Process for the production of a tertiary alkyl ether comprising a
fractionation section
    1.
    发明授权
    Process for the production of a tertiary alkyl ether comprising a fractionation section 失效
    制备包含分馏部分的叔烷基醚的方法

    公开(公告)号:US5364975A

    公开(公告)日:1994-11-15

    申请号:US57603

    申请日:1993-05-05

    CPC分类号: C07C41/42 C07C41/06

    摘要: A process for the preparation of a tertiary alkyl ether, in particular methyl tert. amyl ether (MTAE), is described which comprises reacting, in a reaction section, a charge constituted by a mixture of C.sub.5 hydrocarbons, including reactive isopentenes, with an aliphatic monoalcohol in excess, such as methanol, ethanol, propanol or isopropanol, and collecting in the bottom of a fractionation section the corresponding pure tert. alkyl ether. The head effluent, after condensation, is subdivided into a liquid reflux and a distillate. The process is further characterized by providing a finishing reactor for the reflux, or for the reflux + distillate effluent prior to the subdivision thereof, or two finishing reactors are provided, one for the reflux and the other for the distillate, along with the possibility of injecting aliphatic monoalcohol upstream of each finishing reactor.

    摘要翻译: 一种制备叔烷基醚,特别是甲基叔丁基醚的方法。 戊基醚(MTAE),其包括在反应段中使由C5烃(包括反应性异戊烯)与过量的脂族一元醇如甲醇,乙醇,丙醇或异丙醇的混合物构成的电荷反应,并收集 在分馏段的底部,相应的纯叔。 烷基醚。 冷凝后的头部废水被细分为液体回流和馏出物。 该方法的特征还在于提供用于回流的精制反应器或在其分馏之前的回流+馏出物流出物,或者提供两个精整反应器,一个用于回流,另一个用于馏出物,以及可能性 在每个精整反应器上游注入脂族一元醇。

    Process that involves the optimum etherification of a hydrocarbon
fraction that contains olefins that have 6 carbon atoms per molecule
    4.
    发明授权
    Process that involves the optimum etherification of a hydrocarbon fraction that contains olefins that have 6 carbon atoms per molecule 失效
    涉及含有每分子6个碳原子的烯烃的烃馏分的最佳醚化的方法

    公开(公告)号:US5962750A

    公开(公告)日:1999-10-05

    申请号:US602064

    申请日:1996-02-15

    摘要: A process for treating a feedstock containing olefins of 6 carbon atoms per molecule, said olefins being either potentially etherifiable or (directly) etherifiable, wherein isomerization of a portion of the potentially etherifiable olefins is accomplished in part in an isomerization zone, in the presence of an isomerization catalyst that makes it possible to obtain an isomerization effluent which comprises in part etherifiable olefins, and in that, in part, etherification is carried out, in the presence of an etherification catalyst and at least one alcohol that has 1 to 4 carbon atoms per molecule, of a portion of etherifiable olefins that are contained in the feedstock, in a first etherification zone, and in part etherification is carried out of a portion of etherifiable olefins that are contained in said isomerization effluent, in a second etherification zone, in the presence of an etherification catalyst and at least one alcohol that has 1 to 4 carbon atoms per molecule, to optimize the production of ethers.

    摘要翻译: 一种用于处理每分子含有6个碳原子的原料的原料的方法,所述烯烃可潜在地可醚化或(直接)可醚化,其中一部分潜在的可醚化烯烃的异构化部分地在异构化区域中,在 异构化催化剂,其可以获得异构化流出物,其部分包括可醚化的烯烃,并且部分地在醚化催化剂和至少一种具有1至4个碳原子的醇的存在下进行醚化 在一个第一醚化区中,部分醚化作用包括在原料中的一部分可醚化的烯烃,并且部分醚化由在所述异构化流出物中包含的一部分可醚化的烯烃进行,在第二醚化区,在 存在醚化催化剂和每分子具有1至4个碳原子的至少一种醇以优化 e生产醚类。

    ACETONITRILE REMOVAL FROM THE OLEFINIC FEED OF ETHER PRODUCTION PROCESSES USING IONIC LIQUIDS
    6.
    发明申请
    ACETONITRILE REMOVAL FROM THE OLEFINIC FEED OF ETHER PRODUCTION PROCESSES USING IONIC LIQUIDS 失效
    从使用离子液体的生产过程的油脂进料中除去乙腈

    公开(公告)号:US20080154068A1

    公开(公告)日:2008-06-26

    申请号:US11954108

    申请日:2007-12-11

    IPC分类号: C07C41/01

    摘要: An enhanced ether production process from an olefinic cut containing at least one iso-olefin and from an alcohol comprises a stage of removal of the acetonitrile present in the hydrocarbon feed by liquid-liquid extraction, the extraction solvent being a non-aqueous ionic liquid of general formula Q+A−, wherein Q+ is an ammonium, phosphonium and/or sulfonium cation, and A− an anion likely to form a liquid salt with said cation. Advantageously, the method according to the invention generally allows the amount of water at the etherification reactor inlet to be divided by at least two and thus the purity of the ether produced to be improved.

    摘要翻译: 含有至少一种异烯烃和醇的烯烃切割剂的增强的乙醚生产方法包括通过液 - 液萃取除去存在于烃进料中的乙腈的一个阶段,萃取溶剂是一种非水离子液体 其中Q +是铵,鏻和/或锍阳离子,并且A + SUP>可能与所述阳离子形成液体盐的阴离子。 有利地,根据本发明的方法通常允许将醚化反应器入口处的水量除以至少两个,从而提高生产的醚的纯度。

    Process and unit for carrying out a reaction on an organic feed, such as dimerization or metathesis, in the presence of a polar phase containing a catalyst
    10.
    发明授权
    Process and unit for carrying out a reaction on an organic feed, such as dimerization or metathesis, in the presence of a polar phase containing a catalyst 有权
    在含有催化剂的极性相存在下,在有机原料上进行反应的方法和单元,例如二聚或复分解

    公开(公告)号:US06630112B2

    公开(公告)日:2003-10-07

    申请号:US09779649

    申请日:2001-02-09

    IPC分类号: C08F200

    摘要: A process for carrying out a reaction on an organic feed, for example dimerization, co-dimerization, oligomerization or metathesis of olefins, as described in which the catalyst is a catalytic metal compound dissolved in a non-aqueous ionic medium which is not or is only slightly miscible with hydrocarbons. The reaction is carried out in a system comprising at least two treatment loops each comprising at least one reaction zone and at least one zone for separating the organic and polar phases between which the polar medium containing the catalytic metal compound, and the organic phase circulate. Fresh polar phase is injected into the second loop and used polar phase is eliminated from the first loop. The hydrocarbon to be transformed is injected into the first loop and the products are withdrawn from the second loop. The invention also concerns a unit for carrying out the process.

    摘要翻译: 对有机原料进行反应的方法,例如烯烃的二聚,共二聚,低聚或复分解,其中催化剂是溶解在非水性离子介质中的催化金属化合物,其不是或不是 只与碳氢化合物轻微混溶。 该反应在包括至少两个处理回路的系统中进行,每个处理回路各自包含至少一个反应区和至少一个用于分离有机相和极性相的区域,在该区域之间含有催化金属化合物的极性介质和有机相循环。 新鲜极性相注入到第二回路中,并且使用极性相从第一回路中消除。 将待转化的烃注入第一回路中,并从第二回路中取出产物。 本发明还涉及用于执行该过程的单元。