摘要:
The present invention is directed to a method and system for integrating a catalyst regeneration system with a plurality of hydrocarbon conversion apparatuses, preferably, a plurality of multiple riser reactor units. One embodiment of the present invention is a reactor system including a plurality of reactor units, at least one reactor unit preferably comprising a plurality of riser reactors. The system also includes a regenerator for converting an at least partially deactivated catalyst to a regenerated catalyst. A first conduit system transfers the at least partially deactivated catalyst from the reactor units to the regenerator, and a second conduit system transfers regenerating catalysts from the regenerator to the plurality of reactor units. Optionally, catalysts from a plurality of hydrocarbon conversion apparatuses may be directed to a single stripping unit and/or a single regeneration unit.
摘要:
This invention is directed to removing contaminants from an oxygenate-containing feedstream for an oxygenate to olefin reaction system. Oxygenate feeds used in the conversion of oxygenates to olefins, and which contain contaminants, are heated to form a vapor stream and a liquid stream. The heating is conducted so that a majority of the metalloaluminophosphate molecular sieve catalyst contaminants is contained in the liquid stream. The vapor stream is separated from the liquid stream, and the separated vapor stream is contacted with the metalloaluminophosphate molecular sieve catalyst to form olefin product. The heating of the feedstream and the separation of the vapor stream can be carried out in one or more stages.
摘要:
A process and apparatus for fluidizing a population of catalyst particles having a low catalyst fines content includes a fluidized bed reactor which includes a plurality of catalyst particles in the reactor wherein the catalyst particles having a d2 value of greater than about 40 microns. The catalyst particles are contacted with a fluidizing medium under conditions to fluidize the particles, the reactor includes a continuous reaction zone and separation zone and the fluidized of the catalyst particles are situated within the reaction and both the reaction zone and the separation zone include obstructing members which obstruct the flow of particles such that the catalyst particles can be maintained at an axial gas Peclet number from about 10 to about 20.
摘要:
This invention is directed to removing contaminants from an oxygenate-containing feedstream for an oxygenate to olefin reaction system. Oxygenate feeds used in the conversion of oxygenates to olefins, and which contain contaminants, are heated to form a vapor stream and a liquid stream. The heating is conducted so that a majority of the metalloaluminophosphate molecular sieve catalyst contaminants is contained in the liquid stream. The vapor stream is separated from the liquid stream, and the separated vapor stream is contacted with the metalloaluminophosphate molecular sieve catalyst to form olefin product. The heating of the feedstream and the separation of the vapor stream can be carried out in one or more stages.
摘要:
A feed vaporization process and apparatus for oxygenate to olefin conversion is provided which uses a vapor-liquid disengaging drum to separate non-volatiles and/or partial non-volatiles from volatiles in the oxygenate feed and produce a vaporized effluent that is reduced in non-volatiles and/or partial non-volatiles while at the same time maintaining the effluent at optimal temperature and pressure as a feed for oxygenate to olefin conversion.
摘要:
Disclosed is a method of removing dimethyl ether from an ethylene and/or propylene containing stream. Dimethyl ether is removed at a high pressure, preferably in a distillation column. The high pressure separation has the benefit of providing a relatively low bottoms temperature separation, while allowing for recovery of a highly concentrated ethylene and/or propylene stream.
摘要:
This invention is directed to a method of removing dimethyl ether from an olefin stream. Dimethyl ether is removed from the olefin stream by first separating the olefin stream into a first stream comprising dimethyl ether and lighter boiling point compounds, and a second stream comprising C4+ olefin and higher boiling point hydrocarbons. The dimethyl ether is then separated from the first stream using extractive distillation.
摘要:
The present invention relates to processes for fluidizing a population of catalyst particles that are depleted of catalyst fines. In one embodiment, the process includes providing a plurality of catalyst particles in the reactor, wherein the catalyst particles have a d2 value of greater than about 40 microns. The catalyst particles are contacted with a fluidizing medium under conditions effective to cause the catalyst particles to behave in a fluidized manner and form a fluidized bed. The particles are contacted with one or more primary obstructing members while in the fluidized bed. By fluidizing the catalyst particles in this manner, the catalyst particles can be maintained at an axial gas Peclet number of from about 10 to about 20.
摘要:
The present invention relates to processes for fluidizing a population of catalyst particles that are depleted of catalyst fines. In one embodiment, the process includes providing a plurality of catalyst particles in the reactor, wherein the catalyst particles have a d2 value of greater than about 40 microns. The catalyst particles are contacted with a fluidizing medium under conditions effective to cause the catalyst particles to behave in a fluidized manner and form a fluidized bed. The particles are contacted with one or more primary obstructing members while in the fluidized bed. By fluidizing the catalyst particles in this manner, the catalyst particles can be maintained at an axial gas Peclet number of from about 10 to about 20.
摘要:
The invention concerns methods and systems for minimizing back-mixing of feedstock flow in converting oxygenates to olefins. In one embodiment, back-mixing is reduced by providing a reactor that includes baffles to reduce the hydraulic diameter of at least a portion of the reactor. Some or all of the baffles can also serve as cooling tubes for reducing temperature gradients in the reactor, and thereby maximize light olefin production.