline properties. Compared with traditional materials, the dental material displays a lower decrease in volume upon polymerization and, because of its low viscosity, higher filler contents can be achieved.
摘要翻译： 描述了基于可聚合单体的牙科材料，其含有至少一种具有液晶性质的可聚合单体。 与传统材料相比，牙科材料在聚合时体积减小，粘度低，可以实现更高的填料含量。
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公开(公告)号：US20140371341A1
公开(公告)日：2014-12-18
申请号：US14343300
申请日：2012-09-10
申请人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
发明人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
IPC分类号： A61K6/083 , C07D239/47 , C08F122/22 , C07F3/06
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3— or —NR3—CO—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical, k and l in each case independently are 0, 1, 2 or 3 and m and n in each case independently are 1, 2 or 3.
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公开(公告)号：US20050165129A1
公开(公告)日：2005-07-28
申请号：US10928540
申请日：2004-08-27
IPC分类号： A61K6/093 , C08F290/06 , C08G77/20 , C09D183/04 , A61K6/08
CPC分类号： C09D183/04 , A61K6/0017 , Y10S522/908 , C08L83/16
摘要： Polymerizable materials which contain (1) 1 to 80 wt.-% of at least one polysiloxane, (2) 0.1 to 5 wt.-% of one or more initiators for radical polymerization, (3) 0 to 60 wt.-% of radically polymerizable monomer and (4) 1 to 50 wt.-% of one or more radically polymerizable monomers which carry at least phosphonic acid group, sulphonic acid group and/or mono- or dihydrogen phosphoric acid ester group, the polysiloxane (1), the monomer (3) or both being substituted by fluorine. The materials are suitable in particular for the coating of natural or artificial teeth.
摘要翻译： 含有（1）1至80重量％的至少一种聚硅氧烷的可聚合材料，（2）0.1至5重量％的一种或多种用于自由基聚合的引发剂，（3）0至60重量％ 可自由基聚合的单体和（4）1至50重量％的至少携带膦酸基，磺酸基和/或单或二氢磷酸酯基的一种或多种可自由基聚合的单体，聚硅氧烷（1）， 单体（3）或两者均被氟取代。 这些材料特别适用于天然或人造牙齿的涂层。
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公开(公告)号：US06281271B1
公开(公告)日：2001-08-28
申请号：US09296340
申请日：1999-04-22
申请人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
发明人： André Rumphorst , Ulrich Salz , Alexandros Gianasmidis , Thomas Völkel , Volker Rheinberger , Norbert Moszner
IPC分类号： A61K6083
CPC分类号： A61K6/083 , A61K6/0023 , A61K6/005 , A61K6/0073 , C08L33/00
摘要： The invention relates to a dental material with at least one polymerizable binder and at least one filler containing a redox-initiator system for the radical polymerization, which comprises an initiator and an activator. The material is characterized in that the filler contains a homogeneous mixture of a first part of the filler, which is mixed with the initiator, a second part of the filler, which is mixed with the activator, and a third part of the filler, which does not contain a component of the initiator system. The materials are particularly suitable as cements and filling materials.
摘要翻译： 本发明涉及具有至少一种可聚合粘合剂和至少一种含有用于自由基聚合的氧化还原引发剂体系的填料的牙科材料，其包含引发剂和活化剂。 该材料的特征在于填料含有与引发剂混合的填料的第一部分，与活化剂混合的填料的第二部分和填料的第三部分的均匀混合物，其中 不包含引发剂体系的组分。 这些材料特别适合作为水泥和填充材料。
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公开(公告)号：US09320686B2
公开(公告)日：2016-04-26
申请号：US14343300
申请日：2012-09-10
申请人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
发明人： Norbert Moszner , Thomas Hirt , Kai Rist , Ulrich Salz , Christoph Weder , Gina Fiore , Christian Heinzmann , Volker Rheinberger
IPC分类号： A61K6/083 , A61C7/00 , A61K6/00 , C07D239/47 , C07F3/06 , C08F122/22
CPC分类号： A61K6/0835 , A61K6/0002 , A61K6/0023 , A61K6/083 , C07D239/47 , C07F3/06 , C08F122/22 , C08L33/00
摘要： The invention relates to a dental restorative material which comprises a thermolabile compound of Formula I: [(Z1)m-Q1-X)]k-T-[Y-Q2-(Z2)n]l Formula I, in which T represents a thermolabile unit which contains at least one thermolabile group based on non-covalent interactions, Z1 and Z2 in each case independently represent a polymerizable group selected from vinyl groups, CH2═CR1—CO—O— and CH2═CR1—CO—NR2— or an adhesive group selected from —Si(OR)3, —COOH, —O—PO(OH)2, —PO(OH)2, —SO2OH and —SH, Q1 in each case independently is missing or represents an (m+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, Q2 in each case independently is missing or represents an (n+1)-valent linear or branched aliphatic C1-C20 radical which can be interrupted by —O—, —S—, —CO—O—, —O—CO—, —CO—NR3—, —NR3—CO—, —O—CO—NR3—, —NR3—CO—O— or —NR3—CO—NR3—, X and Y in each case independently are missing or represent —O—, —S—, CO—O—, —O—CO—, —CO—NR3— or —NR3—CO—, R, R1, R2 and R3 in each case independently represent H or a C1-C7 alkyl radical, k and l in each case independently are 0, 1, 2 or 3 and m and n in each case independently are 1, 2 or 3.
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公开(公告)号：US07851515B2
公开(公告)日：2010-12-14
申请号：US11212065
申请日：2005-08-25
申请人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
发明人： Ulrich Salz , Angela Mucke , Jorg Zimmermann , Norbert Moszner , Frank Zeuner , Volker Rheinberger
IPC分类号： C07F9/06 , C07F9/113 , C07F9/143 , A61K6/083 , A61K6/08 , A61K6/00 , A61C5/00 , C08F20/58 , C08F220/54
CPC分类号： A61K6/083 , A61K6/0017 , A61K6/0023 , A61K6/0835 , C08L33/00
摘要： Dental composition containing (i) at least one acid (meth)acrylamide monomer which has two or more polymerizable groups, (ii) at least one acid monomer which has only one polymerizable group and (iii) at least one polymerization initiator.
摘要翻译： 含有（i）至少一种具有两个或多个可聚合基团的酸（甲基）丙烯酰胺单体，（ii）至少一种仅具有一个可聚合基团的酸单体和（iii）至少一种聚合引发剂）的牙科组合物。
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7.发明申请公开(公告)号：US20060135719A1
公开(公告)日：2006-06-22
申请号：US11211938
申请日：2005-08-25
申请人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
发明人： Norbert Moszner , Iris Lamparth , Frank Zeuner , Ulrich Salz , Angela Mucke , Jorg Zimmermann , Jorg Angermann , Volker Rheinberger
IPC分类号： C08F120/54
CPC分类号： A61K6/0017 , A61K6/0023 , A61K6/0029 , A61K6/083 , A61K6/09 , C08L33/26 , C08L33/04 , C08L75/04
摘要： Polymerizable dental material, characterized in that it contains at least one (meth)acrylamide phosphate of the following general formula (I): in which R1 is H or CH3; R2 is H or a C1-C4 alkyl radical or forms together with the nitrogen atom to which it is bonded and one or more atoms which belong to R3 or R3′ a heterocyclic ring; R3, R3′ independently of each other are a linear or branched aliphatic C1-C50 radical with a valency of m+n or p+n, an aromatic C6-C18 radical with a valency of m+n or p+n, or a cycloaliphatic, araliphatic or heterocyclic C3-C18 radical with a valency of m+n or p+n, wherein the carbon chains of the radical or radicals can be interrupted by O, S, CONR4, OCONH, or form together with one or more atoms which belong to R2 and the nitrogen atom, to which the R2 is bonded a heterocyclic ring, R3′ being H if p=0, and R4 being H, C1-C10 alkyl, C6-C12 aryl, C6-C10 aralkyl or a bicylic C4-C12 radical; n is 1, 2, 3 or 4 if p=0, and is 1 or 2 if p≠0; m is 1, 2, 3 or 4; p is 0, 1, 2, 3 or 4; x is 0 or S.
摘要翻译： 可聚合的牙科材料，其特征在于它含有至少一种下列通式（I）的（甲基）丙烯酰胺磷酸酯：其中R 1是H或CH 3; R 2是H或C 1 -C 4烷基，或与其键合的氮原子一起形成一个或多个 属于R 3或R 3'杂原子的杂原子; R 3，R 3，R 3'彼此独立地是直链或支链的脂族C 1 -C 50 - 基团 具有m + n或p + n的化合价，m + n或p + n的芳族C 6 -C 18 - 基团，或脂环族基团， 芳烷基或杂环C 3 -C 18 - 基团，其价态为m + n或p + n，其中基团或基团的碳链可以被O， S，CONR 4，OCONH，或与一个或多个属于R 2的原子和氮原子一起形成，R 2 O 2 >键合杂环，如果p = 0，则R 3'为H，R 4为H，C 1 -C 3 C 10 -C 12烷基，C 6 -C 12芳基，C 6 -C 10芳烷基或C 6 -C 12烷基 二元C 4 -C 12 - 基团; 如果p = 0，则n为1,2,3或4，如果p <0，则为1或2; m为1,2,3或4; p是0，1，2，3或4; x是0或S.
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公开(公告)号：US06900251B2
公开(公告)日：2005-05-31
申请号：US10606142
申请日：2003-06-25
申请人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
发明人： Norbert Moszner , Ulrich Salz , Frank Zeuner , Jörg Zimmermann , Volker Rheinberger , Jorg Angermann , Urs Karl Fischer
IPC分类号： A61C13/087 , A61K6/00 , A61K6/083 , C07F9/38 , C08F30/02 , C08F220/54 , C08F230/02 , C09J4/00 , C09J4/02 , C09J11/04 , C09J11/06 , A61K8/00 , C07F9/09 , C08F2/46
CPC分类号： A61K6/0023 , A61K6/083 , C07F9/3808 , C08F30/02 , C08L33/00 , C08L43/02 , C08L39/06
摘要： Acrylic ester phosphonic acids of general formula (I), stereoisomers thereof and mixtures of these, wherein n is 1 or 2, on the condition that for n=1 R1 has the meaning and for n=2 R1 has the meaning R2 is a C1 to C12 alkylene radical, C4-C8 cycloalkylene radical or C7 to C15 alkylene phenylene radical; R3 is hydrogen, a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical; and R4, R5, independently of each other, each stand for a C1 to C5 alkyl radical or a C1 to C5 O-alkyl radical.
摘要翻译： 在通式（I）的丙烯酸酯膦酸，其立体异构体和它们的混合物，其中n为1或2，条件是对于n = 1的R 1具有含义，n = 2 R 1具有R 2是C 1至C 12亚烷基的C 1至C 4亚烷基，C 4 C 1 -C 8亚环烷基或C 7至C 15亚烷基亚苯基; R 3是氢，C 1至C 5烷基或C 1至C 6烷基， 5 O - 烷基; 和R 4，R 5，R 5彼此独立地代表C 1至C 5烷基 自由基或C 1至C 5 - O-烷基。
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公开(公告)号：US06353039B1
公开(公告)日：2002-03-05
申请号：US09209905
申请日：1998-12-11
申请人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
发明人： Volker Rheinberger , Ulrich Salz , Wolfram Höland , André Rumphorst , Kurt Grabher , Urs Karl Fischer , Marcel Schweiger , Norbert Moszner
IPC分类号： A61K6083
摘要： A composite material is described which contains polymerizable monomers plus a special transparent glass having high release of calcium ions and fluorine ions and, because of this release property and in particular of its optical properties, can be used as a restoration material in dentistry.
摘要翻译： 描述了一种复合材料，其包含可聚合单体加上具有高释放的钙离子和氟离子的特殊透明玻璃，并且由于该释放性质，特别是其光学性质，可用作牙科中的修复材料。
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公开(公告)号：US5703249A
公开(公告)日：1997-12-30
申请号：US548104
申请日：1995-10-25
IPC分类号： C07D321/06 , A61C13/00 , A61C13/23 , A61K6/00 , A61K6/08 , A61K6/087 , C07D321/10 , C07D493/04 , C07D493/10 , C07D493/20 , C08G63/00 , C08L67/00 , C07D317/44 , C07D317/72
CPC分类号： C07D493/04 , A61K6/0023 , A61K6/087 , C07D493/10
摘要： The present invention relates to novel bicycloaliphatic 2-methylene-1,3-dioxepanes, which are suitable as starting materials for the preparation of polymers and copolymers, preferably of composite and dental materials. The 2-methylene-1,3-dioxepanes according to the invention, which can undergo radical polymerisation with ring opening with only very little volume shrinkage, can be prepared in a simple manner, are easy to purify and to modify chemically, and are characterised by lack of odour and advantageous physical properties.
摘要翻译： 本发明涉及新的双环脂族2-亚甲基-1,3-二氧杂环庚烯，它们适合作为制备聚合物和共聚物的起始材料，优选为复合材料和牙科材料。 根据本发明的2-亚甲基-1,3-二氧杂环庚烯可以以简单的方式制备，其可以以仅具有非常小的体积收缩率的开环进行自由基聚合，易于化学纯化和修饰，并且被表征 缺乏气味和有利的物理特性。
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