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    Preparation of anhydrous 2-amino-1-methoxypropane
    1.
    发明授权
    Preparation of anhydrous 2-amino-1-methoxypropane 失效
    无水2-氨基-1-甲氧基丙烷的制备

    公开(公告)号：US5910612A

    公开(公告)日：1999-06-08

    申请号：US82543

    申请日：1998-05-21

    申请人： Joachim Simon ,  Andreas Henne ,  Heinz Lingk

    发明人： Joachim Simon ,  Andreas Henne ,  Heinz Lingk

    IPC分类号： C07C213/02 ,  C07C213/10 ,  C07C217/08 ,  C07C209/02

    CPC分类号： C07C213/02 ,  C07C213/10

    摘要： The process for preparing anhydrous 2-amino-1-methoxypropane proceeds by(a) admixing a 2-amino-1-methoxypropane-containing water-containing reaction mixture, obtainable from the reaction of 1-methoxy-2-propanol with ammonia on a catalyst, with sodium hydroxide solution, forming an aqueous phase containing sodium hydroxide solution and a 2-amino-1-methoxypropane-containing phase,(b) separating off the 2-amino-1-methoxypropane-containing phase from the aqueous phase and(c) distilling the 2-amino-1-methoxypropane-containing phase, an azeotrope of water and 2-amino-1-methoxypropane, which is recycled to step (a) or (b), first being produced and anhydrous 2-amino-1-methoxypropane then being produced.

    摘要翻译： 制备无水2-氨基-1-甲氧基丙烷的方法是：（a）将可从1-甲氧基-2-丙醇反应得到的含2-氨基-1-甲氧基丙烷的含水反应混合物与氨混合， 催化剂，用氢氧化钠溶液，形成含有氢氧化钠溶液和含2-氨基-1-甲氧基丙烷的相的水相，（b）从水相中分离出含2-氨基-1-甲氧基丙烷的相和（ c）蒸馏出含有2-氨基-1-甲氧基丙烷的相，再循环至步骤（a）或（b）的水和2-氨基-1-甲氧基丙烷的共沸物，首先制得无水2-氨基-1-甲氧基丙烷， 然后生产1-甲氧基丙烷。

    Preparation of bis(2-morpholinoethyl) ether
    3.
    发明授权
    Preparation of bis(2-morpholinoethyl) ether 有权
    双（2-吗啉代乙基）醚的制备

    公开(公告)号：US6111100A

    公开(公告)日：2000-08-29

    申请号：US474906

    申请日：1999-12-30

    申请人： Hartmut Riechers ,  Joachim Simon ,  Andreas Henne ,  Arthur Hohn

    发明人： Hartmut Riechers ,  Joachim Simon ,  Andreas Henne ,  Arthur Hohn

    IPC分类号： C07D295/08 ,  B01J23/72 ,  C07D295/088 ,  C07D413/12

    CPC分类号： C07D295/088

    摘要： In a process for preparing bis(2-morpholinoethyl) ether by reacting diethylene glycol with ammonia under superatmospheric pressure and at elevated temperature in the presence of hydrogen and a hydrogenation catalyst, the catalytically active composition of the catalyst prior to reduction with hydrogen comprisesfrom 20 to 85% by weight of aluminum oxide (Al.sub.2 O.sub.3), zirconium dioxide (ZrO.sub.2), titanium dioxide (TiO.sub.2) and/or silicon dioxide (SiO.sub.2),from 1 to 70% by weight of oxygen-containing compounds of copper, calculated as CuO,from 0 to 50% by weight of oxygen-containing compounds of magnesium, calculated as MgO, oxygen-containing compounds of chromium, calculated as Cr.sub.2 O.sub.3, oxygen-containing compounds of zinc, calculated as ZnO, oxygen-containing compounds of barium, calculated as BaO, and/or oxygen-containing compounds of calcium, calculated as CaO, andless than 20% by weight of oxygen-containing compounds of nickel, calculated as NiO, based on the oxygen-containing compounds of copper, calculated as CuO.

    摘要翻译： 在氢气和氢化催化剂的存在下，在二氧化乙烯与氨在超大气压和升高的温度下反应制备双（2-吗啉代乙基）醚的方法中，用氢还原之前的催化剂催化活性组合物包括20 至85重量％的氧化铝（Al 2 O 3），二氧化锆（ZrO 2），二氧化钛（TiO 2）和/或二氧化硅（SiO 2），1至70重量％的含氧化合物的铜，以CuO ，0〜50重量％的以氧化镁计的含氧化合物的镁，以Cr 2 O 3计算的含氧化合物的铬，以ZnO计的氧的含氧化合物，钡的含氧化合物，计算值 作为BaO，和/或以CaO计的钙的含氧化合物，以NiO计，基于含氧化合物的铜，小于20重量％的含氧化合物的镍 ，以CuO计算。

    Removal of halides from halide-containing nitrile mixtures
    7.
    发明授权
    Removal of halides from halide-containing nitrile mixtures 失效
    从含卤素腈混合物中除去卤化物

    公开(公告)号：US6153784A

    公开(公告)日：2000-11-28

    申请号：US24457

    申请日：1998-02-17

    申请人： Heinz-Josef Kneuper ,  Hans-Jurgen Weyer ,  Horst Neuhauser ,  Johann-Peter Melder ,  Andreas Henne ,  Karl-Heinz Ross ,  Rainer Becker

    发明人： Heinz-Josef Kneuper ,  Hans-Jurgen Weyer ,  Horst Neuhauser ,  Johann-Peter Melder ,  Andreas Henne ,  Karl-Heinz Ross ,  Rainer Becker

    IPC分类号： B01J27/18 ,  B01J31/02 ,  C07B61/00 ,  C07C209/48 ,  C07C211/09 ,  C07C253/14 ,  C07C253/34 ,  C07C255/04

    CPC分类号： C07C253/14 ,  C07C209/48 ,  C07C253/34

    摘要： Halides are removed from halide-containing nitrile mixtures by(a) thermally treating the halide-containing nitrile mixture,(b) subsequently adding a base to the thermally treated nitrile mixture and(c) subsequently separating off the base from the nitrile mixture.Amines are prepared by(A) reacting alkyl halides with metal cyanides in an at least two-phase reaction medium in the presence of halide-containing phase-transfer catalysts to give alkanenitriles,(B) separating off the resulting halide-containing alkanenitrile mixture phase and(C) further treating the halide-containing alkanenitrile mixture phase, as described in the stages(a)-(c) removing halides from halide-containing nitrile mixtures and(d) hydrogenating nitrites obtained in stage (c) to give amines, in the presence of suspended or fixed-bed catalysts.

    摘要翻译： 通过（a）热处理含卤素腈混合物，（b）随后向经热处理的腈混合物中加入碱，和（c）随后将腈与腈混合物分离，从卤化物腈混合物中除去卤化物。 胺通过（A）在卤化物相转移催化剂存在下在至少两相反应介质中将烷基卤与金属氰化物反应得到烷腈，（B）将所得的含卤素的烷腈混合物相分离 （C）进一步处理含卤化物的腈腈混合物相，如步骤（a） - （c）所述从卤化物腈混合物中除去卤化物，和（d）氢化阶段（c）中得到的亚硝酸盐，得到胺， 在悬浮或固定床催化剂存在下。