公开(公告)号：US20150182947A1

公开(公告)日：2015-07-02

申请号：US14573177

申请日：2014-12-17

Applicant: Ivy D. Johnson ,  Tilman W. Beutel ,  Peter I. Ravikovitch ,  Harry W. Deckman ,  Jack W. Johnson ,  Jean W. Beeckman ,  Natalie A. Fassbender ,  Nadya A. Hrycenko ,  Randy J. Smiley

Inventor： Ivy D. Johnson ,  Tilman W. Beutel ,  Peter I. Ravikovitch ,  Harry W. Deckman ,  Jack W. Johnson ,  Jean W. Beeckman ,  Natalie A. Fassbender ,  Nadya A. Hrycenko ,  Randy J. Smiley

IPC: B01J20/30 ,  B01J20/18 ,  B01J20/282 ,  C01B39/04

CPC classification number: B01J20/3078 ,  B01D53/02 ,  B01D2253/108 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/186 ,  B01J20/282 ,  B01J20/30 ,  B01J20/3085 ,  B01J29/035 ,  B01J29/70 ,  B01J2220/80 ,  B01J2229/36 ,  B01J2229/40 ,  C01B37/02 ,  C01B39/026 ,  C01B39/04 ,  C01B39/48 ,  Y02C10/08 ,  Y02P20/152

Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Additionally, by controlling the ratio of water content to silica content in the synthesis mixture, it has unexpectedly been found that ZSM-58 crystals can be formed with an improved morphology. The improved morphology can result in ZSM-58 crystals with a more uniform size across the various dimensions of the crystal, which allows for more uniform diffusion within the crystal. This is in contrast to conventionally synthesized crystals, where the size of the crystal can vary along different axes of the crystals.

Abstract translation: 提供了用于合成具有改进的形态和/或改进的尺寸分布的ZSM-58晶体的方法。 通过控制合成ZSM-58晶体的条件，可以产生具有窄尺寸分布的有用尺寸的晶体。 另外，通过控制合成混合物中水含量与二氧化硅含量的比例，意外地发现可以形成具有改进的形态的ZSM-58晶体。 改进的形态可以导致在晶体的各种尺寸上具有更均匀尺寸的ZSM-58晶体，这允许在晶体内更均匀的扩散。 这与常规合成的晶体形成对比，其中晶体的尺寸可以沿晶体的不同轴线变化。

公开(公告)号：US07332636B2

公开(公告)日：2008-02-19

申请号：US11581534

申请日：2006-10-16

Applicant: Teng Xu ,  Stephen Neil Vaughn ,  Richard B. Hall ,  Kenneth Ray Clem ,  Jack W. Johnson

Inventor： Teng Xu ,  Stephen Neil Vaughn ,  Richard B. Hall ,  Kenneth Ray Clem ,  Jack W. Johnson

IPC: C07C1/00

CPC classification number: B01J37/0045 ,  B01J29/06 ,  B01J29/85 ,  B01J2229/42 ,  C07C1/20 ,  C07C2521/06 ,  C07C2521/08 ,  C07C2521/10 ,  C07C2521/12 ,  C07C2523/02 ,  C07C2523/10 ,  C07C2529/85 ,  C10G3/45 ,  C10G3/48 ,  C10G3/49 ,  C10G3/56 ,  C10G3/62 ,  C10G2300/1022 ,  C10G2300/708 ,  C10G2300/802 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

Abstract: The invention provides low metal content molecular sieve catalyst compositions, processes for making such catalysts, and processes for using such catalysts in the conversion of an oxygenate into one or more light olefins. Preferably, the catalyst composition comprises a matrix material having a low metal content. By utilizing matrix materials having low metal contents, the amount of metal-catalyzed side reaction byproducts formed in a reaction system, particularly in an oxygenate-to-olefin reaction system, can be advantageously reduced.

Abstract translation: 本发明提供了低金属含量的分子筛催化剂组合物，制备这种催化剂的方法，以及在将含氧化合物转化成一种或多种轻质烯烃时使用这种催化剂的方法。 优选地，催化剂组合物包含具有低金属含量的基质材料。 通过利用具有低金属含量的基质材料，可以有利地减少在反应体系中形成的金属催化的副反应副产物的量，特别是在含氧化合物 - 烯烃反应体系中。

公开(公告)号：US5346871A

公开(公告)日：1994-09-13

申请号：US28442

申请日：1993-03-09

Applicant: John L. Robbins ,  Elise Marucchi-Soos ,  Jack W. Johnson ,  John F. Brody

Inventor： John L. Robbins ,  Elise Marucchi-Soos ,  Jack W. Johnson ,  John F. Brody

IPC: B01J23/60 ,  B01J23/62 ,  B01J29/04 ,  C07C5/32 ,  C07C5/333 ,  B01J21/16 ,  B01J23/06 ,  B01J23/08

CPC classification number: B01J29/049 ,  B01J23/60 ,  B01J23/62 ,  C07C5/325 ,  C07C5/3337

Abstract: The present invention is directed to a novel catalyst composition and its use in the dehydrogenation of paraffins to olefins. The catalyst comprises an alloy of a Group VIII noble metal and a metal selected from the group consisting of zinc and gallium on a support selected from the group consisting of silica, zinc oxide modified silica and zinc oxide modified silica-pillared clays when said alloy is a zinc alloy, and silica, gallium oxide modified silica and gallium oxide modified silica-pillared clays when said alloy is a gallium alloy. The instant catalyst is an active and selective catalyst for the catalytic dehydrogenation of paraffins to olefins, especially gaseous paraffins, having the added benefit of retaining high activity and selectivity even following repeated regeneration by calcination in oxygen containing gas at temperatures of 450.degree. C. to 650.degree. C., preferably 450.degree. C. to 500.degree. C.

Abstract translation: 本发明涉及新型催化剂组合物及其在链烷烃脱氢成烯烃中的应用。 所述催化剂包含由选自二氧化硅，氧化锌改性二氧化硅和氧化锌改性二氧化硅柱状粘土的载体上的第八族贵金属和选自锌和镓的金属的合金，当所述合金为 锌合金，二氧化硅，氧化镓改性二氧化硅和氧化镓改性二氧化硅柱状粘土。 本催化剂是用于将链烷烃催化脱氢成烯烃，特别是气态烷烃的活性和选择性催化剂，具有保持高活性和选择性的附加益处，即使在含氧气体中通过在450℃至450℃的温度下煅烧反复再生， 650℃，优选450℃至500℃

公开(公告)号：US5258567A

公开(公告)日：1993-11-02

申请号：US935503

申请日：1992-08-26

Applicant: Michael C. Kerby ,  Kenneth L. Riley ,  Fred M. Long ,  Jack W. Johnson ,  John F. Brody

Inventor： Michael C. Kerby ,  Kenneth L. Riley ,  Fred M. Long ,  Jack W. Johnson ,  John F. Brody

IPC: C07C5/09 ,  C07C5/32 ,  C07C5/333

CPC classification number: B01J29/049 ,  C07C5/324 ,  C07C5/325 ,  C07C5/3337

Abstract: This invention relates to a process for the dehydrogenation of C.sub.2 -C.sub.10 hydrocarbons at dehydrogenation conditions with a pillared mica catalyst which contains an active metal selected from the group consisting of Pt, Cr and mixtures thereof, and a first modifier metal selected from the group consisting of Sn, Ga and mixtures thereof. The micas may also contain a second modifier metal selected from the group consisting of alkali metals, alkaline earth metals, and rare earth metals, and mixtures thereof.

Abstract translation: 本发明涉及使用含有选自Pt，Cr及其混合物的活性金属的柱撑云母催化剂在脱氢条件下脱氢C2-C10烃的方法和选自以下的第一种改性金属： 的Sn，Ga及其混合物。 云母还可以含有选自碱金属，碱土金属和稀土金属的第二改性金属及其混合物。

公开(公告)号：US4355162A

公开(公告)日：1982-10-19

申请号：US205141

申请日：1980-11-10

Applicant: Jack W. Johnson ,  Allan J. Jacobson

Inventor： Jack W. Johnson ,  Allan J. Jacobson

IPC: H01M4/58 ,  C01B25/37 ,  C01B25/45 ,  C01G31/00 ,  C07D213/18 ,  C07D213/22 ,  C07F9/00 ,  C07F9/02 ,  C07F9/58 ,  C07F9/68 ,  C07F11/00 ,  C08G79/14 ,  H01B1/06 ,  H01M4/60 ,  C07F13/00

CPC classification number: C07F9/02 ,  C07F9/581 ,  C08G79/14

Abstract: A new composition of matter comprising the reaction product of a mixed oxide having layers of corner linked octahedra and tetrahedra and a Lewis base. The reaction product forms a layered compound of the formula L.sub.x MOM'O.sub.4 where MOM'O.sub.4 is a mixed oxide selected from the group consisting of VOPO.sub.4, VOSO.sub.4, VOAsO.sub.4, VOMoO.sub.4, NbOPO.sub.4, NbOAsO.sub.4, TaOPO.sub.4 and MoOPO.sub.4, x is from about 0.1 to 1.0 and L is a Lewis base containing nitrogen or oxygen electron donor and is selected from the group consisting of 5-membered heterocyclic amines, 6-membered heterocyclic amines, amine oxides, triorganophosphates, phosphine oxides and sulfoxides. The layered compounds are characterized in that L is covalently bound to a metal atom in the MOM'O.sub.4 layer.

Abstract translation: 一种新的物质组合物，其包含具有角连接八面体和四面体层的路易斯碱的混合氧化物的反应产物。 反应产物形成式LxMOM'O4的层状化合物，其中MOM'O4是选自VOPO4，VOSO4，VOAsO4，VOMoO4，NbOPO4，NbOAsO4，TaOPO4和MoOPO4的混合氧化物，x为约0.1至1.0 L是含有氮或氧电子给体的路易斯碱，选自5元杂环胺，6元杂环胺，氧化胺，三有机磷酸盐，氧化膦和亚砜。 层状化合物的特征在于L与MOM'O4层中的金属原子共价键合。

公开(公告)号：US09573116B2

公开(公告)日：2017-02-21

申请号：US14573177

申请日：2014-12-17

Applicant: Ivy D. Johnson ,  Tilman W. Beutel ,  Peter I. Ravikovitch ,  Harry W. Deckman ,  Jack W. Johnson ,  Jean W. Beeckman ,  Natalie A. Fassbender ,  Nadya A Hrycenko ,  Randolph J. Smiley

Inventor： Ivy D. Johnson ,  Tilman W. Beutel ,  Peter I. Ravikovitch ,  Harry W. Deckman ,  Jack W. Johnson ,  Jean W. Beeckman ,  Natalie A. Fassbender ,  Nadya A Hrycenko ,  Randolph J. Smiley

IPC: C01B39/02 ,  B01J20/30 ,  C01B39/04 ,  B01J20/18 ,  B01J20/282 ,  B01D53/02 ,  C01B37/02 ,  C01B39/48

CPC classification number: B01J20/3078 ,  B01D53/02 ,  B01D2253/108 ,  B01D2256/245 ,  B01D2257/304 ,  B01D2257/504 ,  B01J20/18 ,  B01J20/186 ,  B01J20/282 ,  B01J20/30 ,  B01J20/3085 ,  B01J29/035 ,  B01J29/70 ,  B01J2220/80 ,  B01J2229/36 ,  B01J2229/40 ,  C01B37/02 ,  C01B39/026 ,  C01B39/04 ,  C01B39/48 ,  Y02C10/08 ,  Y02P20/152

Abstract: Methods are provided for synthesizing ZSM-58 crystals with an improved morphology and/or an improved size distribution. By controlling the conditions during synthesis of the ZSM-58 crystals, crystals of a useful size with a narrow size distribution can be generated. Steaming the H-form DDR framework type crystals at a temperature from 426±° C. to 1100±° C. for a time period from about 30 minutes to about 48 hours can attain one or more of the following properties: a CH4 diffusivity of no more than 95% of the CH4 diffusivity of the unsteamed H-form DDR framework type crystals; an N2 BET surface area from 85% to 110% of the surface area of unsteamed H-form DDR framework type crystals; and an equilibrium CO2 sorption capacity from 80% to 105% of the equilibrium CO2 sorption capacity of unsteamed H-form DDR framework type crystals.

Abstract translation: 提供了用于合成具有改进的形态和/或改进的尺寸分布的ZSM-58晶体的方法。 通过控制合成ZSM-58晶体的条件，可以产生具有窄尺寸分布的有用尺寸的晶体。 在从426℃至1100℃的温度下将H型DDR骨架型晶体蒸馏约30分钟至约48小时的时间段可以获得一种或多种以下性质：CH4扩散系数 不超过95％的未蒸发的H型DDR骨架型晶体的CH4扩散性; N2 BET表面积为未蒸发的H型DDR骨架型晶体的表面积的85％至110％; 和平衡CO2吸附容量从未蒸发的H型DDR骨架型晶体的平衡CO 2吸附容量的80％至105％。

公开(公告)号：US09186626B2

公开(公告)日：2015-11-17

申请号：US14078860

申请日：2013-11-13

Applicant: Daniel P. Leta ,  Jack W. Johnson ,  Ni Zheng ,  Harry W. Deckman

Inventor： Daniel P. Leta ,  Jack W. Johnson ,  Ni Zheng ,  Harry W. Deckman

IPC: B01D53/52 ,  B01D53/62 ,  B01D53/02 ,  B01D53/80

CPC classification number: B01D53/526 ,  B01D53/025 ,  B01D53/52 ,  B01D53/62 ,  B01D53/80 ,  B01D2252/204 ,  B01D2253/202 ,  B01D2253/206 ,  B01D2253/25 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/126 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/08

Abstract: Methods are provided for removing CO2 and/or H2S from a gas phase stream, such as a refinery flue gas stream, a coal-fired or petroleum-burning power plant, or a natural gas stream. A gas phase stream containing CO2 and/or H2S can be contacted under effective conditions with an aqueous slurry of supported amine particles. The CO2 and/or H2S can react with the supported amines to form bicarbonates, carbonates, carbamates, sulfide salts, or other species. Because the amine is part of, bonded to, or otherwise supported on a particulate substrate, the reaction product from the amine reaction can also remain bound to the particle. After reacting supported amines with CO2 and/or H2S captured from a gas stream, the supported amines particles can be separated from the aqueous slurry environment for regeneration of the supported amine and release of the CO2 and/or H2S.

Abstract translation: 提供了用于从气相物流（例如炼油厂烟气，燃煤或石油燃烧发电厂或天然气流）中除去CO 2和/或H 2 S的方法。 含有CO 2和/或H 2 S的气相物流可以在有效条件下与负载的胺颗粒的含水浆液接触。 CO 2和/或H 2 S可以与负载的胺反应形成碳酸氢盐，碳酸盐，氨基甲酸盐，硫化物盐或其它物质。 因为胺是颗粒底物的一部分，结合或以其它方式负载的，胺反应的反应产物也可以保持与颗粒结合。 使支持的胺与从气流中捕获的CO 2和/或H 2 S反应后，负载的胺颗粒可以从水性浆料环境中分离出来，以再生负载的胺和释放二氧化碳和/或硫化氢。

公开(公告)号：US20140161697A1

公开(公告)日：2014-06-12

申请号：US14078860

申请日：2013-11-13

Applicant: Daniel P. Leta ,  Jack W. Johnson ,  Ni Zheng ,  Harry W. Deckman

Inventor： Daniel P. Leta ,  Jack W. Johnson ,  Ni Zheng ,  Harry W. Deckman

IPC: B01D53/52

CPC classification number: B01D53/526 ,  B01D53/025 ,  B01D53/52 ,  B01D53/62 ,  B01D53/80 ,  B01D2252/204 ,  B01D2253/202 ,  B01D2253/206 ,  B01D2253/25 ,  B01D2257/304 ,  B01D2257/504 ,  B01D2258/0283 ,  B01D2259/126 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/08

Abstract: Methods are provided for removing CO2 and/or H2S from a gas phase stream, such as a refinery flue gas stream, a coal-fired or petroleum-burning power plant, or a natural gas stream. A gas phase stream containing CO2 and/or H2S can be contacted under effective conditions with an aqueous slurry of supported amine particles. The CO2 and/or H2S can react with the supported amines to form bicarbonates, carbonates, carbamates, sulfide salts, or other species. Because the amine is part of, bonded to, or otherwise supported on a particulate substrate, the reaction product from the amine reaction can also remain bound to the particle. After reacting supported amines with CO2 and/or H2S captured from a gas stream, the supported amines particles can be separated from the aqueous slurry environment for regeneration of the supported amine and release of the CO2 and/or H2S.

Abstract translation: 提供了用于从气相物流（例如炼油厂烟气，燃煤或石油燃烧发电厂或天然气流）中除去CO 2和/或H 2 S的方法。 含有CO 2和/或H 2 S的气相物流可以在有效条件下与负载的胺颗粒的含水浆液接触。 CO 2和/或H 2 S可以与负载的胺反应形成碳酸氢盐，碳酸盐，氨基甲酸盐，硫化物盐或其它物质。 因为胺是颗粒底物的一部分，结合或以其它方式负载的，胺反应的反应产物也可以保持与颗粒结合。 使支持的胺与从气流中捕获的CO 2和/或H 2 S反应后，负载的胺颗粒可以从水性浆料环境中分离出来，以再生负载的胺和释放二氧化碳和/或硫化氢。

公开(公告)号：US06284127B1

公开(公告)日：2001-09-04

申请号：US09416038

申请日：1999-10-12

Applicant: Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

Inventor： Bruce R. Cook ,  Jack W. Johnson ,  Guang Cao ,  Rich A. McEvoy ,  Richard H. Ernst

IPC: G25

CPC classification number: C10G2/30 ,  C10G2400/10

Abstract: A process for dewaxing waxy hydrocarbonaceous materials, such as hydrocarbon fuel and lubricating oil fractions to reduce their cloud and pour points comprises reacting the material with hydrogen in the presence of a dewaxing catalyst comprising at least one metal catalytic component and ferrierite in which at least a portion of its cation exchange positions are occupied by one or more trivalent rare earth metal cations. The rare earth ion exchanged ferrierite catalyst has good selectivity for lubricating oil production, particularly when dewaxing a Fischer-Tropsch wax hydroisomerate. Preferably at least 10% and more preferably at least 15% of the ferreirite cation exchange capacity is occupied by one or more trivalent rare earth metal cations.

Abstract translation: 用于脱蜡蜡质烃类材料（例如烃燃料和润滑油馏分）以降低其云和倾点的方法包括在包含至少一种金属催化组分和镁碱沸石的脱蜡催化剂存在下使材料与氢反应，其中至少一种 其阳离子交换位置的一部分被一种或多种三价稀土金属阳离子占据。 稀土离子交换的镁碱沸石催化剂对于润滑油生产具有良好的选择性，特别是当脱蜡费 - 托蜡蜡加氢异构体时。 优选地，铁氰化物阳离子交换容量的至少10％，更优选至少15％被一种或多种三价稀土金属阳离子占据。

公开(公告)号：US5248644A

公开(公告)日：1993-09-28

申请号：US867581

申请日：1992-04-13

Applicant: Jack W. Johnson ,  John F. Brody

Inventor： Jack W. Johnson ,  John F. Brody

IPC: B01J21/16 ,  B01D53/86 ,  B01J29/00 ,  B01J29/04 ,  C01B33/26 ,  C01B33/42 ,  C01B39/00

CPC classification number: B01J29/049

Abstract: The present invention is directed to improved zirconia-pillared clays exhibiting high crystallinity and layer spacing and significantly higher thermal stability prepared using zirconyl acetate as the pillaring agent by: (a) mixing a clay selected from the group consisting of smectite clays and fluoromicas with a solution of zirconyl acetate for a time and at a temperature sufficient to form a pillared clay product; (b) separating said pillared clay product formed from the solution; (c) washing the separated pillared clay product with water; (d) drying the separated, washed pillared clay product at a temperature from about 50.degree. to 200.degree. C.; (e) calcining the dried pillared clay product at a temperature from about 300.degree. to 700.degree. C.

Abstract translation: 本发明涉及改进的氧化锆柱状粘土，其表现出高结晶度和层间距，并且使用乙酸氧锆酯作为起始剂制备了显着更高的热稳定性，其方法是：（a）将选自蒙脱石粘土和氟代核的粘土与 乙酸氧锆溶液一段时间并在足以形成柱状粘土产物的温度下进行; （b）分离由溶液形成的柱状粘土产品; （c）用水洗涤分离的柱状粘土产品; （d）在约50℃至200℃的温度下干燥分离的经洗涤的柱状粘土产品; （e）在约300℃至700℃的温度下煅烧干燥的柱状粘土产品。