公开(公告)号：US20220062873A1

公开(公告)日：2022-03-03

申请号：US17415059

申请日：2019-12-10

Applicant: IFP Energies Nouvelles

Inventor： Elodie DEVERS ,  Etienne GIRARD ,  Philibert LEFLAIVE

IPC: B01J23/94 ,  B01J23/00 ,  B01J23/882 ,  B01J27/19 ,  B01J27/28 ,  B01J37/02 ,  B01J37/20 ,  B01J38/12 ,  B01J38/62 ,  B01J35/10 ,  C10G45/08

Abstract: The invention relates to a process for the rejuvenation of an at least partially spent catalyst resulting from a hydrotreating process, said at least partially spent catalyst resulting from a fresh catalyst comprising a metal from group VIII, a metal from group VIb, an oxide support, and optionally phosphorus, said at least partially spent catalyst additionally comprising carbon in a content of between 2% and 20% by weight, with respect to the total weight of the at least partially spent catalyst, and sulfur in a content of between 1% and 8% by weight, with respect to the total weight of the at least partially spent catalyst, said process comprising the following stages: a) said spent catalyst is brought into contact with an impregnation solution containing a compound comprising a metal from group VIb, b) a drying stage is carried out at a temperature of less than 200° C.

公开(公告)号：US20240010932A1

公开(公告)日：2024-01-11

申请号：US18036541

申请日：2021-11-18

Applicant: IFP Energies nouvelles

Inventor： Elodie DEVERS ,  Etienne GIRARD ,  Philibert LEFLAIVE

IPC: C10G45/08 ,  B01J21/18 ,  B01J27/19 ,  B01J23/882 ,  B01J35/10 ,  B01J37/02 ,  B01J37/20

CPC classification number: C10G45/08 ,  B01J21/18 ,  B01J27/19 ,  B01J23/882 ,  B01J35/1014 ,  B01J35/1019 ,  B01J37/0201 ,  B01J37/0236 ,  B01J37/20 ,  C10G2300/104 ,  C10G2300/202 ,  C10G2400/02

Abstract: The invention relates to a method for capturing organometallic impurities in a gasoline-type hydrocarbon feedstock containing sulfur compounds and olefins, wherein said feedstock is brought into contact with hydrogen and a capture mass comprising a nickel-based active phase, and a mesoporous and macroporous alumina substrate having a bimodal distribution of mesopores and wherein: —the volume of mesopores having a diameter greater than or equal to 2 nm and less than 18 nm corresponds to between 10 and 30% by volume of the total pore volume of said substrate; —the volume of mesopores with a diameter greater than or equal to 18 nm and less than 50 mm corresponds to between 30 and 50% by volume of the total pore volume of said substrate; the volume of macropores having a diameter greater than or equal to 50 nm and less than 8000 mm corresponds to between 30 and 50% by volume of the total pore volume of said substrate.

公开(公告)号：US20240042423A1

公开(公告)日：2024-02-08

申请号：US18266661

申请日：2021-12-02

Applicant: IFP ENERGIES NOUVELLES

Inventor： Elodie DEVERS

IPC: B01J38/48 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  B01J37/28 ,  B01J37/20 ,  B01J27/19 ,  B01J27/28 ,  B01J21/04 ,  C10G47/20

CPC classification number: B01J38/485 ,  B01J38/02 ,  B01J38/12 ,  B01J38/62 ,  B01J37/28 ,  B01J37/20 ,  B01J27/19 ,  B01J27/285 ,  B01J21/04 ,  C10G47/20

Abstract: The invention relates to a process for rejuvenating an at least partially spent hydrotreating and/or hydrocracking catalyst, said catalyst comprising a group VIII metal, a group VIB metal and an oxide support, said process comprising the following steps:



a) the catalyst is regenerated,
b) said regenerated catalyst is then brought into contact with an impregnation solution consisting of a mixture of water, at least one precursor of a group VIB metal, at least one precursor of a group VIII metal and at least one organic compound, the amount of organic compound introduced into the regenerated catalyst being optimized with respect to the metals already present in the regenerated catalyst and with respect to the amount of metals introduced via the impregnation solution,
c) a drying step is then carried out without subsequently calcining it.

公开(公告)号：US20130261357A1

公开(公告)日：2013-10-03

申请号：US13851258

申请日：2013-03-27

Applicant: IFP ENERGIES NOUVELLES

Inventor： Antoine DAUDIN ,  Elodie DEVERS ,  Julien Gornay ,  Philibert LEFLAIVE

IPC: C07C7/163 ,  C07C5/13

CPC classification number: C07C7/163 ,  B01J23/28 ,  B01J23/30 ,  B01J23/745 ,  B01J23/75 ,  B01J23/755 ,  B01J23/883 ,  B01J35/1019 ,  B01J35/1038 ,  B01J37/0201 ,  B01J37/20 ,  C07C5/13 ,  C10G29/205 ,  C10G45/04 ,  C10G45/06 ,  C10G45/08 ,  C10G45/38 ,  C10G45/60 ,  C10G65/043 ,  C10G65/06 ,  C10G2300/104 ,  C10G2300/1088 ,  C10G2300/202 ,  C10G2400/02

Abstract: The present application relates to a process for the selective hydrogenation of a gasoline which contains polyunsaturated compounds and sulphurous light compounds, the process allowing conjointly the hydrogenation of polyunsaturated compounds into mono-unsaturated compounds, increasing weight of the sulphurous light compounds by reaction with the unsaturated compounds, and maximisation of the isomerisation of the monounsaturated compounds comprising an external C═C double bond into their internal C═C double bond isomer, said process implementing a catalyst containing at least one group VIb metal and at least one group VIII metal deposited on a porous support.

Abstract translation: 本申请涉及一种含有多不饱和化合物和亚硫酸化合物的汽油的选择性氢化方法，该方法允许将多不饱和化合物氢化成单不饱和化合物，通过与不饱和化合物的反应来增加硫化轻质化合物的重量 化合物，以及将包含外部C = C双键的单不饱和化合物异构化到其内部C = C双键异构体中的最大化，所述方法实施含有至少一种VIb族金属和至少一种VIII族金属的催化剂，其沉积在 多孔支撑。

公开(公告)号：US20230038342A1

公开(公告)日：2023-02-09

申请号：US17783684

申请日：2020-12-01

Applicant: IFP Energies Nouvelles

Inventor： Elodie DEVERS ,  Audrey BONDUELLE-SKRZYPCZAK ,  Mona Marie OBADIA

IPC: C25B11/054 ,  C25B1/04 ,  C25B11/052 ,  C25B11/065 ,  C25B11/075 ,  C25B11/091

Abstract: A process for preparing a catalytic material of an electrode for electrochemical reduction reactions, said material comprising an active phase based on at least one group VIB metal and an electrically conductive support, which process is carried out according to at least the following steps:
a) bringing water into contact with said electrically conductive support, b) bringing said wet support into contact with at least one metallic acid hydrate comprising at least one group VIB metal, of which the melting point of said metallic acid hydrate is between 20° C. and 100° C., the weight ratio of said metallic acid to said electrically conductive support being between 0.1 and 4, c) heating, with stirring, to a temperature between the melting point of said metallic acid hydrate and 100° C., d) carrying out a sulfurization step at a temperature of between 100° C. and 600° C.

公开(公告)号：US20220062874A1

公开(公告)日：2022-03-03

申请号：US17414209

申请日：2019-12-10

Applicant: IFP Energies nouvelles

Inventor： Elodie DEVERS

IPC: B01J27/28 ,  B01J27/19 ,  B01J21/04 ,  B01J38/12 ,  B01J38/02 ,  B01J38/62 ,  C10G45/08 ,  C10G47/12

Abstract: The invention concerns a method for rejuvenating an at least partially used catalyst originating from a hydroprocessing and/or hydrocracking process, the at least partially used catalyst being derived from a fresh catalyst comprising at least one group VIII metal (in particular, Co), at least one group VIB metal (in particular, Mo), an oxide support, and optionally phosphorus, the method comprising the steps: a) regenerating the at least partially used catalyst in a gas stream containing oxygen at a temperature between 300° C. and 550° C. so as to obtain a regenerated catalyst, b) then placing the regenerated catalyst in contact with phosphoric acid and an organic acid, each having acidity constant pKa greater than 1.5, c) performing a drying step at a temperature less than 200° C. without subsequently calcining it, so as to obtain a rejuvenated catalyst.

公开(公告)号：US20240009655A1

公开(公告)日：2024-01-11

申请号：US18267371

申请日：2021-12-02

Applicant: IFP Energies nouvelles

Inventor： Elodie DEVERS ,  Pierre-louis CARRETTE ,  Philibert LEFLAIVE ,  Marine MINIERE

IPC: B01J27/19 ,  B01J37/20 ,  B01J37/02 ,  B01J38/04 ,  B01J38/02 ,  B01J27/28 ,  B01J21/04

CPC classification number: B01J27/19 ,  B01J37/20 ,  B01J37/0203 ,  B01J38/04 ,  B01J38/02 ,  B01J27/285 ,  B01J21/04

Abstract: The present invention relates to a process for the production of a recycled catalyst comprising at least one metal M1 from group VI B, and/or at least one metal M2 from group VIII, optionally phosphorus and/or sulfur, and a support based on oxide(s). The process comprises the recycling of at least a part of the metal or metals of a source catalyst comprising the metal M1 and/or the metal M2 common with the recycled catalyst to be produced, with:



an extraction by an extraction solution of the metal M1 and/or of the metal M2 from said source catalyst, in order to obtain a solution of extracted metal/metals, then—an impregnation of the support with an impregnation solution resulting from said solution of extracted metal/metals, in order to obtain an impregnated substrate, said extracted metal(s) remaining in the liquid phase from the extraction until the impregnation.

公开(公告)号：US20220081627A1

公开(公告)日：2022-03-17

申请号：US17414437

申请日：2019-12-10

Applicant: IFP Energies Nouvelles

Inventor： Elodie DEVERS ,  Philibert LEFLAIVE ,  Etienne GIRARD

IPC: C10G45/08 ,  B01J21/04 ,  C10G65/12 ,  B01J35/10 ,  B01J23/882 ,  B01J38/12

Abstract: The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a regenerated catalyst are brought into contact, said process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 h−1; and a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said regenerated catalyst resulting from an at least partially spent catalyst resulting from a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut and comprises at least one metal from group VIII, at least one metal from group VIb and an oxide support.

公开(公告)号：US20220056348A1

公开(公告)日：2022-02-24

申请号：US17414878

申请日：2019-12-10

Applicant: IFP Energies nouvelles

Inventor： Elodie DEVERS ,  Etienne GIRARD ,  Philibert LEFLAIVE

IPC: C10G45/08 ,  B01J23/94 ,  B01J37/02 ,  B01J35/10 ,  B01J37/20

Abstract: The invention relates to a process for the hydrodesulfurization of a sulfur-containing olefinic gasoline cut in which said gasoline cut, hydrogen and a rejuvenated catalyst are brought into contact, said hydrodesulfurization process being carried out at a temperature of between 200° C. and 400° C., a total pressure of between 1 and 3 MPa, an hourly space velocity, defined as being the flow rate by volume of feedstock relative to the volume of catalyst, of between 1 and 10 h−1 and a hydrogen/gasoline feedstock ratio by volume of between 100 and 1200 Sl/l, said rejuvenated catalyst resulting from a hydrotreating process and comprises at least one metal from group VIII, at least one metal from group VIb, an oxide support and at least one organic compound containing oxygen and/or nitrogen and/or sulfur.

公开(公告)号：US20170137724A1

公开(公告)日：2017-05-18

申请号：US15318587

申请日：2015-06-09

Applicant: IFP Energies nouvelles

Inventor： Malika BOUALLEG ,  Elodie DEVERS ,  Bertrand GUICHARD

IPC: C10G45/08 ,  B01J21/04 ,  B01J35/10 ,  B01J27/19

CPC classification number: C10G45/08 ,  B01J21/04 ,  B01J23/002 ,  B01J23/882 ,  B01J23/883 ,  B01J23/888 ,  B01J23/8885 ,  B01J27/188 ,  B01J27/19 ,  B01J35/002 ,  B01J35/023 ,  B01J35/026 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/1071 ,  B01J35/1076 ,  B01J37/0009 ,  B01J37/0201 ,  B01J37/036 ,  B01J37/20 ,  B01J2523/00 ,  C10G2300/1059 ,  B01J2523/25 ,  B01J2523/31 ,  B01J2523/3712 ,  B01J2523/48 ,  B01J2523/51 ,  B01J2523/68 ,  B01J2523/821 ,  B01J2523/845

Abstract: There is described a hydroprocessing process of at least one gas oil cut having a weighted mean temperature (TMP) between 240° C. and 350° C. using a catalyst comprising at least one metal of the group VIB and/or at least one metal of the group VIII of the periodic classification and a support comprising an amorphous mesoporous alumina having a connectivity (Z) greater than 2.7, the hydroprocessing process operating at a temperature between 250° C. and 400° C., at a total pressure between 2 MPa and 10 MPa with a ratio of hydrogen volume to volume of hydrocarbon-containing feedstock between 100 and 800 litres per litre and at an Hourly Volume Rate (HVR) which is defined by the ratio of the volume flow rate of liquid hydrocarbon-containing feedstock to volume of catalyst fed into the reactor between 1 and 10 h−1.