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    Process for the production of a tertiary alkyl ether comprising a fractionation section
    1.
    发明授权
    Process for the production of a tertiary alkyl ether comprising a fractionation section 失效
    制备包含分馏部分的叔烷基醚的方法

    公开(公告)号：US5364975A

    公开(公告)日：1994-11-15

    申请号：US57603

    申请日：1993-05-05

    申请人： Jean-Luc Nocca ,  Phillipe Travers ,  Larry Mank ,  Alain Forestiere

    发明人： Jean-Luc Nocca ,  Phillipe Travers ,  Larry Mank ,  Alain Forestiere

    IPC分类号： B01J31/06 ,  C07B61/00 ,  C07C41/06 ,  C07C41/42 ,  C07C43/04

    CPC分类号： C07C41/42 ,  C07C41/06

    摘要： A process for the preparation of a tertiary alkyl ether, in particular methyl tert. amyl ether (MTAE), is described which comprises reacting, in a reaction section, a charge constituted by a mixture of C.sub.5 hydrocarbons, including reactive isopentenes, with an aliphatic monoalcohol in excess, such as methanol, ethanol, propanol or isopropanol, and collecting in the bottom of a fractionation section the corresponding pure tert. alkyl ether. The head effluent, after condensation, is subdivided into a liquid reflux and a distillate. The process is further characterized by providing a finishing reactor for the reflux, or for the reflux + distillate effluent prior to the subdivision thereof, or two finishing reactors are provided, one for the reflux and the other for the distillate, along with the possibility of injecting aliphatic monoalcohol upstream of each finishing reactor.

    摘要翻译： 一种制备叔烷基醚，特别是甲基叔丁基醚的方法。 戊基醚（MTAE），其包括在反应段中使由C5烃（包括反应性异戊烯）与过量的脂族一元醇如甲醇，乙醇，丙醇或异丙醇的混合物构成的电荷反应，并收集 在分馏段的底部，相应的纯叔。 烷基醚。 冷凝后的头部废水被细分为液体回流和馏出物。 该方法的特征还在于提供用于回流的精制反应器或在其分馏之前的回流+馏出物流出物，或者提供两个精整反应器，一个用于回流，另一个用于馏出物，以及可能性 在每个精整反应器上游注入脂族一元醇。

    Process and apparatus for the low pressure reforming of gasolines with heating by smoke gases
    2.
    发明授权
    Process and apparatus for the low pressure reforming of gasolines with heating by smoke gases 失效
    用烟气加热汽油低压重整的方法和装置

    公开(公告)号：US4973401A

    公开(公告)日：1990-11-27

    申请号：US382886

    申请日：1989-07-21

    申请人： Quang Dang Vu ,  Jean-Paul Bournonville ,  Larry Mank ,  Jean-Charles Viltard

    发明人： Quang Dang Vu ,  Jean-Paul Bournonville ,  Larry Mank ,  Jean-Charles Viltard

    IPC分类号： B01J8/12 ,  B01J8/08 ,  C10G35/12

    CPC分类号： C10G35/12 ,  B01J8/087 ,  B01J2208/0007 ,  B01J2208/00221 ,  B01J2208/00504 ,  B01J2208/0053

    摘要： The present invention relates to a process and a reactor for low pressure catalytic reforming of gasolines with heating by smoke gases.The reactor of the invention comprises:at least one means for introducing and removing the charge,at least one means for introducing and removing the catalyst,at least two elementary reaction cells not adjacent each other, substantially vertical and parallelepipedic, substantially parallel to each other, each of said cells being formed of three substantially parallelepipedic enclosures (an individual charge distributor, an individual processed charge collector, a catalytic bed),at least one general charge distributor,at least one general processed charge collector.The reforming process of the invention may be used in this reactor, smokes-based heating gases, coming from the combustion in air of a hydrocarbon mixture, flowing between the elementary reaction cells and thus bringing the heat required for the reforming reaction.

    摘要翻译： 本发明涉及一种通过烟雾气体加热汽油进行低压催化重整的方法和反应器。 本发明的反应器包括：用于引入和除去电荷的至少一种装置，至少一种用于引入和除去催化剂的装置，至少两个彼此不相邻的基本上垂直和平行六面体的基本反应元件，基本上彼此平行 每个所述电池由三个基本上平行六面体的外壳（单个电荷分布器，单独的处理电荷收集器，催化床），至少一个通用电荷分配器，至少一个通用处理的电荷收集器形成。 本发明的重整方法可用于该反应器中，来自烃类混合物的空气中的燃烧的基于烟雾的加热气体，其在元素反应池之间流动，从而产生重整反应所需的热量。

    Process for the isomerization of C.sub.5 /C.sub.6 normal paraffins with recycling of normal paraffins
    3.
    发明授权
    Process for the isomerization of C.sub.5 /C.sub.6 normal paraffins with recycling of normal paraffins 失效
    C5 / C6正常参比异构体异构化方法与回归方法

    公开(公告)号：US5233120A

    公开(公告)日：1993-08-03

    申请号：US914348

    申请日：1992-07-17

    申请人： Ari Minkkinen ,  Larry Mank ,  Sophie Jullian

    发明人： Ari Minkkinen ,  Larry Mank ,  Sophie Jullian

    IPC分类号： C10G35/095 ,  C10G45/64 ,  C10G61/06

    CPC分类号： C10G61/06 ,  C10G2400/02

    摘要： The isomerization of C.sub.5 /C.sub.6 n-paraffins to isoparaffins, comprises:a stage (1) of deisopentanizing a charge constituted by a light naphtha,a stage (2) of isomerizing the deisopentanization residue, an adsorption stage (3) carried out by passing the isomerization effluent onto an adsorbent retaining the n-paraffins and alternating with the adsorption stage (3), a desorption stage (4) carried out by lowering the pressure and stripping by means of an isopentane-rich gas flow from the deisopentanization stage.The isomerate freed from the n-paraffins in stage (3) is a product having a high octane number.

    摘要翻译： C5 / C6正链烷烃异构化为异链烷烃的方法包括：将由轻质石脑油构成的电荷脱异构化的阶段（1），异戊二烯化残渣的异构化阶段（2），通过时进行的吸附阶段（3） 将异构化流出物保留在保留正链烷烃并与吸附阶段（3）交替的吸附剂上，脱附阶段（4）通过降低压力和通过去异戊烷化阶段的富含异戊烷的气流汽提来进行。 在阶段（3）中脱离正链烷烃的异构体是具有高辛烷值的产物。

    Apparatus for processing a product from catalytic reforming
    5.
    发明授权
    Apparatus for processing a product from catalytic reforming 失效
    用于处理来自催化重整的产物的装置

    公开(公告)号：US5597404A

    公开(公告)日：1997-01-28

    申请号：US466686

    申请日：1995-06-06

    申请人： Bruno Domergue ,  Beatrtice Fischer ,  Larry Mank

    发明人： Bruno Domergue ,  Beatrtice Fischer ,  Larry Mank

    IPC分类号： C01B3/24 ,  C10G35/04 ,  B01D53/04 ,  B01D53/14

    CPC分类号： C10G35/04

    摘要： Apparatus for conducting an improved method of processing a catalytic reformate with an improved production of hydrogen. The apparatus comprises units for conducting a separation stage, absorption at 20.degree. to 60.degree. C. and at a pressure of at least 10 bars, purification of hydrogen over adsorbent beds and recycling of the residual gas obtained at purification.

    摘要翻译： 用于进行改进的氢气生产处理催化重整油的改进方法的装置。 该设备包括用于进行分离阶段的单元，在20℃至60℃的吸收和至少10巴的压力下，在吸附剂床上净化氢气并再循环净化时获得的残余气体。

    Device that comprises recycling to a separator a liquid effluent that is obtained from an absorber and is mixed with a feedstock
    9.
    发明授权
    Device that comprises recycling to a separator a liquid effluent that is obtained from an absorber and is mixed with a feedstock 有权
    包括将从吸收器获得并与原料混合的液体流出物再循环到分离器的装置

    公开(公告)号：US07132044B2

    公开(公告)日：2006-11-07

    申请号：US10071213

    申请日：2002-02-11

    申请人： Larry Mank ,  Laurent Watripont ,  Bruno Domergue

    发明人： Larry Mank ,  Laurent Watripont ,  Bruno Domergue

    IPC分类号： C10G5/00 ,  B01D3/00

    CPC分类号： C10G5/06 ,  C10G5/04 ,  C10G70/041

    摘要： A device comprising at least one absorber, at least one cold separator from which is extracted a gaseous phase that feeds the absorber, at least one recycling to said cold separator of at least a portion of liquid effluent that is obtained from the absorber and which is mixed with the feedstock, at least one heat exchanger for cooling the mixture prior to the recycling, at least one conduit for recovering a light hydrocarbon-enriched liquid fraction obtained from the cold separator and at least one conduit for evacuating gases from the absorber, said device being useable for the treatment of a hydrogen-rich gas or for the recovery of a hydrocarbon-enriched liquid.

    摘要翻译： 一种装置，包括至少一个吸收器，至少一个冷分离器，从其中提取进料吸收器的气相，至少一个回收至所述冷分离器的至少一部分从吸收器获得的液体流出物， 与原料混合的至少一个热交换器，用于在再循环之前冷却混合物的至少一个热交换器，用于回收从冷分离器获得的轻烃富集的液体馏分的至少一个管道和用于从吸收器排出气体的至少一个管道， 装置可用于处理富氢气体或用于回收富含烃的液体。

    Process for co-production of metaxylene and paraxylene
    10.
    发明授权
    Process for co-production of metaxylene and paraxylene 有权
    共生产间二甲苯和对二甲苯的方法

    公开(公告)号：US06359186B1

    公开(公告)日：2002-03-19

    申请号：US09382577

    申请日：1999-08-25

    申请人： Gérard Hotier ,  Larry Mank ,  Françoise Montecot

    发明人： Gérard Hotier ,  Larry Mank ,  Françoise Montecot

    IPC分类号： C07C712

    CPC分类号： C07C7/12 ,  C07C15/08

    摘要： For co-production of metaxylene and paraxylene from a feedstock (line-4) of hydrocarbons, there is employed a simulated moving bed chromatographic column 5 having at least five zones and which delivers an extract, a raffinate and an intermediate raffinate. The feedstock has an ethylbenzene content of less than 5% by weight, and the chromatographic column comprises at least twenty-five beds, of which at least five beds are in zone 3B. The raffinate is distilled (31) to recover the metaxylene at a purity of at least 99% and orthoxylene. The extract is distilled (7, 10) to recover the paraxylene at a purity of at least 99.6%. The recovered isomers can be synthesized into isophthalic acid and terephthalic acid.

    摘要翻译： 为了从烃的原料（管线-4）共同生产间二甲苯和对二甲苯，使用具有至少五个区并且提供萃取物，萃余液和中间萃余液的模拟移动床色谱柱5。 原料的乙苯含量小于5重量％，色谱柱包含至少二十五张床，其中至少五张床位于3B区。 蒸馏塔（31）以回收至少99％纯度的邻二甲苯和邻二甲苯。 将提取物蒸馏（7,10）以回收纯度至少为99.6％的对二甲苯。 回收的异构体可以合成为间苯二甲酸和对苯二甲酸。