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    Catalyst and process for the selective hydrogenation of multi-unsaturated organic compounds
    1.
    发明授权
    Catalyst and process for the selective hydrogenation of multi-unsaturated organic compounds 失效
    用于多不饱和有机化合物选择性氢化的催化剂和方法

    公开(公告)号：US4613714A

    公开(公告)日：1986-09-23

    申请号：US785472

    申请日：1985-10-08

    申请人： Karl-Heinz Stadler ,  Karel Kochloefl

    发明人： Karl-Heinz Stadler ,  Karel Kochloefl

    IPC分类号： C07C5/05 ,  B01J23/12 ,  B01J23/16 ,  B01J23/18 ,  B01J23/40 ,  B01J23/44 ,  B01J23/56 ,  B01J23/58 ,  B01J23/63 ,  B01J23/648 ,  B01J23/652 ,  C07C1/00 ,  C07C5/02 ,  C07C5/03 ,  C07C11/02 ,  C07C67/00

    CPC分类号： C07C5/02 ,  B01J23/40 ,  B01J23/56 ,  B01J23/58 ,  C07C5/03 ,  C07C2521/04 ,  C07C2521/06 ,  C07C2523/02 ,  C07C2523/12 ,  C07C2523/20 ,  C07C2523/22 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/30 ,  C07C2523/40 ,  C07C2523/44

    摘要： Catalyst for the selective hydrogenation of multi-unsaturated organic compounds, in particular of diolefins and dienes in mixtures with other hydrocarbons; the catalyst is characterized by(A) a metal component from one or more elements of Group VIII of the Periodic Table on(B) a support material on the basis(b.sub.1) of one or more n-semiconducting oxides of one or more elements from the Subgroups IVb, Vb and VIb of the Periodic Table or of thorium or cerium, or respectively on the basis(b.sub.2) of one or more n-semiconducting mixed oxide systems of the formula Me.sub.2 Me.sub.1 (0).sub.x, where Me.sub.1 is an element of the group defined in (b.sub.1), Me.sub.2 an alkaline earth metal or an element different from Me.sub.1 or the group defined in (b.sub.1), and x signifies the number of oxygen atoms required for the saturation of Me.sub.1 and Me.sub.2 to the range of an n-semiconducting state;the hydrogen chemisorption capacity, expressed as the atomic ratio between chemisorbed hydrogen atoms and metal atoms of the metal component (A) present on the surface of the metal particles, (H/Me.sub.A), being at least 0.6:1.

    摘要翻译： 用于多不饱和有机化合物，特别是与其它烃混合的二烯烃和二烯烃的选择性氢化的催化剂; 催化剂的特征在于（A）在（B）上周期表第Ⅷ族的一种或多种元素的金属组分，基于（b1）的一种或多种一种或多种元素的n-半导体氧化物的载体材料， 周期表的子组IVb，Vb和VIb，或钍或铈的分组IVb，或分别基于式（b2）的一种或多种式Me2Me1（0）x的n-半导体混合氧化物体系，其中Me1是 （b1）中定义的基团，Me2是碱土金属或不同于Me1的元素或（b1）中定义的基团，x表示Me1和Me2饱和所需的氧原子数在n的范围内 半导体状态; 以化学吸附氢原子和存在于金属颗粒表面上的金属组分（A）的金属原子之间的原子比（H / MeA）表示的氢化学吸附能力为至少0.6:1。

    Process for the production of olefins from synthesis gas
    5.
    发明授权
    Process for the production of olefins from synthesis gas 失效
    从合成气生产烯烃的方法

    公开(公告)号：US4398050A

    公开(公告)日：1983-08-09

    申请号：US234477

    申请日：1981-02-17

    申请人： Carl-Ernst Hofstadt ,  Michael Schneider ,  Karel Kochloefl

    发明人： Carl-Ernst Hofstadt ,  Michael Schneider ,  Karel Kochloefl

    IPC分类号： B01J23/00 ,  B01J23/80 ,  B01J23/86 ,  B01J23/889 ,  B01J27/18 ,  C07B61/00 ,  C07C1/00 ,  C07C1/24 ,  C07C9/02 ,  C07C11/02 ,  C07C27/00 ,  C07C27/06 ,  C07C29/15 ,  C07C29/151 ,  C07C29/154 ,  C07C29/80 ,  C07C31/02 ,  C07C67/00 ,  F02B1/04 ,  C07C1/04

    CPC分类号： C07C29/80 ,  B01J23/80 ,  B01J23/868 ,  B01J23/8892 ,  C07C1/24 ,  C07C29/1512 ,  C07C29/1516 ,  C07C29/154 ,  C07C2521/04 ,  C07C2527/167 ,  F02B1/04 ,  Y02P20/52

    摘要： A process for the production of olefins from synthesis gas comprises a first synthesis stage in which a mixture of methanol and higher alcohols are formed from a synthesis gas comprising hydrogen and carbon monoxide. The catalyst for the first synthesis stage comprises the oxides of copper and zinc in intimate association with each other and a promoting compound selected from the group consisting of chromium, cerium, lanthanum, manganese, thorium, and an alkali metal. The materials from the first synthesis stage are separated into a gas phase and a liquid phase. Thereafter the methanol is separated from the higher alcohol fractions. The higher alcohols are then subjected to dehydration in a dehydration stage which comprises passing the higher alcohol fraction over an alkalized dehydration catalyst at a pressure in the range of 0.5-1 bar and a temperature in the range of 350.degree.-500.degree. C. Thereafter the olefins produced by the dehydration of the higher alcohols are separated into the olefinic and non-olefinic materials. Preferred dehydration catalysts include alkalized aluminum oxide and alkalized calcium phosphate.

    摘要翻译： 从合成气生产烯烃的方法包括第一合成阶段，其中由包含氢气和一氧化碳的合成气形成甲醇和高级醇的混合物。 用于第一合成阶段的催化剂包括彼此紧密结合的铜和锌的氧化物和选自铬，铈，镧，锰，钍和碱金属的促进化合物。 将来自第一合成阶段的材料分离成气相和液相。 此后，甲醇与高级醇馏分分离。 然后将高级醇在脱水阶段进行脱水，该脱水阶段包括使高级醇馏分在0.5-1巴的压力和350-500℃的温度范围内使碱化的脱水催化剂通过。之后 通过高级醇脱水生产的烯烃被分离成烯烃和非烯属材料。 优选的脱水催化剂包括碱化氧化铝和碱化磷酸钙。

    Catalyst for the synthesis of methanol and alcohol mixtures containing higher alcohols and method of making the catalyst
    8.
    发明授权
    Catalyst for the synthesis of methanol and alcohol mixtures containing higher alcohols and method of making the catalyst 失效
    用于合成含高级醇的甲醇和醇混合物的催化剂和制备催化剂的方法

    公开(公告)号：US4598061A

    公开(公告)日：1986-07-01

    申请号：US694986

    申请日：1985-01-25

    申请人： Michael Schneider ,  Karel Kochloefl ,  Ortwin Bock

    发明人： Michael Schneider ,  Karel Kochloefl ,  Ortwin Bock

    IPC分类号： C07C29/15 ,  B01J23/80 ,  C07B61/00 ,  C07C27/00 ,  C07C29/154 ,  C07C31/02 ,  C07C67/00 ,  F02B1/04 ,  B01J21/04 ,  B01J23/06 ,  B01J23/10 ,  B01J23/72

    CPC分类号： C07C29/154 ,  B01J23/80 ,  F02B1/04 ,  Y02P20/52

    摘要： Catalyst for the synthesis of alcohol mixtures containing methanol and higher aliphatic alcohols from CO and H.sub.2, which contains, as an oxide precursor,(a) copper oxide and zinc oxide, which can be transformed into the catalytically active state by reduction with hydrogen;(b) aluminum oxide as a thermostabilizing substance and(c) at least one alkali carbonate or alkali oxide,the oxidic precursor comprising from 20 to 70% of the total volume of pores having a diameter between 14 and 7.5 nm, the alkali content being 13-130.times.10.sup.-6 gram atom alkali metal per gram of the oxidic precursor, and the aluminum oxide component having been obtained from a colloidally dispersed aluminum hydroxide gel or sol.

    摘要翻译： 用于合成含有来自CO和H 2的甲醇和高级脂族醇的醇混合物的催化剂，其包含作为氧化物前体的（a）氧化铜和氧化锌，其可以通过用氢还原转化成催化活性状态; （b）作为热稳定物质的氧化铝和（c）至少一种碱金属碳酸盐或碱金属氧化物，所述氧化物前体包含直径在14和7.5nm之间的孔体积的总体积的20至70％，碱含量为 13-130×10-6克原子碱金属/克氧化物前体，氧化铝组分由胶体分散的氢氧化铝凝胶或溶胶获得。